Abstract6R/S-deutero-α-d-mannopyranoside 1-phosphate was synthesised from a C6 aldehydic mannose thioglycoside donor in four steps. Using NaBD4 as the reductant, isotopic enrichment at C6 was achieved and the resultant C6-deuterated material was converted through to the glycosyl 1-phosphate using a protection/glycosylation/deprotection sequence. The product was fully characterised by 1H, 13C, 31P and 2D NMR, alongside MS analysis. View Full-Text
Share & Cite This Article
Ahmadipour, S.; Miller, G.J. 6R/S-deutero-α-d-mannopyranoside 1-phosphate. Molbank 2019, 2019, M1068.
Ahmadipour S, Miller GJ. 6R/S-deutero-α-d-mannopyranoside 1-phosphate. Molbank. 2019; 2019(3):M1068.Chicago/Turabian Style
Ahmadipour, Sanaz; Miller, Gavin J. 2019. "6R/S-deutero-α-d-mannopyranoside 1-phosphate." Molbank 2019, no. 3: M1068.
Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.