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[O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-κS]-(tri-4-tolylphosphine-κP)gold(I)

Research Centre for Crystalline Materials, School of Science and Technology, Sunway University, No. 5 Jalan Universiti, 47500 Bandar Sunway, Selangor Darul Ehsan, Malaysia
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Molbank 2018, 2018(4), M1028; https://doi.org/10.3390/M1028
Received: 22 October 2018 / Revised: 31 October 2018 / Accepted: 1 November 2018 / Published: 5 November 2018
(This article belongs to the Section Structure Determination)
The synthesis, spectroscopic characterization and X-ray crystal structure of the title compound, (4-tolyl)3PAu[SC(O-i-Pr)=NC6H4NO2-4] (1) are described. Spectroscopy exhibited the expected features confirming the formation of the compound. The molecular structure of 1 confirms the expected linear P–Au–S coordination geometry defined by thiolate-S and phosphane-P atoms. The nearly 7° deviation from linearity is ascribed to the close approach of the imine-bound phenyl group, indicative of a semi-localized Auπ(arene) interaction. The three-dimensional molecular packing is consolidated by methyl- and tolyl-C–HO(nitro) and tolyl-C–Hπ(tolyl) interactions. View Full-Text
Keywords: gold(I); thiocarbamate; Auπ interaction; X-ray crystallography gold(I); thiocarbamate; Auπ interaction; X-ray crystallography
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MDPI and ACS Style

Yeo, C.I.; Tiekink, E.R.T. [O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-κS]-(tri-4-tolylphosphine-κP)gold(I). Molbank 2018, 2018, M1028.

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