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Molbank 2018, 2018(4), M1028; https://doi.org/10.3390/M1028

[O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-κS]-(tri-4-tolylphosphine-κP)gold(I)

Research Centre for Crystalline Materials, School of Science and Technology, Sunway University, No. 5 Jalan Universiti, 47500 Bandar Sunway, Selangor Darul Ehsan, Malaysia
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Received: 22 October 2018 / Revised: 31 October 2018 / Accepted: 1 November 2018 / Published: 5 November 2018
(This article belongs to the Section Structure Determination)
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Abstract

The synthesis, spectroscopic characterization and X-ray crystal structure of the title compound, (4-tolyl)3PAu[SC(O-i-Pr)=NC6H4NO2-4] (1) are described. Spectroscopy exhibited the expected features confirming the formation of the compound. The molecular structure of 1 confirms the expected linear P–Au–S coordination geometry defined by thiolate-S and phosphane-P atoms. The nearly 7° deviation from linearity is ascribed to the close approach of the imine-bound phenyl group, indicative of a semi-localized Auπ(arene) interaction. The three-dimensional molecular packing is consolidated by methyl- and tolyl-C–HO(nitro) and tolyl-C–Hπ(tolyl) interactions. View Full-Text
Keywords: gold(I); thiocarbamate; Auπ interaction; X-ray crystallography gold(I); thiocarbamate; Auπ interaction; X-ray crystallography
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Yeo, C.I.; Tiekink, E.R.T. [O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-κS]-(tri-4-tolylphosphine-κP)gold(I). Molbank 2018, 2018, M1028.

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