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Open AccessFeature PaperShort Note

(3-Ammonio-2,2-dimethyl-propyl)carbamate Dihydrate

Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-University Düsseldorf, Universitätsstraße 1, 40225 Düsseldorf, Germany
Author to whom correspondence should be addressed.
Molbank 2018, 2018(3), M1015;
Received: 16 July 2018 / Revised: 26 August 2018 / Accepted: 27 August 2018 / Published: 29 August 2018
(This article belongs to the Section Structure Determination)
(3-Ammonio-2,2-dimethylpropyl)carbamate dihydrate was synthesised. The title compound was characterised by single crystal X-ray diffraction and IR-/Raman-spectroscopy. It has been demonstrated that a mixture of dilute acetic acid and 2,2-dimethyl-1,3-diaminopropane is able to capture CO2 spontaneously from the atmosphere. An intramolecular hydrogen bond stabilises the conformation of the ylide-type title molecule. Intermolecular hydrogen bonds between all moieties connect them to a strand-type chain structure. View Full-Text
Keywords: carbamate; CO2 absorption; hydrogen bond; X-ray crystallography carbamate; CO2 absorption; hydrogen bond; X-ray crystallography
MDPI and ACS Style

Heimgert, J.; Neumann, D.; Reiss, G.J. (3-Ammonio-2,2-dimethyl-propyl)carbamate Dihydrate. Molbank 2018, 2018, M1015.

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