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Molbank 2018, 2018(3), M1015;

(3-Ammonio-2,2-dimethyl-propyl)carbamate Dihydrate

Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-University Düsseldorf, Universitätsstraße 1, 40225 Düsseldorf, Germany
Author to whom correspondence should be addressed.
Received: 16 July 2018 / Revised: 26 August 2018 / Accepted: 27 August 2018 / Published: 29 August 2018
(This article belongs to the Section Structure Determination)
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(3-Ammonio-2,2-dimethylpropyl)carbamate dihydrate was synthesised. The title compound was characterised by single crystal X-ray diffraction and IR-/Raman-spectroscopy. It has been demonstrated that a mixture of dilute acetic acid and 2,2-dimethyl-1,3-diaminopropane is able to capture CO2 spontaneously from the atmosphere. An intramolecular hydrogen bond stabilises the conformation of the ylide-type title molecule. Intermolecular hydrogen bonds between all moieties connect them to a strand-type chain structure. View Full-Text
Keywords: carbamate; CO2 absorption; hydrogen bond; X-ray crystallography carbamate; CO2 absorption; hydrogen bond; X-ray crystallography
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Heimgert, J.; Neumann, D.; Reiss, G.J. (3-Ammonio-2,2-dimethyl-propyl)carbamate Dihydrate. Molbank 2018, 2018, M1015.

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