4-Acetyl-2-hydroxy-2,5-dimethylfuran-3(2H)-one
1
Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, Kurokami 2-39-1, Kumamoto 860-8555, Japan
2
Department of Chemistry, Kumamoto University, Kurokami 2-39-1, Kumamoto 860-8555, Japan
*
Author to whom correspondence should be addressed.
Academic Editors: Luke R. Odell and Norbert Haider
Molbank 2016, 2016(4), M913; https://doi.org/10.3390/M913
Received: 7 September 2016 / Revised: 12 October 2016 / Accepted: 14 October 2016 / Published: 20 October 2016
The facile synthesis of 4-acetyl-2-hydroxy-2,5-dimethylfuran-3(2H)-one (4) was achieved by the Mn(OAc)3-mediated aerobic oxidation of 2,4-pentanedione or the direct reaction of Mn(acac)3 in AcOH-TFE at room temperature under a dried air stream.
View Full-Text
Keywords:
4-acetyl-2-hydroxy-2,5-dimethylfuran-3(2H)-one; keto-hemiacetal; Mn(acac)3; Mn(OAc)3; aerobic oxidation; 2,4-pentanedione; cyclic acetal; trifluoroethanol
▼
Show Figures
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited
- Supplementary File 1:
Supplementary 3D structure (MOL, 1 KiB)
Display in JSmol Viewer
3D structure generated by CORINA Classic by MN-AM. - Supplementary File 2:
Supplementary (INCHI, 361 B)
- Supplementary File 3:
Supplementary (MOL, 1 KiB)
Display in JSmol Viewer
- Supplementary File 4:
Supplementary (PDF, 1776 KiB)
MDPI and ACS Style
Akazaki, C.; Kawabata, S.; Nishino, H. 4-Acetyl-2-hydroxy-2,5-dimethylfuran-3(2H)-one. Molbank 2016, 2016, M913. https://doi.org/10.3390/M913
AMA Style
Akazaki C, Kawabata S, Nishino H. 4-Acetyl-2-hydroxy-2,5-dimethylfuran-3(2H)-one. Molbank. 2016; 2016(4):M913. https://doi.org/10.3390/M913
Chicago/Turabian StyleAkazaki, Chiaki; Kawabata, Shun; Nishino, Hiroshi. 2016. "4-Acetyl-2-hydroxy-2,5-dimethylfuran-3(2H)-one" Molbank 2016, no. 4: M913. https://doi.org/10.3390/M913
Find Other Styles
Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.
Search more from Scilit