Quantum Chemical and FTIR Spectroscopic Studies on the Linkage Isomerism of Carbon Monoxide in Alkali-Metal-Exchanged Zeolites: A Review of Current Research
Abstract
:1. Introduction
2. Summary of experimental procedures and results
3. Outline of Quantum Chemical Studies
System | ν(HF), cm-1 | ν(LF), cm-1 | ΔH°, kJ mol-1 |
CO/Na-ZSM-5 | 2178 | 2112 | 3.8 |
CO/K-ZSM-5 | 2166 | 2117 | 3.2 |
CO/Rb-ZSM-5 | 2161 | 2120 | 1.8 |
CO/Na-Y | 2171 | 2122 | 2.4 |
M+ | ΔH°/bare cation | ΔH°/[AlH(OH)3]-M+ | ΔH°/experimental |
---|---|---|---|
Li+ | 16.3 | 6.3 | - |
Na+ | 12.2 | 5.6 | 3.8 |
K+ | 6.3 | 2.9 | 3.2 |
Rb+ | 5.4 | 2.5 | 1.8 |
Cs+ | 4.6 | 2.1 | - |
4. Discussion
4.1 Thermal isomerization equilibrium
4.2 Isomerization enthalpy as a function of electric field
5. Conclusions and outlook
References
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Areán, C.O.; Palomino, G.T.; Tsyganenko, A.A.; Garrone, E. Quantum Chemical and FTIR Spectroscopic Studies on the Linkage Isomerism of Carbon Monoxide in Alkali-Metal-Exchanged Zeolites: A Review of Current Research. Int. J. Mol. Sci. 2002, 3, 764-776. https://doi.org/10.3390/i3070764
Areán CO, Palomino GT, Tsyganenko AA, Garrone E. Quantum Chemical and FTIR Spectroscopic Studies on the Linkage Isomerism of Carbon Monoxide in Alkali-Metal-Exchanged Zeolites: A Review of Current Research. International Journal of Molecular Sciences. 2002; 3(7):764-776. https://doi.org/10.3390/i3070764
Chicago/Turabian StyleAreán, C. Otero, G. Turnes Palomino, A. A. Tsyganenko, and E. Garrone. 2002. "Quantum Chemical and FTIR Spectroscopic Studies on the Linkage Isomerism of Carbon Monoxide in Alkali-Metal-Exchanged Zeolites: A Review of Current Research" International Journal of Molecular Sciences 3, no. 7: 764-776. https://doi.org/10.3390/i3070764