CuO Modified by 7,7,8,8-Tetracyanoquinodimethane and Its Application to CO2 Separation
Abstract
:1. Introduction
2. Results and Discussion
2.1. Scanning Electron Microscope (SEM)
2.2. Fourier Transform Infrared (FTIR)
2.3. TGA
2.4. UV–Vis Spectroscopy
2.5. Separation Test
3. Materials and Methods
3.1. Materials
3.2. Methods
3.2.1. Membrane Preparation
3.2.2. Gas Permeance Experiments
3.2.3. Characterization
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
- Lonngren, K.E.; Bai, E. On the global warming problem due to carbon dioxide. Energy Policy 2008, 36, 1567–1568. [Google Scholar] [CrossRef]
- Mohajan, H. Greenhouse gas emissions increase global warming. Int. J. Econ. Political Integr. 2011, 1, 21–34. [Google Scholar]
- Tol, R.S. The economic effects of climate change. J. Econ. Perspect. 2009, 23, 29–51. [Google Scholar] [CrossRef] [Green Version]
- Houghton, J. The science of global warming. Interdiscip. Sci. Rev. 2001, 26, 247–257. [Google Scholar] [CrossRef]
- Adom, P.K.; Bekoe, W.; Amuakwa-Mensah, F.; Mensah, J.T.; Botchway, E. Carbon dioxide emissions, economic growth, industrial structure, and technical efficiency: Empirical evidence from Ghana, Senegal, and Morocco on the causal dynamics. Energy 2012, 47, 314–325. [Google Scholar] [CrossRef]
- Yoon, K.W.; Kang, S.W. Highly permeable and selective CO2 separation membrane to utilize 5-hydroxyisophthalic acid in poly(ethylene oxide) matrix. Chem. Eng. J. 2018, 334, 1749–1753. [Google Scholar] [CrossRef]
- Tucker, M. Carbon dioxide emissions and global GDP. Ecol. Econ. 1995, 15, 215–223. [Google Scholar] [CrossRef]
- Xu, J.; Wu, H.; Wang, Z.; Qiao, Z.; Zhao, S.; Wang, J. Recent advances on the membrane processes for CO2 separation. Chin. J. Chem. Eng. 2018, 26, 2280–2291. [Google Scholar] [CrossRef]
- Wang, M.; Wang, Z.; Zhao, S.; Wang, J.; Wang, S. Recent advances on mixed matrix membranes for CO2 separation. Chin. J. Chem. Eng. 2017, 25, 1581–1597. [Google Scholar] [CrossRef]
- Sakamoto, Y.; Nagata, K.; Yogo, K.; Yamada, K. Preparation and CO2 separation properties of amine-modified mesoporous silica membranes. Microporous Mesoporous Mater. 2007, 101, 303–311. [Google Scholar] [CrossRef]
- L’Orange Seigo, S.; Dohle, S.; Siegrist, M. Public perception of carbon capture and storage (CCS): A review. Renew. Sustain. Energy Rev. 2014, 38, 848–863. [Google Scholar] [CrossRef]
- Tong, Z.; Ho, W.W. Facilitated transport membranes for CO2 separation and capture. Sep. Sci. Technol. 2017, 52, 156–167. [Google Scholar] [CrossRef]
- Brunetti, A.; Scura, F.; Barbieri, G.; Drioli, E. Membrane technologies for CO2 separation. J. Membr. Sci. 2010, 359, 115–125. [Google Scholar] [CrossRef]
- Míguez, J.L.; Porteiro, J.; Pérez-Orozco, R.; Gómez, M.Á. Technology evolution in membrane-based CCS. Energies 2018, 11, 3153. [Google Scholar] [CrossRef] [Green Version]
- Li, J.; Wang, D.K.; Tseng, H.; Wey, M. Solvent effects on diffusion channel construction of organosilica membrane with excellent CO2 separation properties. J. Membr. Sci. 2021, 618, 118758. [Google Scholar] [CrossRef]
- Kim, S.; Lee, Y.M. High performance polymer membranes for CO2 separation. Curr. Opin. Chem. Eng. 2013, 2, 238–244. [Google Scholar] [CrossRef]
- Han, Y.; Ho, W.W. Polymeric membranes for CO2 separation and capture. J. Membr. Sci. 2021, 628, 119244. [Google Scholar] [CrossRef]
- Vinoba, M.; Bhagiyalakshmi, M.; Alqaheem, Y.; Alomair, A.A.; Pérez, A.; Rana, M.S. Recent progress of fillers in mixed matrix membranes for CO2 separation: A review. Sep. Purif. Technol. 2017, 188, 431–450. [Google Scholar] [CrossRef]
- Hasebe, S.; Aoyama, S.; Tanaka, M.; Kawakami, H. CO2 separation of polymer membranes containing silica nanoparticles with gas permeable nano-space. J. Membr. Sci. 2017, 536, 148–155. [Google Scholar] [CrossRef]
- Zhang, J.; Xin, Q.; Li, X.; Yun, M.; Xu, R.; Wang, S.; Li, Y.; Lin, L.; Ding, X.; Ye, H.; et al. Mixed matrix membranes comprising aminosilane-functionalized graphene oxide for enhanced CO2 separation. J. Membr. Sci. 2019, 570–571, 343–354. [Google Scholar] [CrossRef]
- Hossain, I.; Al Munsur, A.Z.; Choi, O.; Kim, T. Bisimidazolium PEG-mediated crosslinked 6FDA-durene polyimide membranes for CO2 separation. Sep. Purif. Technol. 2019, 224, 180–188. [Google Scholar] [CrossRef]
- Lilleby Helberg, R.M.; Dai, Z.; Ansaloni, L.; Deng, L. PVA/PVP blend polymer matrix for hosting carriers in facilitated transport membranes: Synergistic enhancement of CO2 separation performance. Green Energy Environ. 2020, 5, 59–68. [Google Scholar] [CrossRef]
- Xin, Q.; Wu, H.; Jiang, Z.; Li, Y.; Wang, S.; Li, Q.; Li, X.; Lu, X.; Cao, X.; Yang, J. SPEEK/amine-functionalized TiO2 submicrospheres mixed matrix membranes for CO2 separation. J. Membr. Sci. 2014, 467, 23–35. [Google Scholar] [CrossRef]
- Rhyu, S.Y.; Kang, S.W. Accelerated CO2 transport by synergy effect of ionic liquid and Zn particles. J. Ind. Eng. Chem. 2021, 103, 216–221. [Google Scholar] [CrossRef]
- Lee, H.J.; Kang, S.W. CO2 separation with polymer/aniline composite membranes. Polymers 2020, 12, 1363. [Google Scholar] [CrossRef] [PubMed]
- Kim, H.; Sohn, H.; Kang, S.W. CO2 separation membranes consisting of ionic liquid/CdO composites. J. Nanosci. Nanotechnol. 2018, 18, 5817–5821. [Google Scholar] [CrossRef]
- Kim, H.Y.; Kang, S.W. CO2 separation using composites consisting of 1-butyl-3-methylimidazolium tetrafluoroborate/CdO/1-aminopyridinium iodide. Sci. Rep. 2019, 9, 16563. [Google Scholar] [CrossRef]
- Kim, B.J.; Kang, S.W. Accelerated CO2 transport on the surface-tuned Ag nanoparticles by p-benzoquinone. J. Ind. Eng. Chem. 2022, 106, 311–316. [Google Scholar]
CO2/N2 Selectivity | CO2 Permeance (GPU) | |
---|---|---|
Neat PVP | Not measurable | Not measurable |
PVP/CuO | 0.9 | 13.3 |
PVP/CuO/TCNQ | 174 ± 9.5 | 1.7 ± 0.1 |
Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. |
© 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Share and Cite
Lee, J.; Kang, S. CuO Modified by 7,7,8,8-Tetracyanoquinodimethane and Its Application to CO2 Separation. Int. J. Mol. Sci. 2022, 23, 14583. https://doi.org/10.3390/ijms232314583
Lee J, Kang S. CuO Modified by 7,7,8,8-Tetracyanoquinodimethane and Its Application to CO2 Separation. International Journal of Molecular Sciences. 2022; 23(23):14583. https://doi.org/10.3390/ijms232314583
Chicago/Turabian StyleLee, Juyeong, and Sangwook Kang. 2022. "CuO Modified by 7,7,8,8-Tetracyanoquinodimethane and Its Application to CO2 Separation" International Journal of Molecular Sciences 23, no. 23: 14583. https://doi.org/10.3390/ijms232314583