Tunneling Quantum Dynamics in Ammonia
Abstract
:1. Introduction
2. Quantum Hamilton Mechanics
3. Vibrational Eigenfunctions of Ammonia
4. Nitrogen Dynamics in Single-Well Potential
5. Tunneling Dynamic in Stationary States
5.1. Tunneling Trajectory in the Ground State
5.2. Tunneling Trajectory in the Excited States
6. Tunneling Dynamics in Two-Level Transition States
7. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Equilibrium Positions | 0 | |||
Tunneling Range | ||||
Tunneling Frequency | Hz | Hz | Hz | |
Equilibrium Positions | ||||
Tunneling Range | - | 0 | ||
Tunneling Frequency | Hz | Hz | Hz | |
Equilibrium Positions | - | |||
Tunneling Range | - | |||
Tunneling Frequency | - | Hz | Hz | |
Equilibrium Positions | - | - | ||
Tunneling Range | - | - | −3.298~−3.145, 3.145~3.298 | |
Tunneling Frequency | - | - | Hz | |
Hz |
Comparison | Tunneling Range | Energy Splitting | Tunneling Frequency |
---|---|---|---|
Experimental data | |||
Theoretical results | - | ||
Computation results |
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Yang, C.-D.; Han, S.-Y. Tunneling Quantum Dynamics in Ammonia. Int. J. Mol. Sci. 2021, 22, 8282. https://doi.org/10.3390/ijms22158282
Yang C-D, Han S-Y. Tunneling Quantum Dynamics in Ammonia. International Journal of Molecular Sciences. 2021; 22(15):8282. https://doi.org/10.3390/ijms22158282
Chicago/Turabian StyleYang, Ciann-Dong, and Shiang-Yi Han. 2021. "Tunneling Quantum Dynamics in Ammonia" International Journal of Molecular Sciences 22, no. 15: 8282. https://doi.org/10.3390/ijms22158282