Optical Properties of Bismuth Tellurite Based Glass
Abstract
:1. Introduction
2. Results and Discussion
2.1. XRD
2.2. Density and Molar Volume
2.3. FTIR Results
2.4. Refractive Index and Optical Absorption
3. Experimental
4. Conclusions
Acknowledgments
References
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Samples | x (mol%) | Molar mass (g/mol) | Density (g/cm3) | Molar Volume (cm3/mol) |
---|---|---|---|---|
TB5 | 5 | 174.92 | 5.43 | 32.22 |
TB8 | 8 | 184.11 | 5.69 | 32.35 |
TB10 | 10 | 190.23 | 5.85 | 32.49 |
TB12 | 12 | 196.36 | 6.03 | 32.56 |
TB15 | 15 | 205.55 | 6.26 | 32.86 |
Wavenumber(cm−1) | Mode |
---|---|
400–600 | Bi–O–Bi + Bi–O in BiO6 octahedral [23] |
650–660 | Te–Oax in [TeO4] [24,25] |
775 | Te–Oeq in [TeO4] [26,27] |
633, 695 | (shoulders) Te-O− [10] |
600–610 | Bi–O− stretch in BiO6 units [28] |
860–865 | Bi–O vibration in distorted BiO6 units [11] |
Sample glass | Indirect bandgap, Eopt (eV) | Direct bandgap (eV) | Urbach energy, Eg (eV) | Refractive index in wavelength 632.8 nm, n |
---|---|---|---|---|
TB 5 | 2.40 | 3.02 | 0.44 | 1.97 |
TB 8 | 2.77 | 3.10 | 0.22 | 1.99 |
TB 10 | 2.75 | 3.08 | 0.23 | 2.02 |
TB 12 | 2.70 | 3.04 | 0.24 | 2.07 |
TB 15 | 2.60 | 3.00 | 0.25 | 2.12 |
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Oo, H.M.; Mohamed-Kamari, H.; Wan-Yusoff, W.M.D. Optical Properties of Bismuth Tellurite Based Glass. Int. J. Mol. Sci. 2012, 13, 4623-4631. https://doi.org/10.3390/ijms13044623
Oo HM, Mohamed-Kamari H, Wan-Yusoff WMD. Optical Properties of Bismuth Tellurite Based Glass. International Journal of Molecular Sciences. 2012; 13(4):4623-4631. https://doi.org/10.3390/ijms13044623
Chicago/Turabian StyleOo, Hooi Ming, Halimah Mohamed-Kamari, and Wan Mohd Daud Wan-Yusoff. 2012. "Optical Properties of Bismuth Tellurite Based Glass" International Journal of Molecular Sciences 13, no. 4: 4623-4631. https://doi.org/10.3390/ijms13044623