Conventional Study on Novel Dicationic Ionic Liquid Inclusion with β-Cyclodextrin
Abstract
:1. Introduction
2. Experimental
2.1. Reagent and Solution
2.2. Instrumentation
2.3. Synthesis
2.3.1. Preparation of 3,3′-(1,4-Phenylenebis [methylene]) bis(1-methyl-1H-imidazol-3-ium) di(bromide) (PhenmimBr)
2.3.2. Synthesis of β-Cyclodextrin-PhenmimBr (β-CD-PhenmimBr)
2.4. Procedure
2.4.1. Preparation of β-CD-PhenmimBr for Spectroscopic Studies
3. Results and Discussion
3.1. 1H Nuclear Magnetic Resonance (NMR) Spectra
3.2. Correlation Spectroscopy (COSY)
3.3. Fourier Transform Infrared (FT-IR) Spectroscopy
3.4. X-ray Diffraction (XRD) Analysis
3.5. Thermogravimetric Analysis (TGA)
3.6. Differential Scanning Calorimetry (DSC)
3.7. Scanning Electron Microscopy (SEM)
3.8. UV-Visible Spectroscopy
3.8.1. Stoichiometry of the Complex and Formation Constant
3.8.2. Inclusion Structure
4. Conclusion
Acknowledgement
Reference
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β-CD | PhenmimBr | β-CD-PhenmimBr | ||
---|---|---|---|---|
δ | δ | δ | Δδ | |
H1 | 4.8191 | 4.8094 | −0.0097 | |
H2 | 3.3144 | 3.2955 | −0.0189 | |
H3 | 3.6402 | 3.5987 | −0.0415 | |
H4 | 3.3607 | 3.3504 | −0.0103 | |
H5 | 3.6006 | 3.5591 | −0.0415 | |
H6 | 3.6469 | 3.6189 | −0.0280 | |
Ha | 3.8532 | 3.8410 | −0.0122 | |
Hb | 9.3449 | 9.2430 | −0.1019 | |
Hc | 5.4598 | 5.4226 | −0.0372 | |
Hd | 7.8243 | 7.7633 | −0.0610 | |
He | 7.7291 | 7.6974 | −0.0317 | |
Hf | 7.4948 | 7.4637 | −0.0311 |
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Mohamad, S.; Surikumaran, H.; Raoov, M.; Marimuthu, T.; Chandrasekaram, K.; Subramaniam, P. Conventional Study on Novel Dicationic Ionic Liquid Inclusion with β-Cyclodextrin. Int. J. Mol. Sci. 2011, 12, 6329-6345. https://doi.org/10.3390/ijms12096329
Mohamad S, Surikumaran H, Raoov M, Marimuthu T, Chandrasekaram K, Subramaniam P. Conventional Study on Novel Dicationic Ionic Liquid Inclusion with β-Cyclodextrin. International Journal of Molecular Sciences. 2011; 12(9):6329-6345. https://doi.org/10.3390/ijms12096329
Chicago/Turabian StyleMohamad, Sharifah, Hemavathy Surikumaran, Muggundha Raoov, Tilagam Marimuthu, Kumuthini Chandrasekaram, and Puvaneswary Subramaniam. 2011. "Conventional Study on Novel Dicationic Ionic Liquid Inclusion with β-Cyclodextrin" International Journal of Molecular Sciences 12, no. 9: 6329-6345. https://doi.org/10.3390/ijms12096329