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Synthesis and Reactions of N-Methylbenzylammonium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Oxidant

Department of Chemistry, Tarbiat Modarres University, P.O. Box 14155-4838, Tehran, Iran
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Molecules 2004, 9(10), 825-829; https://doi.org/10.3390/91000825
Received: 28 June 2004 / Revised: 11 June 2004 / Accepted: 15 June 2004 / Published: 30 September 2004
N-Methylbenzylammonium fluorochromate(VI) (MBAFC) is easily synthesized by addition of N-methylbenzylamine to an aqueous solution of CrO3 and HF. MBAFC shows selectivity in the oxidation of aryl alcohols to their corresponding aldehydes and ketones under mild conditions. The durability, ease of work up and efficiency of MBAFC are considerably increased upon its absorption on silica gel. View Full-Text
Keywords: N-Methylbenzylammonium fluorochromate(VI); heterogeneous oxidants; silica gel; oxidation; alcohols. N-Methylbenzylammonium fluorochromate(VI); heterogeneous oxidants; silica gel; oxidation; alcohols.
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Kassaee, M.Z.; Sayyed-Alangi, S.Z.; Sajjadi-Ghotbabadi, H. Synthesis and Reactions of N-Methylbenzylammonium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Oxidant. Molecules 2004, 9, 825-829.

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