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Synthesis of Substituted 2-Pyridyl-4-phenylquinolines

Department of Physical and Chemical Methodologies for Engineering, Engineering Faculty, University of Catania, V.le Andrea Doria 6, I-95125 Catania, Italy
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Molecules 2002, 7(8), 618-627; https://doi.org/10.3390/70800618
Received: 21 June 2002 / Revised: 2 August 2002 / Accepted: 3 August 2003 / Published: 31 August 2002
The acid-catalyzed condensation of o-aminobenzophenones with aromatic acetyl derivatives, in a basic methanol/tetrahydrofuran medium, has been used to prepare a series of substituted 2-pyridyl-4-phenylquinolines. Derivatives having two aza binding sites can act as asymmetric bidendate ligands to complex transition metals such as ruthenium, osmium or iridium. All the compounds were characterized by elemental analysis, Ei or FAB (+) MS, 1H- and 13C-NMR spectroscopies. Complete assignments of the 1H spectra were accomplished by using a combination of one- and two-dimensional NMR techniques. View Full-Text
Keywords: Quinoline derivatives; asymmetric bidentate aza-ligands; 2D-NMR Quinoline derivatives; asymmetric bidentate aza-ligands; 2D-NMR
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Mamo, A.; Nicoletti, S.; Tat, N.C. Synthesis of Substituted 2-Pyridyl-4-phenylquinolines. Molecules 2002, 7, 618-627.

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