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Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates

Research and Development, Roche Vitamins Ltd, CH-4070 Basel, Switzerland
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Molecules 2002, 7(8), 601-617; https://doi.org/10.3390/70800601
Received: 16 May 2002 / Revised: 13 August 2002 / Accepted: 24 August 2002 / Published: 31 August 2002
The trichloromethylsulfonyl-, dichloromethylsulfonyl-, chlorosulfonyl-, and fluorosulfonyl esters of a neopentyl-type alcohol have been prepared via sulfonylation or sulfinylation followed by oxidation. The preparative usefulness and potential of the transformations are discussed. View Full-Text
Keywords: Alkylation reagents; SN2 substitution reactions; steric hindrance; sulfonic esters; sulfur-oxygen bond cleavage. Alkylation reagents; SN2 substitution reactions; steric hindrance; sulfonic esters; sulfur-oxygen bond cleavage.
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Netscher, T.; Bohrer, P. Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates. Molecules 2002, 7, 601-617.

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