Next Article in Journal
Synthesis, Structure and Antitumor Activity of Dibutyltin Oxide Complexes with 5-Fluorouracil Derivatives. Crystal Structure of [(5-Fluorouracil)-1-CH2CH2COOSn(n-Bu) 2]4O2
Previous Article in Journal
Heterocyclic o-Aminonitriles: Preparation of Pyrazolo[3,4-d]-pyrimidines with Modification of the Substituents at the 1- Position
Open AccessArticle

Electrochemical Study of Bromide in the Presence of 1,3-Indandione. Application to the Electrochemical Synthesis of Bromo Derivatives of 1,3-Indandione

Department of Chemistry, Faculty of Science, University of Bu-Ali-Sina, Hamadan, Iran
*
Author to whom correspondence should be addressed.
Molecules 2001, 6(7), 639-646; https://doi.org/10.3390/60700639
Received: 15 November 2000 / Revised: 7 June 2001 / Accepted: 8 June 2001 / Published: 30 June 2001
The electrochemical oxidation of bromide in the presence of 1,3-indandione (1) in water/acetic acid and methanol/acetic acid mixtures has been studied by cyclic voltammetry and controlled-potential coulometry. The results indicate the participation of 1,3-indandione in the bromination reaction. On the basis of the electroanalytical and preparative results a reaction mechanism including electron transfer, chemical reaction and regeneration of bromide was discussed. The electrochemical synthesis of bromo derivatives of 1,3-indandione (2-3) has been successfully performed at constant current, in an undivided cell, in good yield and purity. View Full-Text
Keywords: Electrochemical oxidation; cyclic voltammetry; 1; 3-indandione; 2-bromo- 1; 3-indandione; 2; 2-dibromo-1; 3-indandione Electrochemical oxidation; cyclic voltammetry; 1; 3-indandione; 2-bromo- 1; 3-indandione; 2; 2-dibromo-1; 3-indandione
Show Figures

Figure 1

MDPI and ACS Style

Nematollahi, D.; Akaberi, N. Electrochemical Study of Bromide in the Presence of 1,3-Indandione. Application to the Electrochemical Synthesis of Bromo Derivatives of 1,3-Indandione. Molecules 2001, 6, 639-646.

Show more citation formats Show less citations formats

Article Access Map by Country/Region

1
Only visits after 24 November 2015 are recorded.
Back to TopTop