Next Article in Journal
Synthesis of D-Homo Analogs of Neurosteroids
Previous Article in Journal
Synthesis of Aziridinosteroids
Article Menu

Export Article

Open AccessAbstract
Molecules 2000, 5(3), 445-446; https://doi.org/10.3390/50300445

3,3-Dimethylacylthioureas: "S", "-S", "U" or "W" Conformation?

1
Facultad de Química, Universidad de La Habana, Cuba
2
Instituto Superior de Ciencias y Tecnologías Nucleares, Cuba
3
Depto. de Química Orgánica, Facultad de Ciencias Exactas y Naturales Universidad de Buenos Aires, Argentina
*
Author to whom correspondence should be addressed.
Published: 22 March 2000
Full-Text   |   PDF [15 KB, uploaded 18 June 2014]

Abstract

We report a study of 3,3-dimethyl substituted acylthioureas. X ray data and quantum mechanical calculations demonstrated that the "S" conformation is the most stable both for the acylthioureas and the corresponding anions. The high regioselectivity towards S-alkylation is explained on the basis of the localization of the HOMO mainly over the sulfur atom. View Full-Text
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
SciFeed

Share & Cite This Article

MDPI and ACS Style

Sosa, M.; Piris, M.; Burton, G. 3,3-Dimethylacylthioureas: "S", "-S", "U" or "W" Conformation? Molecules 2000, 5, 445-446.

Show more citation formats Show less citations formats

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top