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Molecules 2000, 5(2), 132-152; https://doi.org/10.3390/50200132

1,3-Dipolar Cycloadditions of N-Benzyl Furfuryl Nitrones with Electron-rich Alkenes

Departamento de Quimica Organica. Facultad de Ciencias-ICMA. Universidad de Zaragoza. E-50009 Zaragoza. Aragon. Spain
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Received: 25 January 2000 / Accepted: 14 February 2000 / Published: 18 February 2000
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Abstract

The 1,3-dipolar cycloaddition reaction of N-benzyl-C-(2-furyl)nitrones with electron-rich alkenes gives preferentially trans-substituted 3,5-disubstituted isoxazolidines (endo approach). These experimental results are in good qualitative agreement with the predicted ones by semiempirical (AM1 and PM3) and ab initio (HF/3-21G) methods. View Full-Text
Keywords: Nitrones; isoxazolidines; pyrrolidines; theoretical calculations; cycloaddition Nitrones; isoxazolidines; pyrrolidines; theoretical calculations; cycloaddition
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Merino, P.; Anoro, S.; Merchan, F.L.; Tejero, T. 1,3-Dipolar Cycloadditions of N-Benzyl Furfuryl Nitrones with Electron-rich Alkenes. Molecules 2000, 5, 132-152.

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