Controlling the Redox Catalytic Activity of a Cyclic Selenide Fused to 18-Crown-6 by the Conformational Transition Induced by Coordination to an Alkali Metal Ion
Abstract
:1. Introduction
2. Results and Discussion
3. Materials and Methods
3.1. General
3.2. Synthesis of 10a,13a-trans-Decahydroselenopheno[3,4-b][1,4,7,10]tetraoxacyclododecine (1)
3.3. Synthesis of 13a,16a-trans-Dodecahydroselenopheno[3,4-b][1,4,7,10,13]pentaoxacyclopentadecine (2)
3.4. Synthesis of 16a,19a-trans-Tetradecahydroselenopheno[3,4-b][1,4,7,10,13,16]hexaoxacyclooctadecine (3)
3.5. Synthesis of 19a,22a-Trans-hexadecahydroselenopheno[3,4-b][1,4,7,10,13,16,19]heptaoxacyclohenicosine (4)
3.6. Complex Preparation
3.7. X-ray Analysis
3.8. 1H NMR Titration Study in CD3OD
3.9. Redox Assay for DHS-crown-6 (3)
3.10. Theoretical Calculation
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Iwaoka, M.; Oba, H.; Ito, T. Controlling the Redox Catalytic Activity of a Cyclic Selenide Fused to 18-Crown-6 by the Conformational Transition Induced by Coordination to an Alkali Metal Ion. Molecules 2023, 28, 3607. https://doi.org/10.3390/molecules28083607
Iwaoka M, Oba H, Ito T. Controlling the Redox Catalytic Activity of a Cyclic Selenide Fused to 18-Crown-6 by the Conformational Transition Induced by Coordination to an Alkali Metal Ion. Molecules. 2023; 28(8):3607. https://doi.org/10.3390/molecules28083607
Chicago/Turabian StyleIwaoka, Michio, Hajime Oba, and Takeru Ito. 2023. "Controlling the Redox Catalytic Activity of a Cyclic Selenide Fused to 18-Crown-6 by the Conformational Transition Induced by Coordination to an Alkali Metal Ion" Molecules 28, no. 8: 3607. https://doi.org/10.3390/molecules28083607