Mechanically Stimulated Solid-State Interaction of Platinum Tetrachloride with Sodium β-Diketonates
Abstract
:1. Introduction
2. Results
3. Experimental
3.1. Materials and Methods
3.2. Synthesis
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Sample Availability
References
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Na(hfac) | Ground Mixture, 3 h | Ground Mixture, 4 h | Pt(hfac)2 | Assignment |
---|---|---|---|---|
1673 s | 1669 m | 1672 m | 1681 w | ν(C…O) |
1656 s | 1657 m | 1650 m | ν(C…C) | |
1555 w 1533 m 1514 sh 1490 m | 1553 w 1531 m 1513 w 1494 m | 1553 w 1531 m 1493 m | 1586 m 1560 vw 1535 vw 1436 m | ν(C…O) + ν(C…C…C) |
1334 w | 1332 w | 1320 w | 1348 w | νs(C–CF3) |
1259 m 1205 m wide | 1259 m 1191 m | 1256 m 1212 m | 1257 m 1200 m | ν(C–CF3), ν(C–F), ν(C…C…C) |
1131 vs | 1127 vs | 1135 vs | 1146 vs | δ(C–H) in plane |
1087 vw | 1087 vw | 1079 w | 1102 s | |
948 vw | 948 vw | 946 w | 955 vw | ν(C…O) |
847 vw 802 m | 852 w 794 m | 852 w 792 m | 833 vw 818 m | δ as(C–CF3) |
763 vw | 763 vw | 754 w | δ s(C–CF3) | |
739 m | 739 m | 739 m | 721 m | Ring def. |
663 m | 663 m | 663 m | ||
579 m | 579 m | 580 m | 612 m |
Na(tfac) | Ground Mixture, 4 h | Pt(tfac)2 | Assignment |
---|---|---|---|
1694 vw | 1686 s, 1668 s | ν(C…O) | |
1636 s | 1611 s | 1583 s | ν(C…O) |
1517 m 1495 s | 1525 s | 1523 m | ν(C…C…C) |
1429 w | 1449 m | 1450 m | δas(CH3) |
1363 w | 1363 m | 1367 m | δs(CH3) |
1287 s 1272 s | 1287 m | 1304 s | ν(C…C) + ν(C–CH3) |
1225 w, 1217 w, 1178 m, 1135 s | 1192 s 1137 s 1090 m | 1234 s, 1188 m, 1158 s, 1142 vs | ν(C–F) + ν(C–CF3) |
1020 w | 1024 w 1001 w | 1025 w | ρr(CH3) |
994 w | 949 m | 948 w | ν(C–CH3) + ν(C…O) |
845 m | 843 w | 882 m | |
765 m | 802 m | 801 m | δ as(C–CF3), δ(C–H) out-of-plane |
727 m | 725 m | 745 m 720 m | δ s(C–CF3) |
690 w | 662 w | 694 m | Ring def. |
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Makhaev, V.D.; Petrova, L.A. Mechanically Stimulated Solid-State Interaction of Platinum Tetrachloride with Sodium β-Diketonates. Molecules 2023, 28, 3496. https://doi.org/10.3390/molecules28083496
Makhaev VD, Petrova LA. Mechanically Stimulated Solid-State Interaction of Platinum Tetrachloride with Sodium β-Diketonates. Molecules. 2023; 28(8):3496. https://doi.org/10.3390/molecules28083496
Chicago/Turabian StyleMakhaev, Victor D., and Larisa A. Petrova. 2023. "Mechanically Stimulated Solid-State Interaction of Platinum Tetrachloride with Sodium β-Diketonates" Molecules 28, no. 8: 3496. https://doi.org/10.3390/molecules28083496