Diiron Aminocarbyne Complexes with NCE− Ligands (E = O, S, Se)
Abstract
:1. Introduction
2. Results and Discussion
3. Experimental
3.1. Materials and Methods
3.2. General Procedure
3.3. General Procedure
4. X-ray Crystallography
5. Computational Details
6. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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trans-6b | |
---|---|
Formula | C16H16Fe2N2O2 |
FW | 380.01 |
T, K | 100(2) |
λ, Å | 0.71073 |
Crystal system | Monoclinic |
Space group | P21/c |
a, Å | 8.7226(2) |
b, Å | 12.4479(3) |
c, Å | 14.1827(4) |
β, ° | 107.2940(10) |
Cell Volume, Å3 | 1470.31(6) |
Z | 4 |
Dc, g∙cm−3 | 1.717 |
μ, mm−1 | 1.980 |
F(000) | 776 |
Crystal size, mm | 0.16 × 0.15 × 0.13 |
θ limits, ° | 2.222–26.996 |
Reflections collected | 23,142 |
Independent reflections | 3205 [Rin = 0.0474] |
Data/restraints/parameters | 3205/0/201 |
Goodness on fit on F2 | 1.074 |
R1 (I > 2σ(I)) | 0.0283 |
wR2 (all data) | 0.0677 |
Largest diff. peak and hole, e Å−3 | 0.562/−0.444 |
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Bresciani, G.; Zacchini, S.; Pampaloni, G.; Bortoluzzi, M.; Marchetti, F. Diiron Aminocarbyne Complexes with NCE− Ligands (E = O, S, Se). Molecules 2023, 28, 3251. https://doi.org/10.3390/molecules28073251
Bresciani G, Zacchini S, Pampaloni G, Bortoluzzi M, Marchetti F. Diiron Aminocarbyne Complexes with NCE− Ligands (E = O, S, Se). Molecules. 2023; 28(7):3251. https://doi.org/10.3390/molecules28073251
Chicago/Turabian StyleBresciani, Giulio, Stefano Zacchini, Guido Pampaloni, Marco Bortoluzzi, and Fabio Marchetti. 2023. "Diiron Aminocarbyne Complexes with NCE− Ligands (E = O, S, Se)" Molecules 28, no. 7: 3251. https://doi.org/10.3390/molecules28073251