CO2 to CO Electroreduction, Electrocatalytic H2 Evolution, and Catalytic Degradation of Organic Dyes Using a Co(II) meso-Tetraarylporphyrin †
Abstract
:1. Introduction
2. Results and Discussion
2.1. Synthesis and 1H NMR Spectroscopy
2.2. Photophysical Properties
2.3. Electrochemical Characterisation
2.4. Electrocatalytic H2 Production in the Presence of Acetic Acid (AcOH)
2.5. Electroreduction CO2 to CO
2.6. Catalytic Oxidative Degradation of Dyes
3. Experimental Section
3.1. Materials
3.2. Synthetic Procedures
3.2.1. Synthesis of the meso-Tetrakis(4-(trifluoromethyl)phenyl)porphyrin (H2TMFPP)
3.2.2. Synthesis of the meso-Tetrakis(4-(trifluoromethyl)phenyl)porphyrinato Co(II) [Co(TMFPP)]
3.3. Instrumentation
3.4. Electrochemistry
3.5. Electrocatalytic CO2 Reduction
3.6. Gas Detection
3.7. Faradaic Efficiency Calculation
3.8. Catalytic Dye Degradation
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Guergueb, M.; Loiseau, F.; Molton, F.; Nasri, H.; Klein, A. CO2 to CO Electroreduction, Electrocatalytic H2 Evolution, and Catalytic Degradation of Organic Dyes Using a Co(II) meso-Tetraarylporphyrin. Molecules 2022, 27, 1705. https://doi.org/10.3390/molecules27051705
Guergueb M, Loiseau F, Molton F, Nasri H, Klein A. CO2 to CO Electroreduction, Electrocatalytic H2 Evolution, and Catalytic Degradation of Organic Dyes Using a Co(II) meso-Tetraarylporphyrin. Molecules. 2022; 27(5):1705. https://doi.org/10.3390/molecules27051705
Chicago/Turabian StyleGuergueb, Mouhieddinne, Frédérique Loiseau, Florian Molton, Habib Nasri, and Axel Klein. 2022. "CO2 to CO Electroreduction, Electrocatalytic H2 Evolution, and Catalytic Degradation of Organic Dyes Using a Co(II) meso-Tetraarylporphyrin" Molecules 27, no. 5: 1705. https://doi.org/10.3390/molecules27051705