Synthesis and Electrochemistry of New Furylpyrazolino[60]fullerene Derivatives by Efficient Microwave Radiation
Abstract
:1. Introduction
2. Results
2.1. Synthesis
2.2. Crystal Structure
2.3. UV-Vis Spectra
2.4. Fluorescence Spectra
2.5. Electrochemistry
3. Materials and Methods
3.1. General Methods
3.2. Synthesis
3.2.1. General Synthesis Procedure of Substituted Hydrazones (2a–e)
3.2.2. General Synthesis Procedure of Cycloadducts (3a–e)
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample Availability: Samples of the synthesized compounds are available from the corresponding authors. |
Method A a | Method B b | ||||
---|---|---|---|---|---|
Entry | Product | Yield c (%) | Recovered C60 % | Yield c (%) | Recovered C60 % |
2a | 3a | 15 | 44 | 20 | 30 |
2b | 3b | 15 | 50 | 25 | 35 |
2c | 3c | 19 | 40 | 30 | 30 |
2d | 3d | 20 | 42 | 34 | 33 |
2e | 3e | 19 | 43 | 25 | 34 |
3a | −1.048 | −1.457 | −1.911 | −2.374 | 0.807 b |
3b | −1.055 | −1.451 | −1.993 (−2.106) | −2.416 (−2.581) | 0.755 b |
3c | −1.093 | −1.410 (−1.616) | −1.885 | −2.419 | 0.839 b |
3d | −1.054 | −1.432 | −1.949 | −2.336 | 0.788 b |
3e | −1.087 | −1.477 | −1.961 | −2.316 | 0.710 b |
C60 | −1.058 | −1.458 | −1.959 | −2.472 |
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Al-Matar, H.M.; BinSabt, M.H.; Shalaby, M.A. Synthesis and Electrochemistry of New Furylpyrazolino[60]fullerene Derivatives by Efficient Microwave Radiation. Molecules 2019, 24, 4435. https://doi.org/10.3390/molecules24244435
Al-Matar HM, BinSabt MH, Shalaby MA. Synthesis and Electrochemistry of New Furylpyrazolino[60]fullerene Derivatives by Efficient Microwave Radiation. Molecules. 2019; 24(24):4435. https://doi.org/10.3390/molecules24244435
Chicago/Turabian StyleAl-Matar, Hamad M., Mohammad H. BinSabt, and Mona A. Shalaby. 2019. "Synthesis and Electrochemistry of New Furylpyrazolino[60]fullerene Derivatives by Efficient Microwave Radiation" Molecules 24, no. 24: 4435. https://doi.org/10.3390/molecules24244435