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Evaluation of Efficient and Practical Methods for the Preparation of Functionalized Aliphatic Trifluoromethyl Ethers
Article

Electrophilic Trifluoromethylselenolation of Boronic Acids

1
Institute of Chemistry and Biochemistry (ICBMS-UMR CNRS 5246), Université de Lyon, Université Lyon 1, CNRS, F-69622 Lyon, France
2
CERMEP—In Vivo Imaging, Groupement Hospitalier Est, F-69677 Lyon, France
*
Author to whom correspondence should be addressed.
Academic Editor: Derek J. McPhee
Molecules 2017, 22(5), 833; https://doi.org/10.3390/molecules22050833
Received: 1 May 2017 / Revised: 13 May 2017 / Accepted: 15 May 2017 / Published: 19 May 2017
Trifluoromethylselenylated compounds are emergent compounds with interesting physicochemical properties that still suffer from a lack of efficient synthetic methods. We recently developed an efficient one-pot strategy to generate in situ CF3SeCl and use it in various reactions. Herein, we continue our study of the reactivity scope of this preformed reagent. Cross-coupling reactions with aromatic and heteroaromatic boronic acids have been investigated. The expected products have been obtained, using a stoichiometric amount of copper, with moderate yields. View Full-Text
Keywords: trifluoromethylselenolation; boronic acids; trifluoromethylselenyl chloride; fluorine; selenium trifluoromethylselenolation; boronic acids; trifluoromethylselenyl chloride; fluorine; selenium
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MDPI and ACS Style

Ghiazza, C.; Tlili, A.; Billard, T. Electrophilic Trifluoromethylselenolation of Boronic Acids. Molecules 2017, 22, 833. https://doi.org/10.3390/molecules22050833

AMA Style

Ghiazza C, Tlili A, Billard T. Electrophilic Trifluoromethylselenolation of Boronic Acids. Molecules. 2017; 22(5):833. https://doi.org/10.3390/molecules22050833

Chicago/Turabian Style

Ghiazza, Clément, Anis Tlili, and Thierry Billard. 2017. "Electrophilic Trifluoromethylselenolation of Boronic Acids" Molecules 22, no. 5: 833. https://doi.org/10.3390/molecules22050833

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