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Molecules 2014, 19(9), 12949-13009;

Chemistry of Phosphorylated Formaldehyde Derivatives. Part I

Laboratory of Organophosphorus Compounds, Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova str., 28, Moscow 119991, Russia
Received: 8 July 2014 / Revised: 8 August 2014 / Accepted: 15 August 2014 / Published: 25 August 2014
(This article belongs to the Special Issue Organophosphorus Chemistry)


The underinvestigated derivatives of unstable phosphorylated formaldehyde acetals and some of the structurally related compounds, such as thioacetals, aminonitriles, aminomethylphosphinoyl compounds, are considered. Separately considered are halogen aminals of phosphorylated formaldehyde, acetals of phosphorylated formaldehyde of H-phosphinate-type and a phosphorylated gem-diol of formaldehyde. Synthetic methods, chemical properties and examples of practical applications are given. View Full-Text
Keywords: phosphorylated acetals; -thioacetals; -aminonitriles; -aminomethylphosphinoyl compounds; -chloro(or bromo)aminals; -gem-dioles; -ketene acetale; H-phosphinate phosphorylated acetals; -thioacetals; -aminonitriles; -aminomethylphosphinoyl compounds; -chloro(or bromo)aminals; -gem-dioles; -ketene acetale; H-phosphinate

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This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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Morgalyuk, V.P. Chemistry of Phosphorylated Formaldehyde Derivatives. Part I. Molecules 2014, 19, 12949-13009.

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