Chemical Reactions Catalyzed by Metalloporphyrin-Based Metal-Organic Frameworks
Abstract
:1. Metalloporphyrins as Bioinspired Systems
1.1. Synthetic Porphyrins
1.2. Metalloporphyrins as Catalysts for Oxidation Reactions in Homogenous Phase
2. Advances in the Field of Coordination Polymers and Metal-Organic Frameworks
2.1. Strategies to Synthesize MOFs
3. MOFs with Porphyrins as Building Blocks
4. Activity of Metalloporphyrin-Based MOFs in Heterogeneous Catalysis
4.1. Oxidation Reaction
4.2. Lewis Acid Catalysis
- (i)
- Lewis acid activation: preliminary coordination of NAI to a zinc-porphyrin site withdraws the electron density from the carbonyl group, generating the negative charge (Figure 12, center).
- (ii)
- Concentration of the substrates: ZnPO-MOF cavities can concentrate the substrates and increase the reaction rate without changing the activation energy.
- (iii)
- Preferred orientation of reactants: ZnPO-MOF cavity size (Zn-Zn distance = 11.6 Å) allows a pair of 3-PC and NAI to align, providing the ideal orientation for the reaction to take place.
5. Conclusions
Acknowledgments
Conflicts of Interest
References and Notes
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Nakagaki, S.; Ferreira, G.K.B.; Ucoski, G.M.; Dias de Freitas Castro, K.A. Chemical Reactions Catalyzed by Metalloporphyrin-Based Metal-Organic Frameworks. Molecules 2013, 18, 7279-7308. https://doi.org/10.3390/molecules18067279
Nakagaki S, Ferreira GKB, Ucoski GM, Dias de Freitas Castro KA. Chemical Reactions Catalyzed by Metalloporphyrin-Based Metal-Organic Frameworks. Molecules. 2013; 18(6):7279-7308. https://doi.org/10.3390/molecules18067279
Chicago/Turabian StyleNakagaki, Shirley, Gabriel Kaetan Baio Ferreira, Geani Maria Ucoski, and Kelly Aparecida Dias de Freitas Castro. 2013. "Chemical Reactions Catalyzed by Metalloporphyrin-Based Metal-Organic Frameworks" Molecules 18, no. 6: 7279-7308. https://doi.org/10.3390/molecules18067279