Special Issue "Organophosphorus Chemistry 2018"
Deadline for manuscript submissions: 30 September 2018
Prof. Dr. György Keglevich
Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, H-1521 Budapest, Hungary
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Interests: organophosphorus chemistry (P-heterocycles, phospha -Michael reactions, Kabachnik-Fields (phospha-Mannich) reaction, C-P coupling reactions); green chemistry; MW chemistry; platinum complexes with P-ligands; synthesis of dronates; phase transfer catalysis
Organophosphorus chemistry is an important discipline within organic chemistry. Phosphorus compounds, such as phosphines, trialkyl phosphites, phosphine oxides (chalcogenides), phosphonates, phosphinates and >P(O)H species, etc., may be important starting materials or intermediates in syntheses. Let us mention the Wittig reaction and the related transformations, the Arbuzov- and the Pudovik reactions, the Kabachnik–Fields condensation, the Hirao reaction, the Mitsunobu reaction, etc. Other reactions, e.g., homogeneous catalytic transformations or C-C coupling reactions involve P-ligands in transition metal (Pt, Pd, etc.) complex catalysts. The synthesis of chiral organophosphorus compounds means a continuous challenge. Methods have been elaborated for the resolution of tertiary phosphine oxides and for stereoselective organophosphorus transformations. P-heterocyclic compounds, including aromatic and bridged derivatives, P-functionalized macrocycles, dendrimers and low coordinated P-fragments, are also of interest. An important segment of organophosphorus chemistry is the pool of biologically-active compounds that are searched and used as drugs, or as plant-protecting agents. The natural analogue of P-compounds may also be mentioned. Many new phosphine oxides, phosphinates, phosphonates and phosphoric esters have been described, which may find application on a broad scale. Phase transfer catalysis, ionic liquids and detergents also have connections to phosphorus chemistry. Green chemical aspects of organophosphorus chemistry (e.g., microwave-assisted syntheses, solvent-free accomplishments, optimizations, and atom-efficient syntheses) represent a dynamically developing field. Last, but not least, theoretical approaches and computational chemistry are also a strong sub-discipline within organophosphorus chemistry. All potential authors working in the field of phosphorus chemistry are invited to contribute, and to enrich the Special Issue “Organophosphorus Chemistry 2018”.
Prof. Dr. György Keglevich
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- organophosphorus chemistry
- phosphine chalcogenides
- phosphinic acids
- phosphonic acids
- phosphine boranes
- phosphine complexes
- homogeneous catalysis
- phase transfer catalysis
- ionic liquids
- biologically active substrates
- theoretical calculations