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Keywords = ultrafine cement (UFC)

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17 pages, 9513 KiB  
Article
Analysis of the Effect of Ultra-Fine Cement on the Microscopic Pore Structure of Cement Soil in a Peat Soil Environment
by Jing Cao, Chenhui Huang, Huafeng Sun, Yongfa Guo, Wenyun Ding and Guofeng Hua
Appl. Sci. 2023, 13(23), 12700; https://doi.org/10.3390/app132312700 - 27 Nov 2023
Cited by 1 | Viewed by 1460
Abstract
Treating peat soil foundations around Dianchi Lake and Erhai Lake in Yunnan is a complex problem in practical engineering projects. Peat soil solely reinforced with ordinary cement (OPC) does not satisfy demand. This study aims to solidify soil to achieve better mechanical properties. [...] Read more.
Treating peat soil foundations around Dianchi Lake and Erhai Lake in Yunnan is a complex problem in practical engineering projects. Peat soil solely reinforced with ordinary cement (OPC) does not satisfy demand. This study aims to solidify soil to achieve better mechanical properties. The preparation of peat soil incorporates a humic acid (HA) reagent into cohesive soil, and cement and ultra-fine cement (UFC) are mixed by stirring to prepare cement soil samples. They are then immersed in fulvic acid (FA) solution to simulate cement soil in the actual environment. X-ray diffraction (XRD), mercury intrusion porosimetry (MIP), scanning electron microscopy (SEM), and pores and cracks analysis system (PCAS) tests are used to study the impact of the UFC on the microscopic pore structure of cement soil in a peat soil environment. The unconfined compressive strength (UCS) test is used for verification. The microscopic test results indicate that incorporating UFC enhances the specimen’s micropore structure. The XRD test results show the presence of C–S–H, C–A–S–H, and C–A–H. SEM and PCAS tests show that the UFC proportion increases by between 0% and 10%, and the percentage reduction in the macropore volume is the largest, at 38.84%. When the UFC admixture is 30%, the cumulative reduction in the percentage of macropore volume reaches 71.55%. The MIP test results show that the cumulative volume greater than 10 µm in pore size decreases from 7.68% to 0.17% with an increase in the UFC proportion. The UCS test results show that the maximum strength growth of cement soil is 12.99% when the UFC admixture is 0–10%. Incorporating UFC to form a compound curing agent solves the problem of the traditional reinforcement treatment of peat soil foundation being undesirable and decreases the amount of cement. This study provides practical guidance for reducing carbon emissions in actual projects. Full article
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17 pages, 6833 KiB  
Article
Effect of Ultrafine Cement (UFC) on the Corrosion Resistance of Cement Soil in Peat Soil Environment
by Yongfa Guo, Jing Cao, Huafeng Sun, Wenyun Ding, Guofeng Hua, Wei Wei and Siyang Huang
Materials 2023, 16(16), 5520; https://doi.org/10.3390/ma16165520 - 8 Aug 2023
Cited by 1 | Viewed by 1584
Abstract
Many peat soils are distributed around plateau lakes, and the reinforcement of peat soils with high organic matter content by ordinary cement cannot meet the actual engineering requirements. In order to obtain better mechanical properties and durability of the reinforcement, this experiment prepared [...] Read more.
Many peat soils are distributed around plateau lakes, and the reinforcement of peat soils with high organic matter content by ordinary cement cannot meet the actual engineering requirements. In order to obtain better mechanical properties and durability of the reinforcement, this experiment prepared peat soil by mixing humic acid reagent into the alluvial clay soil with low organic matter content. The cement soil samples were prepared by adding cement and ultrafine cement (UFC) by stirring method; the samples were then soaked in fulvic acid solution to simulate the cement soil in the peat soil environment. Using the unconfined compressive strength (UCS) test, scanning electron microscope (SEM) test, and pores and cracks analysis system (PCAS) test, the effect of UFC content change on cement soil’s humic acid erosion resistance was explored, and the optimal UFC content range was sought. The results of the UCS test show that with an increase in immersion time, the strength curves of cement soil samples gradually increase to the peak strength and then decrease. Significant differences in the time correspond to the peak strength, and the overall presentation is two processes: the strength enhancement stage and the corrosion stage of the sample. The incorporation of UFC makes the cement soil in the peat soil environment exhibit excellent corrosion resistance, and the optimal UFC content is 10%. The results of the SEM and PCAS tests show that the microstructure of cement soil after immersion time exceeds 90 days, increases with an increase in immersion time, and its structural connectivity gradually weakens. The excellent characteristics of UFC particles, such as small particle size, narrow particle size distribution, fast hydration reaction rate, high hydration degree, and many hydration products, weakened the adverse effects of humic acid on the cement soil structure to a certain extent. Therefore, although the number of macropores increases, they are not connected. It still presents a relatively compact honeycomb overall structure, which correlates well with the UCS results. Full article
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16 pages, 6194 KiB  
Article
Effect of Ultra-Fine Cement on the Strength and Microstructure of Humic Acid Containing Cemented Soil
by Jing Cao, Fangyi Liu, Zhigang Song, Wenyun Ding, Yongfa Guo, Jianyun Li and Guoshou Liu
Sustainability 2023, 15(7), 5923; https://doi.org/10.3390/su15075923 - 29 Mar 2023
Cited by 4 | Viewed by 2079
Abstract
The peat soil in the Dianchi Lake area of Yunnan, China, is widely distributed, bringing many problems to engineering. The peat soil foundation is usually treated by the cement mixing method, and the reinforcement effect of cemented soil is mainly affected by humic [...] Read more.
The peat soil in the Dianchi Lake area of Yunnan, China, is widely distributed, bringing many problems to engineering. The peat soil foundation is usually treated by the cement mixing method, and the reinforcement effect of cemented soil is mainly affected by humic acid (HA). Ultra-fine cement (UFC) can improve cement performance and reduce cement consumption, decreasing CO2 emissions and the impact of human activities on the environment. Simulated peat soils in different environments are prepared with HA reagent and cohesive soil, reinforced by composite cement curing agent mixed with ultrafine cement (UFC). The relationship among the UFC proportion, HA reagent content, soaking time, and sample strength was studied. The unconfined compressive strength test (UCS), scanning electron microscope (SEM), and PCAS microscopic quantitative test techniques were used to explore the mechanism of the effect of UFC on the strength of HA-containing cemented soil. The increasing UFC proportion in the composite cement curing agent gradually increased HA-containing cemented soil’s strength. UFC significantly reduced the percentage of macropores in HA-containing cemented soil and made the microstructure denser. The HA-containing cemented soil’s qu increased the most when the UFC proportion increased from 0% to 10%. The solidification effect of the composite cement curing agent mixed with UFC was always stronger than that of OPC. The composite cement curing agent with a UFC proportion of 10% is practical. Cement is still an important building material in the current construction industry, and UFC provides a new method for reducing environmental impact in engineering construction. Full article
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16 pages, 8562 KiB  
Article
Effect of UFC on the Microscopic Pore Structure of Cemented Soil in Humic Acid Environment
by Jing Cao, Fangyi Liu, Siyang Huang, Hong Liu, Zhigang Song, Jianyun Li and Guoshou Liu
Sustainability 2023, 15(4), 3241; https://doi.org/10.3390/su15043241 - 10 Feb 2023
Cited by 4 | Viewed by 1892
Abstract
Peat soil is widely distributed in the Dianchi Lake area of Yunnan, and the effect of the cement deep-mixing method on peat soil foundation is mainly affected by humic acid (HA). In this paper, a composite cement curing agent is formed by adding [...] Read more.
Peat soil is widely distributed in the Dianchi Lake area of Yunnan, and the effect of the cement deep-mixing method on peat soil foundation is mainly affected by humic acid (HA). In this paper, a composite cement curing agent is formed by adding different proportions of ultra-fine cement (UFC) to ordinary Portland cement (OPC) and used to cure the HA-containing cohesive soil. Mercury intrusion porosimetry (MIP), scanning electron microscopy (SEM), and X-ray powder diffraction (XRD) are used to study the influence mechanism of UFC on the micropore structure of HA-containing cemented soil. The unconfined compressive strength test (UCS) is used to verify it. MIP, SEM, and XRD results show that UFC can significantly improve the microscopic pore structure of the samples. The hydration reaction rate of cement increases with the increase in the proportion of UFC, and the generated hydration products can fill the pores of the samples. The filling effect of hydration products on macropores is enhanced, and the pores change from fibrous filling to cemented filling. The enhanced cementation of the hydration products improved the loose and overhead structure inside the sample. Enhancing the cementation of hydration products improves the loose and overhead structure inside the sample and the integrity of cemented soil. UCS verified that the increase in the UFC proportion increases the HA-containing cemented soil strength. It achieves the purpose of reducing the amount of cement when curing peat soil foundations and supports reducing carbon emissions in practical projects. Full article
(This article belongs to the Section Air, Climate Change and Sustainability)
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15 pages, 4309 KiB  
Article
Understanding the Effect of Cementitious Grouting Pressure on Micro-Fracture Permeability for Rock Reinforcement Underground: A Lab Study
by Kai Wang, Lianguo Wang, Bo Ren and Hao Fan
Energies 2020, 13(16), 4225; https://doi.org/10.3390/en13164225 - 15 Aug 2020
Cited by 10 | Viewed by 2668
Abstract
In grouting support projects, due to the small concealment of micro-fractures, the support effect often fails to meet design requirements. The percolation effect is a common factor that causes grouting failure, and the influence of grouting pressure on the percolation effect is very [...] Read more.
In grouting support projects, due to the small concealment of micro-fractures, the support effect often fails to meet design requirements. The percolation effect is a common factor that causes grouting failure, and the influence of grouting pressure on the percolation effect is very obvious. In this article, a design of a micro-fracture grouting experimental system is presented that can realize high-pressure grouting and then uses a variety of ultrafine cements to carry out high- and low-pressure grouting tests under different fracture opening conditions, thereby obtaining the grouting pressure and accumulated grouting weight during the grouting process. The results show that a combination of the grouting pressure curve and the cumulative grouting weight curve can determine whether the ultrafine cement will have a percolation effect. Increasing the grouting pressure can reduce the critical fracture opening value and also reduce the occurrence of the percolation effect. The research results provide a theoretical basis for the high-pressure grouting of micro-fracture rock masses and offer certain guiding significance for the design of high-pressure grouting support schemes. Full article
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15 pages, 4798 KiB  
Article
Application of Poly-γ-Glutamic Acid Flocculant to Flocculation–Sedimentation Treatment of Ultrafine Cement Suspension
by Tomokazu Yanagibashi, Motoyoshi Kobayashi and Keisuke Omori
Water 2019, 11(9), 1748; https://doi.org/10.3390/w11091748 - 22 Aug 2019
Cited by 7 | Viewed by 5033
Abstract
We examined the effect of poly-γ-glutamic acid flocculant (PGAF) on the removal of ultrafine cement (UFC) particles stabilized by a poly-carboxylate co-polymer, which is a superplasticizer (SP). The flocculation–sedimentation treatment with PGAF successfully removed the SP-stabilized cement particles through the gravitational settling of [...] Read more.
We examined the effect of poly-γ-glutamic acid flocculant (PGAF) on the removal of ultrafine cement (UFC) particles stabilized by a poly-carboxylate co-polymer, which is a superplasticizer (SP). The flocculation–sedimentation treatment with PGAF successfully removed the SP-stabilized cement particles through the gravitational settling of the formed flocs. The removal efficiency reduced with the increase in the ionic strength, probably because of the shrunk form of poly-γ-glutamic acid (γ-PGA) at high ionic strengths. Increasing the mixing intensity during rapid mixing improved the removal efficiency. A series of flocculation–sedimentation experiments provided a diagram showing the relationship between ionic strengths and the addition amount of PGAF. Our results suggest that PGAF is a good candidate for the purification of cement suspension by flocculation–sedimentation, and a better removal performance can be obtained at lower ionic strengths with intense rapid mixing. From the diagram of the control charts presented in this study, we can determine the optimal addition amount of PGAF for achieving the target removal rate for cement suspension under any ionic strength. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
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