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Keywords = theory of volumetric rigidity

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18 pages, 2231 KB  
Article
Comparative DFT Study of K2AgSbBr6 and K2NaScBr6: Exploring the Role of BB Cation Substitution on Material Properties
by Abdelkebir Ejjabli, Mohamed Karouchi, Hamza Errahoui, Abdelmounaim Laassouli, Aymane El haji, Youssef Lachtioui and Omar Bajjou
Atoms 2025, 13(6), 53; https://doi.org/10.3390/atoms13060053 - 13 Jun 2025
Cited by 6 | Viewed by 1549
Abstract
The effects of cation substitution are the main emphasis of this investigation into the structural, mechanical, electronic, and optical properties of double perovskites K2AgSbBr6 and K2NaScBr6. Outwardly favorable tolerance and octahedral factors and negative formation energy [...] Read more.
The effects of cation substitution are the main emphasis of this investigation into the structural, mechanical, electronic, and optical properties of double perovskites K2AgSbBr6 and K2NaScBr6. Outwardly favorable tolerance and octahedral factors and negative formation energy confirmed structural stability and thermodynamic feasibility. Mechanical analysis showed that K2AgSbBr6 possesses greater volumetric stability and rigidity, while K2NaScBr6 exhibits greater ductility and isotropic characteristics. The electronic properties determined based on density functional theory (DFT) calculations indicate that K2AgSbBr6 has an indirect bandgap of 0.857 eV, making it suitable for applications using visible light, and K2NaScBr6 has a direct bandgap of 3.107 eV, making it ideal for UV-specific technologies. Optical analyses demonstrate complementary characteristics, particularly in terms of the dielectric function, absorption, reflectivity, energy loss function, refractive index, extinction coefficient, and optical conductivity. K2AgSbBr6 exhibits strong visible light absorptivity. Full article
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23 pages, 8147 KB  
Article
Dielectric Hybrid Optimization Model Based on Crack Damage in Semi-Rigid Base Course
by Zhiyong Huang, Guoyuan Xu, Huayang Yu, Xuetang Xiong and Bo Zang
Buildings 2024, 14(11), 3599; https://doi.org/10.3390/buildings14113599 - 13 Nov 2024
Viewed by 1174
Abstract
To accurately predict the relative permittivity of cement-stabilized base materials, a study on the dielectric mixing model for cracked base materials was conducted. Based on the electromagnetic mixing theory of multiphase composites, a comprehensive dielectric mixing model of cement-stabilized base materials was derived. [...] Read more.
To accurately predict the relative permittivity of cement-stabilized base materials, a study on the dielectric mixing model for cracked base materials was conducted. Based on the electromagnetic mixing theory of multiphase composites, a comprehensive dielectric mixing model of cement-stabilized base materials was derived. The volume ratios and relative permittivity values of the specimen constituents in different cracking states of the cement-stabilized base were determined using industrial CT and a Percometer relative permittivity meter, with comprehensive consideration given to the effects of different initial porosities and crack widths on the dielectric properties. Based on the volumetric and dielectric properties of the base material specimens in both intact and cracked states, as well as the error analysis between the predicted and measured values of the relative permittivity constant, the u-optimal solution of the dielectric mixing model for cement-stabilized base material was determined to be 1. Consequently, an optimization dielectric mixing model for semi-rigid base course materials in a cracked state was developed. The optimization model proposed is suitable for predicting the dielectric properties of cement-stabilized base material with crack widths generally greater than 3 mm during the service life of semi-rigid base course in engineering practice. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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16 pages, 7348 KB  
Article
Improving the Efficiency of the Drive of the Test Bench of Rotary Hydraulic Machines
by Alexander Rybak, Besarion Meskhi, Dmitry Rudoy, Anastasiya Olshevskaya, Yuliya Serdyukova, Svetlana Teplyakova and Alexey Pelipenko
Actuators 2024, 13(2), 63; https://doi.org/10.3390/act13020063 - 6 Feb 2024
Cited by 9 | Viewed by 3141
Abstract
Volumetric hydraulic drive systems are quite widespread in many industrial sectors. To determine the degree of reliability of hydraulic machines, it is necessary to conduct resource tests. The main requirement for such tests is the compliance of the load level with the operating [...] Read more.
Volumetric hydraulic drive systems are quite widespread in many industrial sectors. To determine the degree of reliability of hydraulic machines, it is necessary to conduct resource tests. The main requirement for such tests is the compliance of the load level with the operating mode of the hydraulic machine. Analysis of existing methods of creating such a load showed a significant drawback of bench tests—the lack of useful work. Therefore, a number of authors suggest the use of stands with a regenerative drive system. One peculiarity of the work of such stands is the possibility of returning part of the spent energy back to the test system. However, such systems are insufficiently studied and have significant drawbacks. The purpose of this work is to increase the efficiency of the regenerative drive system of the test bench of volumetric hydraulic machines of rotational action by improving the theory and methodology of its calculation and design. This article describes the principle of operation of the circuit of the regenerative drive of the test bench of rotary hydraulic machines. A model of the elastic-dissipative state of the sections of the elements of the hydro-mechanical drive system of the stand is also proposed, which allows for the calculation of the structural and energy parameters of the regenerative hydro-mechanical system. The main structural and functional parameters affecting the operational performance of the system as a whole are also identified. A “test efficiency coefficient” is proposed, which allows for evaluation of the energy efficiency of the test process. Full article
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