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Keywords = steel slag carbonations’ influencing factors

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24 pages, 2086 KiB  
Review
Comprehensive Review of Thermally Induced Self-Healing Behavior in Asphalt Mixtures and the Role of Steel Slag
by Yihong Yan, Wenbo Li, Chaochao Liu and Boyang Pan
Coatings 2025, 15(6), 668; https://doi.org/10.3390/coatings15060668 - 30 May 2025
Viewed by 711
Abstract
Asphalt pavements face escalating challenges from traffic loading, climate change, and material degradation, necessitating innovative maintenance solutions. Thermally induced self-healing technologies, leveraging the viscoelastic properties of asphalt binders, can autonomously repair microcracks through targeted thermal activation. This review explored thermally induced self-healing in [...] Read more.
Asphalt pavements face escalating challenges from traffic loading, climate change, and material degradation, necessitating innovative maintenance solutions. Thermally induced self-healing technologies, leveraging the viscoelastic properties of asphalt binders, can autonomously repair microcracks through targeted thermal activation. This review explored thermally induced self-healing in asphalt mixtures, with a focus on leveraging steel slag as a functional aggregate to enhance sustainability and durability. Two thermal-activation methods, electromagnetic induction and microwave heating, were critically analyzed, highlighting their distinct advantages in heating efficiency, depth, and uniformity. Steel slag offers dual benefits: improving mechanical interlock and skid resistance in mixtures while facilitating efficient heat generation via electromagnetic induction or microwave heating. However, challenges such as hydration-induced expansion, heterogeneous slag composition, and energy-intensive heating processes impede widespread adoption. Pretreatment methods, including natural aging, carbonation, and surface modifications, are essential to mitigate volumetric instability and optimize slag performance. Key factors influencing healing efficacy, including binder properties, operational parameters (e.g., microwave power, frequency), and environmental trade-offs, were systematically evaluated. Future research directions emphasized standardized pretreatment protocols, hybrid heating technologies for uniform temperature distribution, and smart-infrastructure integration for predictive maintenance. Full article
(This article belongs to the Special Issue Novel Cleaner Materials for Pavements)
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17 pages, 2879 KiB  
Review
A Review on the Carbonation of Steel Slag: Properties, Mechanism, and Application
by Shuping Wang, Mingda Wang, Fang Liu, Qiang Song, Yu Deng, Wenhao Ye, Jun Ni, Xinzhong Si and Chong Wang
Materials 2024, 17(9), 2066; https://doi.org/10.3390/ma17092066 - 28 Apr 2024
Cited by 18 | Viewed by 4102
Abstract
Steel slag is a by-product of the steel industry and usually contains a high amount of f-CaO and f-MgO, which will result in serious soundness problems once used as a binding material and/or aggregates. To relieve this negative effect, carbonation treatment was believed [...] Read more.
Steel slag is a by-product of the steel industry and usually contains a high amount of f-CaO and f-MgO, which will result in serious soundness problems once used as a binding material and/or aggregates. To relieve this negative effect, carbonation treatment was believed to be one of the available and reliable methods. By carbonation treatment of steel slag, the phases of f-CaO and f-MgO can be effectively transformed into CaCO3 and MgCO3, respectively. This will not only reduce the expansive risk of steel slag to improve the utilization of steel slag further but also capture and store CO2 due to the mineralization process to reduce carbon emissions. In this study, based on the physical and chemical properties of steel slag, the carbonation mechanism, factors affecting the carbonation process, and the application of carbonated steel slag were reviewed. Eventually, the research challenge was also discussed. Full article
(This article belongs to the Special Issue CO2 Mineralization of Calcium Silicates Cements)
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23 pages, 1349 KiB  
Review
Evaluation of Potential Factors Affecting Steel Slag Carbonation
by Amer Baras, Jiajie Li, Wen Ni, Zahid Hussain and Michael Hitch
Processes 2023, 11(9), 2590; https://doi.org/10.3390/pr11092590 - 29 Aug 2023
Cited by 35 | Viewed by 5611
Abstract
Steel slag is a solid waste product generated during the carbonation stage of steelmaking. It has high levels of heavy metals and substantial amounts of free calcium and magnesium oxide, making it unsuitable for use as a cement material. Furthermore, the disposal of [...] Read more.
Steel slag is a solid waste product generated during the carbonation stage of steelmaking. It has high levels of heavy metals and substantial amounts of free calcium and magnesium oxide, making it unsuitable for use as a cement material. Furthermore, the disposal of steel slag in landfills requires many resources and can seriously contaminate the surrounding environment. One method of reducing its negative environmental impact is carbonation, which involves reacting steel slag with carbon dioxide to form stable minerals. However, many parameters influence the carbonation efficiency of steelmaking slag, including temperature, time, particle size, pressure, CO2 concentration, liquid-to-solid ratio, moisture content, humidity, additives, etc. To this end, this paper comprehensively reviews the most important steel slag carbonation-influencing factors. Moreover, it compares the characteristics from two perspectives based on their causes and effects on carbonation. Finally, this article reviews earlier studies to identify the factors that affect steel slag carbonation and the potential of carbonated steel slag as a sustainable construction material. Based on previous research, it systematically examines all the elements for future work that need to be improved. Full article
(This article belongs to the Special Issue Advanced Technologies for Carbon Mitigation and Carbon Utilization)
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20 pages, 4881 KiB  
Review
Study on the Bath Smelting Reduction Reaction and Mechanism of Iron Ore: A Review
by Guilin Wang, Jianliang Zhang, Yaozu Wang, Yubo Tan, Zhen Li, Bo Zhang and Zhengjian Liu
Metals 2023, 13(4), 672; https://doi.org/10.3390/met13040672 - 29 Mar 2023
Cited by 8 | Viewed by 5107
Abstract
Against the background of low global carbonization, blast furnace ironmaking technology with coking puts huge amounts of pressure on the global steel industry to save energy and reduce emissions due to its high pollution levels and high energy consumption. Bath smelting reduction technology [...] Read more.
Against the background of low global carbonization, blast furnace ironmaking technology with coking puts huge amounts of pressure on the global steel industry to save energy and reduce emissions due to its high pollution levels and high energy consumption. Bath smelting reduction technology is globally favored and studied by metallurgists as a non-blast furnace ironmaking technology that directly reduces iron ore into liquid metal without using coke as the raw material. The smelting reduction reaction of iron ore, which is the core reaction of the process, is greatly significant to its productivity and energy saving. Therefore, this paper focuses on the behavior and mechanism of iron ore’s smelting reduction. This work focuses on three key aspects of smelting reduction, namely, the thermal decomposition characteristics of iron ore during the smelting reduction, the smelting reduction mechanism of iron-ore particles, and the smelting reduction mechanism of FeO-bearing slag. The experimental study methods, reaction mechanisms, influencing factors, and kinetic behavior of the three are highlighted. In this work, the reaction mechanism of thermal iron-ore decomposition, iron-ore particle smelting reduction, and FeO-bearing slag smelting reduction on the three reactions were observed, providing a theoretical basis for how to select and optimize raw materials for the bath smelting reduction process. Moreover, the kinetic study clarifies the limiting steps of the reactions and provides guidance for an improvement in the reaction rate. However, certain blank points in previous studies need to be further explored, such as the differences in the research results of same factor, the large variation in reaction activation energy, and the coupling mechanism and inter-relatedness of the three key aspects’ reactions with each other. Full article
(This article belongs to the Section Extractive Metallurgy)
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12 pages, 4879 KiB  
Article
Effects of Basicity and Mesh on Cr Leaching of EAF Carbon Steel Slag
by Davide Mombelli, Silvia Barella, Andrea Gruttadauria, Carlo Mapelli, Gwenn Le Saout and Eric Garcia-Diaz
Appl. Sci. 2019, 9(1), 121; https://doi.org/10.3390/app9010121 - 31 Dec 2018
Cited by 13 | Viewed by 3492
Abstract
The slag’s chromium leaching is one of the most pressing concerns in Electric Arc Furnace (EAF) carbon and stainless steels production. In recent years, many studies have aimed at understanding which properties (basicity, cooling speed) and phases (spinels, wustite, silicates) determine the Cr [...] Read more.
The slag’s chromium leaching is one of the most pressing concerns in Electric Arc Furnace (EAF) carbon and stainless steels production. In recent years, many studies have aimed at understanding which properties (basicity, cooling speed) and phases (spinels, wustite, silicates) determine the Cr leaching, defining different indices (sp-factor, cs-factor) in order to forecast the slag’s behavior compared to the leaching of this toxic metal. The literature suggests that spinel formation is usually a good way to fix Cr and prevent its leaching. However, in some conditions (high basicity, low amount of spinel-forming species) soluble Cr-bearing phases can be formed, i.e., Ca-chromite or unstable spinel. In these conditions, Cr can be leached easily, even if it is bound in a spinel structure. In this paper, the effects of basicity and impurities (Ca, Si) on the instability of Cr-spinel was investigated, with respect to slag mesh. The influence of basicity was also studied on Mg-wustite stability, which might contribute to the leaching of Cr. Different samples of carbon steel slag, suspected of forming unstable spinels, belonging to different steel grade production, were also investigated. Both granulated (4 mm) and milled (<100 μm) slag were analyzed. Scanning Electron Microscopy coupled with Energy Dispersive Spectroscopy (SEM-EDS) analyses were carried out to measure the local chemical composition of Cr-bearing phases. This data was correlated with slag basicity (by X-Ray Fluorescence: XRF), spinel fraction (by X-Ray Diffraction: XRD), and Cr leaching (by Inductively Coupled Plasma Mass Spectrometry: ICP-MS). The main results indicate that the increase of the slag basicity implies an increase of the impurity content (Ca, Si) in the spinel, also over-saturated by Cr. This aspect, coupled with spinel geometrical features, seems to justify the unexpected Cr leaching of some slag samples. Basicity does not influence the chemistry of wustite, thus excluding it as an additional Cr leaching source. Full article
(This article belongs to the Section Environmental Sciences)
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