Search Results (5)

Plasma electrolytic oxidation (PEO) is often used to improve the physical and mechanical properties of valve metals. This method allows for the formation of thicker and denser metal oxide coatings, which helps to improve physical and mechanical properties, especially the wear and corrosion resistance of the surface. The PEO process is widely used in areas such as mechanical engineering, aerospace, biomedical, and others. This review aims to summarize and explain the fundamental principles of the PEO process, with a focus on the influence of waveform types and their parameters on the properties of PEO coatings. This study found that a sinusoidal waveform promotes the generation of more stable discharges compared to a rectangular waveform, thereby enhancing the corrosion resistance of the coatings. Furthermore, it was demonstrated that using a rectangular waveform with adjustable parameters enables the production of thicker and more wear-resistant coatings. Meanwhile, the application of sawtooth and trapezoidal waveforms reduces sharp current spikes during the onset of discharges, minimizing defect formation and positively influencing the coating formation process. In addition, bipolar and unipolar modes are analyzed, and the promising future directions are discussed. Full article

Conventional plasma electrolytic oxidation treatments produce oxide coatings with micron-scale discharge pores, resulting in insulation and wear and corrosion resistance far below that expected of highly dense Al₂O₃ coatings. The introduction of cathodic polarization during the plasma electrolytic oxidation process, especially when the applied cathode-to-anode current ratio (Rpn) is greater than 1, triggers a unique plasma discharge phenomenon known as “soft sparking”. The soft spark discharge mode significantly improves the densification of the anode ceramic layer and facilitates the formation of the high-temperature α-Al₂O₃ phase within the coating. Although the soft spark discharge phenomenon has been known for a long time, the growth behavior of the coating under its discharge mode still needs to be studied and improved. In this paper, the growth behavior of the coating before and after soft spark discharge is investigated with the help of the micro-morphology, phase composition and element distribution of a homemade fixture. The results show that the ceramic layer grows mainly along the oxide–electrolyte direction before the soft spark discharge transformation; after the soft spark discharge, the ceramic layer grows along the oxide–substrate direction. It was also unexpectedly found that, under soft spark discharge, the silicon element only exists on the outside of the coating, which is caused by the large size and slow migration of SiO₃²⁻, which can only enter the ceramic layer and participate in the reaction through the discharge channel generated by the strong discharge. In addition, it was also found that the relative phase content of α-Al₂O₃ in the coating increased from 0.487 to 0.634 after 10 min of rotary spark discharge, which is an increase of 30.2% compared with that before the soft spark discharge transition. On the other hand, the relative phase content of α-Al₂O₃ in the coating decreased from 0.487 to 0.313 after 20 min of transfer spark discharge, which was a 55.6% decrease compared to that before the soft spark discharge transformation. Full article

Soft sparking during micro-arc oxidation can form a ceramic coating with high hardness and high bond strength on titanium alloy while avoiding the continuous strong micro-arc that can damage the substrate properties and the integrity of the coating. Existing studies have reported that the soft spark discharge is significantly influenced by the electrolyte anions, and the detailed mechanism of its influence remains unclear. Therefore, we considered four monolithic electrolytes, namely Na₂B₄O₇, NaF, Na₃PO₄, and Na₂SiO₃, for the bipolar pulsed micro-arc oxidation (MAO) treatment of the Ti6Al4V alloy to investigate the mechanism of the soft sparking discharge and the affections of different electrolytes on the soft sparking discharge. The results showed that soft spark discharges were observed in both Na₂SiO₃ and Na₃PO₄ electrolytes while not in Na₂B₄O₇ and NaF electrolytes. We attributed this situation to the fact that the deposition of Si and P elements in the coating changed the structure and passivation ability of the coating and affected the rate of ion transport and electron tunneling in the coating, resulting in forming a thick and dense, soft spark MAO inner layer. Additionally, the soft sparking discharge facilitated particle deposition and did not destroy the structure of the initial film layer, and also had no significant effect on the corrosion resistance. Full article

Plasma electrolytic oxidation processing is a novel promising surface modification approach for various materials. However, its large-scale application is still restricted, mainly due to the problem of high energy consumption of the plasma electrolytic oxidation processing. In order to solve this problem, a novel intelligent self-adaptive control technology based on real-time active diagnostics and on the precision adjustment of the process parameters was developed. Both the electrical characteristics of the plasma electrolytic oxidation process and the microstructure of the coating were investigated. During the plasma electrolytic oxidation process, the discharges are maintained in the soft-sparking regime and the coating exhibits a good uniformity and compactness. A total specific energy consumption of 1.8 kW h m⁻² μm⁻¹ was achieved by using such self-adaptive plasma electrolytic oxidation processing on pre-anodized 6061 aluminum alloy samples. Full article

A dense inner layer is highly valued among the surface coatings created through plasma electrolytic oxidation (PEO) treatment, because the PEO coating has been troubled by inherent porosity since its conception. To produce the favored structure, a proven technique is to prompt a soft sparking transition, which involves a sudden decrease in light and acoustic emissions, and a drop in anodic voltage under controlled current mode. Typically these phenomena occur in an electrolyte of sodium silicate and potassium hydroxide, when an Al-based sample is oxidized with an AC or DC (alternating or direct current) pulse current preset with the cathodic current exceeding the anodic counterpart. The dense inner layer feature is pronounced if a sufficient amount of oxide has been amassed on the surface before the transition begins. Tremendous efforts have been devoted to understand soft sparking at the metal–oxide–electrolyte interface. Studies on aluminum alloys reveal that the dense inner layer requires plasma softening to avoid discharge damages while maintaining a sufficient growth rate, a porous top layer to retain heat for sintering the amassed oxide, and proper timing to initiate the transition and end the surface processing after transition. Despite our understanding, efforts to replicate this structural feature in Mg- and Ti-based alloys have not been very successful. The soft sparking phenomena can be reproduced, but the acquired structures are inferior to those on aluminum alloys. An analogous quality of the dense inner layer is only achieved on Mg- and Ti-based alloys with aluminate anion in the electrolytic solution and a suitable cathodic current. These facts point out that the current soft sparking knowledge on Mg- and Ti-based alloys is insufficient. The superior inner layer on the two alloys still relies on rectification and densification of aluminum oxide. Full article