Search Results (2)

Methods for preliminary modification of the surface of structural metals with formulations based on organosilanes, including both solutions of individual organosilanes and two-component mixtures consisting of two organosilanes or an organosilane with an organic corrosion inhibitor, have been developed. As a result of this modification, a self-assembling siloxane polymeric/oligomeric nanoscale layer is formed on the metal surface. Such layers are capable of changing the physicochemical properties of the metal surface, in particular reducing the susceptibility of the metal to corrosive destruction. In this work, the mechanism of formation of organosilicon nanolayers and their effect on the electrochemical and corrosion behavior of metals have been studied in detail by a set of electrochemical methods, while laboratory studies and accelerated corrosion tests of carbon steel and zinc, modified with formulations based on organosilanes, have been carried out. The greatest inhibitory effect is demonstrated by two-component modifying formulations, namely mixtures of vinyl with aminosilane and vinylsilane with benzotriazole. The mechanism of corrosion inhibition by surface nanolayers formed upon surface modification with two-component mixtures has been considered. Full article

Reducing the risks caused by losses due to the atmospheric corrosion of metal structures has been relevant for many years and is an important scientific and technical task. Previously, for this purpose, the preliminary modification of the surface of structural metals with solutions of compositions, based on both individual organosilanes and their mixtures with amine-containing corrosion inhibitors, was proposed. Such treatment leads to the formation of self-assembled siloxane polymeric/oligomeric nanoscale layers on the metal surface, which are capable of changing the physicochemical properties of the metal surface (namely, by reducing the tendency of the metal to corrosive destruction). In this work, annual atmospheric corrosion tests of samples of steel, copper, zinc, and aluminum without protection, and samples modified with compositions based on organosilanes in an urban atmosphere, were carried out. It was established (by the gravimetric method) that the corrosion rate of unmodified (without protection) metals is as follows: steel—0.0022 mm/year; aluminum—0.0015 mm/year; copper—0.00018 mm/year; and zinc—0.00023 mm/year. Using gravimetry and optical microscopy, it was shown that the preliminary modification of metal surfaces with compositions based on organosilanes led to the inhibition of both uniform and local corrosion of metals. The corrosion rates of samples that were modified with one-component compositions decreased by almost two times. The maximum inhibitory effect for the studied systems was demonstrated by mixed binary modifying compositions: mixtures of vinyl- and aminosilane, vinylsilane, and benzotriazole. The corrosion rate decreased for all the studied metals. The minimum effect was observed on zinc (2.5 times) and the maximum inhibition of the corrosion rate was obtained on copper (5.1 times). The mechanism of corrosion inhibition by layers formed as a result of surface modification with two-component mixtures was considered. Full article