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Keywords = salt-fog exposition

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16 pages, 3528 KB  
Article
On the Response to Aging of OPEFB/Acrylic Composites: A Fungal Degradation Perspective
by Vladimir Valle, Alex Darío Aguilar, Paola Yánez, Cristina E. Almeida-Naranjo, Francisco Cadena, Jerónimo Kreiker and Belén Raggiotti
Polymers 2023, 15(3), 704; https://doi.org/10.3390/polym15030704 - 30 Jan 2023
Cited by 3 | Viewed by 2591
Abstract
Biological agents and their metabolic activity produce significant changes over the microstructure and properties of composites reinforced with natural fibers. In the present investigation, oil palm empty fruit bunch (OPEFB) fiber-reinforced acrylic thermoplastic composites were elaborated at three processing temperatures and subjected to [...] Read more.
Biological agents and their metabolic activity produce significant changes over the microstructure and properties of composites reinforced with natural fibers. In the present investigation, oil palm empty fruit bunch (OPEFB) fiber-reinforced acrylic thermoplastic composites were elaborated at three processing temperatures and subjected to water immersion, Prohesion cycle, and continuous salt-fog aging testing. After exposition, microbiological identification was accomplished in terms of fungal colonization. The characterization was complemented by weight loss, mechanical, infrared, and thermogravimetric analysis, as well as scanning electron microscopy. As a result of aging, fungal colonization was observed exclusively after continuous salt fog treatment, particularly by different species of Aspergillus spp. genus. Furthermore, salt spray promoted filamentous fungi growth producing hydrolyzing enzymes capable of degrading the cell walls of OPEFB fibers. In parallel, these fibers swelled due to humidity, which accelerated fungal growth, increased stress, and caused micro-cracks on the surface of composites. This produced the fragility of the composites, increasing Young’s modulus, and decreasing both elongation at break and toughness. The infrared spectra showed changes in the intensity and appearance of bands associated with functional groups. Thermogravimetric results confirmed fungal action as the main cause of the deterioration. Full article
(This article belongs to the Special Issue Sustainable Polymeric Composites: Fabrication and Application)
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17 pages, 3257 KB  
Article
Effect of Glass Fiber Hybridization on the Durability in Salt-Fog Environment of Pinned Flax Composites
by Vincenzo Fiore and Luigi Calabrese
Polymers 2021, 13(23), 4201; https://doi.org/10.3390/polym13234201 - 30 Nov 2021
Cited by 8 | Viewed by 2836
Abstract
The aim of the present paper is to evaluate the effect of the hybridization with external layers of glass fibers on the durability of flax fiber reinforced composites in severe aging conditions. To this scope, full glass, full flax and hybrid glass–flax pinned [...] Read more.
The aim of the present paper is to evaluate the effect of the hybridization with external layers of glass fibers on the durability of flax fiber reinforced composites in severe aging conditions. To this scope, full glass, full flax and hybrid glass–flax pinned laminates were exposed to a salt-fog environment for up to 60 days. Double-lap pinned joint tests were performed to assess the pin-hole joints performances at varying the laminate stacking sequence. In order to better discriminate the relationship between the mechanical behavior and the fracture mechanisms of joints at increasing the aging time, different geometries (i.e., by varying both the hole diameter D and the free edge distance from the center of the hole E) were investigated after 0 (i.e., unaged samples), 30 and 60 days of salt-fog exposition. It was shown that the hybridization positively affects the mechanical performance as well as the stability of pinned composites: i.e., improvements in both strength and durability against the salt-fog environment were evidenced. Indeed, the hybrid laminate exhibited a reduction in the bearing strength of about 20% after 60 days of aging, despite to full flax laminate, for which a total reduction in the bearing strength of 29% was observed. Finally, a simplified joint failure map was assessed, which clusters the main failure mechanisms observed for pinned composites at varying aging conditions, thus assisting the joining design of flax–glass hybrid laminates. Full article
(This article belongs to the Special Issue Natural Fibres and their Composites II)
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18 pages, 4568 KB  
Article
Dynamic Mechanical Behavior Analysis of Flax/Jute Fiber-Reinforced Composites under Salt-Fog Spray Environment
by Vincenzo Fiore, Carmelo Sanfilippo and Luigi Calabrese
Polymers 2020, 12(3), 716; https://doi.org/10.3390/polym12030716 - 24 Mar 2020
Cited by 43 | Viewed by 5116
Abstract
Over the last decades, natural fiber-reinforced polymer composites (NFRPs) gained great attention in several engineering fields thanks to the reduction of the environmental impact and the end-of-life cost disposal. Unfortunately, the use of NFRPs is limited, mainly due to their weak resistance against [...] Read more.
Over the last decades, natural fiber-reinforced polymer composites (NFRPs) gained great attention in several engineering fields thanks to the reduction of the environmental impact and the end-of-life cost disposal. Unfortunately, the use of NFRPs is limited, mainly due to their weak resistance against humid environments. Since limited literature is available about the evolution of the dynamic mechanical response of NFRPs under aggressive environments, this paper aims to investigate the damping properties of flax, jute and flax/jute epoxy composites exposed to salt-fog up to 60 days. Furthermore, sodium bicarbonate fiber treatment was performed to improve the composites’ durability. The effectiveness of treatment was evidenced for full flax-reinforced composites, whereas no beneficial effect was found for jute composites. Moreover, treated hybrid laminates having outer laminae reinforced with flax showed better damping behavior than their hybrid counterparts during the whole aging campaign. Full article
(This article belongs to the Special Issue Advances in Braided Polymer Composites)
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14 pages, 7053 KB  
Article
Pinned Hybrid Glass-Flax Composite Laminates Aged in Salt-Fog Environment: Mechanical Durability
by Luigi Calabrese, Vincenzo Fiore, Paolo Bruzzaniti, Tommaso Scalici and Antonino Valenza
Polymers 2020, 12(1), 40; https://doi.org/10.3390/polym12010040 - 26 Dec 2019
Cited by 24 | Viewed by 4755
Abstract
The aim of the present paper is to study the mechanical performance evolution of pinned hybrid glass-flax composite laminates under environment aging conditions. Hybrid glass-flax fibers/epoxy pinned laminates were exposed to salt-spray fog environmental conditions up to 60 days. With the purpose of [...] Read more.
The aim of the present paper is to study the mechanical performance evolution of pinned hybrid glass-flax composite laminates under environment aging conditions. Hybrid glass-flax fibers/epoxy pinned laminates were exposed to salt-spray fog environmental conditions up to 60 days. With the purpose of assessing the relationship between mechanical performances and failure mechanisms at increasing aging time, single lap joints at varying joint geometry (i.e., hole diameter D and hole distance E from free edge) were characterized after 0 days (i.e., unaged samples), 30 days, and 60 days of salt-fog exposition. Based on this approach, the property–structure relationship of the composite laminates was assessed on these critical environmental conditions. In particular, a reduction of failure strength for long-aging-time-aged samples was observed in the range 20–30% compared to unaged one. Due to the natural fiber degradation in a salt-fog environment, premature catastrophic fractures mode due to shear-out and net-tension were found, related to reduced joint fracture strength. This behavior identifies that this type of joint requires a careful design in order to guarantee an effective mechanical stability of the composite hybrid joint under long-term operating conditions in an aggressive environment. Full article
(This article belongs to the Collection Reinforced Polymer Composites)
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