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Keywords = pulse microcalorimetry

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Article
Pulse Microcalorimetry Study of Methane Dry Reforming Reaction on Ni/Ceria-Zirconia Catalyst
by Mikhail N. Simonov, Vladimir A. Rogov, Marina Yu. Smirnova and Vladislav A. Sadykov
Catalysts 2017, 7(9), 268; https://doi.org/10.3390/catal7090268 - 12 Sep 2017
Cited by 15 | Viewed by 6648
Abstract
For Ni/CeZrO catalyst prepared in supercritical isopropanol main features of methane dry reforming reaction mechanism were studied by the pulse microcalorimetric technique. The reaction scheme is described by a step-wise redox mechanism with independent stages of CH4 transformation on Ni/support interface producing [...] Read more.
For Ni/CeZrO catalyst prepared in supercritical isopropanol main features of methane dry reforming reaction mechanism were studied by the pulse microcalorimetric technique. The reaction scheme is described by a step-wise redox mechanism with independent stages of CH4 transformation on Ni/support interface producing syngas with participation of support oxygen bridging species (the rate-limiting stage) and fast reoxidation of support sites by CO2 yielding CO regenerating reactive oxygen species. Full article
(This article belongs to the Special Issue Conversion of CO2 into CO Using Heterogeneous Catalysis)
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