Search Results (8)

In previous research, many scientists and researchers have carried out related studies about the spontaneous combustion of coal at both the micro and the macro scales. However, the macroscale study of coal clusters and piles cannot reveal the nature of oxidation and combustion, and the mesoscale study of coal molecule and functional groups cannot be directly applied to engineering practice. According to our literature survey, coal is a porous medium and its spontaneous combustion is a multi-scale process. Thus, the mesoscale study of coal’s spontaneous combustion is essential. In this manuscript, the mesoscale of the coal body (such as pore size, pore volume, and specific surface area), and the meso-scale structural morphological characteristics of the coal surface are finely analyzed and characterized. On this basis, the meso-scale structure of pores and fractures are digitally reconstructed. Furthermore, velocity and pressure distributions of the flow field in the pores of the scan plane are outlined and described by numerical simulation. The results indicate that, because of the pore structure characteristics and fluid viscosity, not all fluids in the pores demonstrate flow. This conclusion well explains the source of CO gas in methane extraction pipes, which is one of the main index/indicator gases of the spontaneous combustion of coal. Full article

In order to study the gas migration in gas-bearing coal, and reasonably arrange gas drainage boreholes to improve the efficiency of gas drainage, a gas-solid coupling model is established based on the pore-fracture dual medium porous model. The solid deformation of coal body, gas seepage and diffusion, and gas adsorption and desorption are considered in this model. The COMSOL software is used to simulate the gas change in the coal matrix and coal fracture under single borehole extraction. We analyze the effective extraction range and study the migration mechanism of gas between coal fracture and borehole, coal matrix and coal fracture, and coal matrix. The effective extraction area of multi-borehole negative pressure gas extraction varies with extraction time and borehole spacing. At 140 d, the effective extraction radius is r = 1.3 m, and the spacing of boreholes is $\frac{2\sqrt{3}}{3}\mathrm{r}=1.5\mathrm{m},2\mathrm{r}=2.6\mathrm{m},4\mathrm{m},5\mathrm{m},\mathrm{and}6\mathrm{m}$, respectively. The influence of the equilateral triangle shape of three boreholes on the gas extraction effect is studied. The simulation results show that when three boreholes are extracted for 140 days under different borehole spacing, different gas extraction effects will be affected by a superposition effect. Considering the change in gas pressure, the effect of gas extraction in the effective extraction area, and the safety and cost performance of gas extraction, it is concluded that the optimal hole spacing is 5 m around 140 d. This study aims to provide reference for underground gas drilling layout and reasonable hole spacing. Full article

Exploring the evolution characteristics of gas seepage between boreholes during the drainage process is critical for the borehole’s layout and high-efficiency gas drainage. Based on the dual-porous medium assumption and considering the effect of stress redistribution on coal seam gas seepage characteristics, a coal seam gas seepage model with a three-dimensional roadway and borehole crossing structure has been established and numerically calculated, concluding that the coal seam is between the drainage boreholes. The temporal and spatial evolution characteristics of gas pressure and permeability help elucidate the gas seepage law of the nearly flat coal seam associated with the deep soft rock roadway and borehole intersection model. The results indicate that: (1) The roadway excavation results in localized stress in some areas of the surrounding rock, reducing the strength of the coal body, increasing the expansion stress, and increasing the adsorption of gas by the coal body. (2) Along the direction of the coal seam, the permeability decreases initially and then increases. The gas pressure in the coal seam area in the middle of the borehole is higher than the pressure in the coal seam around the borehole, and the expansion stress and deformation increase, reducing the permeability of the coal body; when near the next borehole, the greater the negative pressure, the faster the desorption of the gas attracts the matrix shrinkage effect and causes the coal seam permeability rate to keep increasing. (3) The improvement of gas drainage with the overlapping arrangement of two boreholes firstly increases and then decreases as time goes on. (4) When the field test results and numerical simulation of the effective area of gas extraction are compared, the effectiveness of the model is verified. Taking the change of the porosity and the permeability into the model, it is able to calculate the radius of gas drainage more accurately. Full article

The fly ash from powerplants used for coal mine end backfilling can effectively reduce the impact of ground fly ash accumulation on the environment. However, due to the long-term action of the overlying strata and groundwater, when the backfilling body is broken, heavy metals will also be leached, thus having an impact on the groundwater. Therefore, in this paper, the eluviation and leaching of elements from a broken fly-ash-based porous geopolymer is studied. The fly-ash-based geopolymer material was prepared to perform a dynamic eluviation and static leaching test, and it was found that the amount of Cu and Zn in the leachate was less abundant, whereas Pb was more abundant, but far less than the limit of the Class III groundwater quality standard. An acidic environment and a smaller solid–liquid ratio can promote the leaching of Cu and Zn, while the leaching of Pb is basically unaffected by the pH value. Moreover, the amount of Cu, Zn, and Pb in the lixivium increased with the increase in leaching time, and the amount of Cu and Zn in the lixivium was still low after 150 h of leaching, whereas the amount of Pb was high, approaching the limit value of the Class III groundwater quality standard, showing a tendency to increase after 100 h of leaching. A leaching orthogonal experiment was designed, and the results showed that the main order of each factor affecting the leaching of heavy metals from the fly-ash-based geopolymer was grain size > pH > solid–liquid ratio; thus, the leaching of heavy metals from fly-ash-based geopolymer can be controlled, which is significant with respect to the extensive use of fly-ash materials underground. Full article

This paper aims to study the porous structure and the mechanical properties of fly-ash-based light-weighted porous geopolymer (FBLPG), exploring the feasibility of using it in roof-adaptive end filling technology based on its in-situ foaming characteristics and plastic yielding performance. A porous structure model of FBLPG during both the slurry and solid period was established to study their influence factor. In addition, this study also built a planar structure model in the shape of a honeycomb with bore walls, proving that the bore walls possess the characteristics of isotropic force. FBLPG shows a peculiar plastic yielding performance in the experiment where its stress stays stable with the gradual increase of the deformation, which can guarantee the stability of a filling body under the cycled load from the roof. At the same time, the in-situ foaming process combined with the unique filling technique can make the FBLPG filling body fully in contact with the irregular roof. This roof-adaptive end filling technology makes it a successful application in plugging the 1305 working face, which avoids problems of the low tight-connection ratio and secondary air-leakage channel resulted from the traditional filling technology, effectively improving coal production in terms of safety and high efficiency. Full article

Water content is an important factor in the deformation-destruction process of coal bodies. To analyze the influence of water on the creep acoustic emission (AE) characteristics of coal rock surrounding a borehole, we conducted graded loading creep AE tests of single-hole specimens with different water contents (0%, 4%, 8% and water-saturation) under uniaxial loading. The findings include the following: the water content affects the creep mechanical properties of the coal body around a borehole. The creep transient strain and steady-state strain increased exponentially with rising water content; the saturated specimen showed the highest increase, reaching 44.5% and 28.6%, respectively. The specimen water content affected the cumulative ringing count (CRC) and the axial strain during creep. The axial strain increased with rising water content, the CRC increased linearly with rising axial strain. The higher the water content, the greater the CRC rise. At different stress levels, the CRC in the 4%, 8% and saturated water content specimens changed by 43%, 53% and 74%, respectively. The AE ringing rate showed a pattern of grow–decline–stabilize at each creep stage. The AEs decreased significantly with the rising water content and the creep curve lagged behind the AE data. This paper provides guidelines for gas extraction, borehole maintenance and AE detection. Full article

Fly ash is an aluminosilicate and the major by-product from coal combustion in power stations; its increasing volumes are major economic and environmental concerns, particularly since it is one of the largest mineral resources based on current estimates. Mullite (3Al₂O₃·2SiO₂) is the only stable phase in the Al₂O₃-SiO₂ system and is used in numerous applications owing to its high-temperature chemical and mechanical stabilities. Hence, fly ash offers a potential economical resource for mullite fabrication, which is confirmed by a review of the current literature. This review details the methodologies to utilise fly ash with different additives to fabricate what are described as porous interconnected mullite skeletons or dense mullite bodies of approximately stoichiometric compositions. However, studies of pure fly ash examined only high-Al₂O₃ forms and none of these works reported long-term, high-temperature, firing shrinkage data for these mullite bodies. In the present work, high-SiO₂ fly ashes were used to fabricate percolated mullite, which is demonstrated by the absence of firing shrinkage upon long-term high-temperature soaking. The major glass component of the fly ash provides viscosities suitably high for shape retention but low enough for ionic diffusion and the minor mullite component provides the nucleating agent to grow mullite needles into a direct-bonded, single-crystal, continuous, needle network that prevents high-temperature deformation and isolates the residual glass in the triple points. These attributes confer outstanding long-term dimensional stability at temperatures exceeding 1500 °C, which is unprecedented for mullite-based compositions. Full article

The production of porcelain stoneware has experienced a considerable increase. Therefore, it was necessary to undertake an investigation that would allow knowing the mineralogical evolution that porcelain stoneware undergoes during the firing process, as well as establishing the influence of the formation of mullite and other mineral or vitreous phases and their quantification. The firing transformations of mine spoils associated with mined coal in the Utrillas-Escucha-Estercuel and Ariño-Andorra areas are studied in this paper. The mineralogical composition of the bulk mine spoils is kaolinite, illite, chlorite, and smectites (in traces), with quartz and feldspar, and minor hematite, calcite, and dolomite. The main objective is to understand the generation of high-temperature mineral phases after firing, and their quantification. The formation of mullite and other high-temperature phases are studied from samples that include variable proportions of illite. Samples with a high content of illite generate mullite at 995 °C. Cristobalite was not detected as a high-temperature phase. Mullite is the most abundant mineral. The hercynite content is higher at low temperatures (995 °C), and hematite content is higher at 1150 °C. The vitreous phase represents about 50% of fired bodies. Despite observing a porous microstructure, the non-porous areas are well sintered. Full article