Search Results (6)

The search for new materials for bone regenerative purposes is still ongoing. Therefore, we present a series of newly constructed composites based on β tricalcium phosphate (βTCP) and poly(3-hydroxybutyrate) bacteria-derived biopolymer (P(3HB)) in the form of 3D scaffolds with different pore sizes. To improve the polymer attachment to the βTCP surface, the etching of ceramic sinters, using citric acid, was applied. As expected, pre-treatment led to the increase in surface roughness and the creation of micropores facilitating polymer adhesion. In this way, the durability and compressive strength of the ceramic–polymer scaffolds were enhanced. It was confirmed that P(3HB) degrades to 3-hydroxybutyric acid, which broadens applications of developed materials in bone tissue engineering as this compound can potentially nourish surrounding tissues and reduce osteoporosis. Moreover, to the best of our knowledge, it is one of the first studies where the impact of βTCP/P(3HB) scaffolds on mesenchymal stem cells (MSCs), cultured in lowered (5%) oxygen concentration, was assessed. It was decided to use a 5% oxygen concentration in the culture to mimic the conditions that would be found in damaged bone in a living organism during regeneration. Scaffolds enabled cell migration and sufficient flow of the culture medium, ensuring high cell viability. Furthermore, in composites with etched βTCP, the MSCs adhesion was facilitated by hydrophilic ceramic protrusions which reduced hydrophobicity. The developed materials are potential candidates for bone tissue regeneration. Nevertheless, to confirm this hypothesis, in vivo studies should be performed. Full article

Dry pet food, made of fresh meats and especially meat meals, represents one of the main types of complete food available on the market by virtue of its practicality and long shelf life. The kibble production process includes mixed thermal and mechanical treatments that help to improve the palatability and durability of the final product but may have undesirable effects on nutrient bioavailability and digestibility. An analysis of the protein and lipid content of different dry pet food formulations, together with an in vitro digestibility analysis, can reveal which formulation can provide a more nourishing diet for pets. In this study, a quantitative and qualitative analysis was performed on three different formulations of chicken-based dry pet food, consisting of fresh meats, meat meals, or a mix of these two. The soluble protein concentration was determined by the Bradford assay, while the crude protein content was assessed through the Kjeldahl method. Quadrupole time-of-flight liquid chromatography/mass spectrometry (Q-TOF LC/MS) was used to analyze the amino acid (AA) and lipid compositions. Finally, a gastric and small intestinal digestion simulation was used to determine the in vitro digestibility. The results show that dry pet food consisting only of chicken fresh meats has the highest content of soluble protein; it also contains more Essential AAs, Branched-Chain AAs, and Taurine, as well as a greater quantity of monounsaturated and polyunsaturated fatty acids. In addition, its in vitro digestibility was the highest, exceeding 90% of its dry weight, in agreement with the soluble protein content. These findings thus make the fresh-meat-based formulation a preferable choice as dry pet food. Full article

One of the main problems faced in coastal management is the loss or destruction of beaches due to erosion. A considerable diversity of factors is involved in coastal erosion, which makes it a complex system to study. The quality of the material that constitutes the beach, as well as the choice of appropriate materials for its nourishment are two of the main ones. Therefore, to make future nourishment projects more sustainable and durable, this work proposes a sediment quality classification based on the physical properties and wear process obtained through laboratory tests. The study of these variables, using principal component analysis, discriminant analysis and ANOVA, has divided the quality of 70 samples into three main groups. A Sediment Quality Classification Index (SQCI) is proposed, which categorizes the quality of the material into poor, regular or good, providing the coastal engineer with a simple tool to ensure more sustainable beach nourishments. Full article

Since 2011, beach nourishment has become the preferred solution for mitigating coastal erosion along the Mediterranean coast of Israel, as it is considered “soft” and environmentally friendly. However, using fine sand for nourishment in Israel without supporting measures is problematic due to the high wave energy and strong longshore currents in the littoral zone that tend to drift the sand away. This would require ongoing, multiyear, costly, and never-ending maintenance. In the present study, we analyzed sand and pebble alternatives for nourishment of the eroded beach in front of Tel Ashkelon, an important coastal archaeological site in southern Israel that suffers from severe erosion. Based on Pranzini et al. (2018), we analyzed the alternatives, evaluated their cost and efficiency, and assessed their potential environmental impacts. The study concluded that for protecting the southern part of Tel Ashkelon beach, pebble nourishment is the optimal solution, mainly regarding durability and cost. Using this material for nourishment will better absorb the storm wave impact and protect the foot of the archaeological Tel from erosion, and require lower maintenance cost than using finer sand nourishment. Full article

Phosphate glasses have potentially interesting properties that can be used in various applications. Recently, different studies are focusing on their dissolution behaviours that can be modified to suit some environmental applications, such as controlled-release fertilisers. In this work, magnesium had been suggested to improve the glass durability of 3P₂O₅-2K₂O-(1 − x)CaO-xMgO glasses (0 ≤ x ≤ 1). Indeed, its effect on glass structure, thermal properties and most important dissolution behaviours were studied, in order to evaluate their suitability of being used as controlled-release fertilisers. Various compositions in which calcium was partially replaced by magnesium were prepared by melting at 800 °C. The samples were characterised by differential scanning calorimetry, density measurements, X-Ray diffraction, FTIR spectroscopy and Raman spectroscopy. The dissolution behaviours were investigated using inductively coupled plasma optical emission spectrometry ICP-OES, pH measurements and SEM. Substitution of calcium by magnesium reduced the glass density, owing to the lower atomic weight of magnesium compared to calcium, and caused an increase in glass transition and crystallisation temperatures. Magnesium substitution significantly improved the chemical durability of the glasses due to more covalent Mg–O bond than the Ca–O bond. This study demonstrated that 3P₂O₅-2K₂O-0.3CaO-0.7MgO (x = 0.7) had a dissolution profile adequate to the criteria of controlled-release fertilisers and could be used to nourish the plants with phosphorus, potassium, calcium and magnesium. Full article

Beach nourishment along the Mediterranean coast of Israel represents a new approach to mitigate coastal erosion by adding suitable sand to threatened beaches. This ‘soft’ solution has become more environmentally and economically acceptable than traditional ‘hard’ solutions, such as seawalls, revetments, detached breakwaters and groins. Beach nourishment projects have been implemented on the Israeli coast north of Ashdod Port (2011), north of Ashkelon Marina (2015) and in the south of Haifa Bay (2016–2017). The performance of these projects was analyzed and compared with nourishment projects along the Mediterranean beaches of Italy, France and Spain. Despite a lack of detailed documentation on most of the European nourishment projects, they proved more durable than the Israeli projects, which were compromised when the imported sand eventually washed offshore. Key factor for the Israeli projects’ failure include the unsuitable morphology of the beaches; insufficient unit sand volume (m³/m—volume of nourished sand per meter of the beach length); and imported sand that was too fine versus native sand. The unique physical conditions of the Israeli coast specifically, its open shelf and straight coastline subject to relatively high waves with a very long fetch—also contributed to the poor durability of the nourishment. To improve durability on future projects: imported grain size should be at least 1.5–2.0 times the native sand; unit sand volume should be 400–500 m³/m; and supporting measures should be utilized as appropriate. Full article