Search Results (3)

Solid oxide fuel cell (SOFC) systems often employ metallic cathode air pre-heaters (CAPHs), frequently made from alloys with high chromium (Cr) content, to recover thermal energy from exhaust gases and pre-heat incoming air and fuel. Cr evaporation from metallic CAPHs can poison SOFC cathodes, reducing their durability. To mitigate this, we investigated controlled pre-oxidation of a FeCrAl alloy (alloy 318) to form a protective alumina scale by self-growing, assessing its impact on and oxidation resistance and Cr retention capability for CAPH applications. The effects of pre-oxidation were investigated across a temperature range of 800 to 1100 °C and dwelling times of 0.5 to 4 h. The formed oxide scales were characterised using gravimetry in combination with advanced analytic techniques, such as SEM/EDX, STEM/EDX, TEM, and XRD. Subsequently, the pre-oxidised FeCrAl alloys were characterised with respect to the oxidation rate and Cr₂O₃ evaporation in a tubular furnace at 850 °C, with 6.0 L/min air flow and 3 vol% H₂O to simulate the SOFC cathode environment. TEM analysis confirmed that the FeCrAl alloys formed alumina scales with 10 nm and 34 nm thickness after 1 h of pre-oxidation at 900 and 1100 °C, respectively. The corrosion and Cr₂O₃ evaporation rates of the FeCrAl alloy at 850 °C in humidified air were shown to be dramatically decreased by pre-oxidation. It was found that the mechanisms of oxidation and Cr₂O₃ evaporation were found to be controlled by the formation of different alumina phases during the pre-oxidation. Measurements of Cr₂O₃ evaporation and weight gain revealed that the alloy 318 pre-treated at 1100 °C for 1 h will form an α-Al₂O₃ scale, leading to a 98% reduction of the oxidation rate and 90% reduction of Cr₂O₃ evaporation compared to the non-oxidised alloy 318 under simulated SOFC cathode conditions. Full article

In this paper, a novel tubular solar air heater is introduced. In this air heater, the hot boundary layer is drawn into the absorber tube and can provide thermal energy at moderate temperatures. Several different cases were simulated and a correlation was proposed to predict the collector’s effectiveness as a function Rayleigh number and Reynolds number. An equation was derived to find the effectiveness of this collector. Finally, a real case was studied with non-uniform solar flux distribution, as well as radiation heat loss. Good agreement was found between the results and those derived by the proposed analytical method. For different suction values, the first-law and the second-law efficiencies were calculated. Based on the exergy analysis, exergy destruction in absorption is the dominant factor that is unavoidable in low-temperature collectors. It was shown that there is an optimum suction value at which the second-law efficiency is maximized. At the optimum point, temperature rise can reach 54 K, which is hardly possible with a flat plate collector. Based on the exergy analysis, the relation between tube wall temperature and air outlet temperature in their dimensionless forms at the optimum working condition was derived, and it was shown that effectiveness at the optimum working condition is around 0.5. This means that the air temperature rise shall be half of the temperature difference between collector wall and the ambient temperatures. A high outlet temperature besides the low cost of construction and maintenance are the main advantages of this air heater. With such a high temperature rise, this type of collector can increase the use of solar energy in domestic applications. Full article

In the current context of environmental deterioration and rising energy costs, systems based on Stirling engines are interesting not only because of their proven efficiency and very low noise level, but also because of their ability to use renewable energies. Micro-CHP units based on Stirling engines fuelled by both solar energy and biomass can reduce CO₂ emissions on a household scale, but the second option avoids problems usually related to the intermittency of solar energy. This paper describes the geometry and experimental characterisation of a new non-tubular heater design that is potentially interesting for biomass applications, and its analysis by means of a CFD model. The CFD model provides valuable information, under engine operating conditions, on the temperature distributions in the walls and the working gas, as well as the pressure and velocity of the gas particles, which are operating variables that are almost impossible to measure in practice. The new heater can be coupled to the Stirling engine of a previously developed micro-CHP unit for solar energy conversion, which has another non-tubular heater. The heat transfer rates achieved with both non-tubular heaters are compared with each other and with the values of the SOLO V160 engine heater, which consists of a tube bundle. The results show that the micro-CHP Stirling unit would develop more indicated power with the biomass heater than with the solar heater, providing information for future improvements of the indicated efficiency. Full article