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Keywords = nickel (Ni)-PTFE plating

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31 pages, 21161 KiB  
Article
Ni-B-PTFE Nanocomposite Co-Deposition on the Surface of 2A12 Aluminum Alloy
by Shunqi Mei, Zekui Hu, Jinyu Yang, Jia Chen, Quan Zheng, Burial Lygdenov and Guryev Alexey
Materials 2024, 17(13), 3294; https://doi.org/10.3390/ma17133294 - 3 Jul 2024
Cited by 5 | Viewed by 1631
Abstract
The spinning cup, a crucial component of textile equipment, relies heavily on 2A12 aluminum alloy as its primary raw material. Commonly, electroplating and chemical nickel–phosphorus (Ni-P) plating are employed to improve the surface characteristics of the object. Nevertheless, due to the growing expectations [...] Read more.
The spinning cup, a crucial component of textile equipment, relies heavily on 2A12 aluminum alloy as its primary raw material. Commonly, electroplating and chemical nickel–phosphorus (Ni-P) plating are employed to improve the surface characteristics of the object. Nevertheless, due to the growing expectations for the performance of aluminum alloys, the hardness and wear resistance of Ni-P coatings are no longer sufficient to fulfill industry standards. This study primarily focuses on the synthesis of Ni-B-PTFE nanocomposite chemical plating and its effectiveness when applied to the surface of 2A12 aluminum alloy. We examine the impact of the composition of the plating solution, process parameters, and various other factors on the pace at which the coating is deposited, the hardness of the surface, and other indicators of the coating. The research findings indicate that the composite co-deposited coating achieves its optimal surface morphology when the following conditions are met: a nickel chloride concentration of 30 g/L, an ethylenediamine concentration of 70 mL, a sodium borohydride concentration of 0.6 g/L, a sodium hydroxide concentration of 90 g/L, a lead nitrate concentration of 30 mL, a pH value of 12, a temperature of 90 °C, and a PTFE concentration of 10 mL/L. The coating exhibits consistency, density, a smooth surface, and an absence of noticeable pores or fissures. The composite co-deposited coating exhibits a surface hardness of 1109 HV0.1, which significantly surpasses the substrate’s hardness of 232.38 HV0.1. The Ni-B-PTFE composite coating exhibits an average friction coefficient of around 0.12. It has a scratch width of 855.18 μm and a wear mass of 0.05 mg. This coating demonstrates superior wear resistance when compared to Ni-B coatings. The Ni-B-PTFE composite coating specimen exhibits a self-corrosion potential of −6.195 V and a corrosion current density of 7.81 × 10−7 A/cm2, which is the lowest recorded. This enhances its corrosion resistance compared to Ni-B coatings. Full article
(This article belongs to the Section Advanced Nanomaterials and Nanotechnology)
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10 pages, 2632 KiB  
Article
The Effect of Electroless Nickel–Polytetrafluoroethylene Coating on the Frictional Properties of Orthodontic Wires
by Kento Numazaki, Masatoshi Takahashi, Arata Ito, Yukyo Takada and Itaru Mizoguchi
Metals 2024, 14(2), 213; https://doi.org/10.3390/met14020213 - 9 Feb 2024
Cited by 1 | Viewed by 1874
Abstract
In orthodontic treatment, to achieve efficient tooth movement, it is important to reduce the frictional force between the wire and the bracket, especially the binding friction that occurs when the angle between the wire and the bracket is large. Electroless nickel–polytetrafluoroethylene (Ni-PTFE) coating [...] Read more.
In orthodontic treatment, to achieve efficient tooth movement, it is important to reduce the frictional force between the wire and the bracket, especially the binding friction that occurs when the angle between the wire and the bracket is large. Electroless nickel–polytetrafluoroethylene (Ni-PTFE) coating is a coating technology used to deposit PTFE particles with a low coefficient of friction on the coating surface to provide a low-friction surface for metallic materials. The purpose of this study was to investigate the effect of Ni-PTFE-coated orthodontic wires on the frictional force between brackets. The surface morphology, surface roughness, and frictional properties of Ni-PTFE-coated stainless steel wires and Ni-Ti wires were evaluated. The results demonstrate that the Ni-PTFE coating reduced the frictional force between the orthodontic wires and brackets, despite the increased surface roughness. Even when the angle between the wire and bracket was increased, assuming binding friction, the frictional force was reduced by the Ni-PTFE coating. This suggests that the friction between the wire and the bracket was suppressed by the PTFE particles deposited on the wire surface in contact with the bracket. Full article
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12 pages, 3443 KiB  
Article
Light Weight, Flexible and Ultrathin PTFE@Ag and Ni@PVDF Composite Film for High-Efficient Electromagnetic Interference Shielding
by Hongbo Liu, Jiajie Huang and Bingzhi Guo
Materials 2023, 16(13), 4831; https://doi.org/10.3390/ma16134831 - 5 Jul 2023
Cited by 8 | Viewed by 1657
Abstract
Dopamine was used to modify polytetrafluoroethylene (PTFE) in order to obtain functional polydopamine (PDA) surface-modified PTFE microporous film (PTFE@PDA). Ag was deposited on the surface of PTFE@PDA using electroless plating in order to obtain Ag-wrapped PTFE@PDA film (PTFE@Ag). A liquid-phase chemical reduction method [...] Read more.
Dopamine was used to modify polytetrafluoroethylene (PTFE) in order to obtain functional polydopamine (PDA) surface-modified PTFE microporous film (PTFE@PDA). Ag was deposited on the surface of PTFE@PDA using electroless plating in order to obtain Ag-wrapped PTFE@PDA film (PTFE@Ag). A liquid-phase chemical reduction method was employed to prepare nickel nanochains. A Ni@PVDF cast film was obtained by mechanically blended nickel nanochains and polyimide (PVDF). The above two films were hot pressed to give a flexible, ultra-thin, and highly effective electromagnetic shielding composite film with a “3+2” layered structure. IR, XRD, and TEM results showed the PTFE@PDA film surface was coated by a tight plating layer of Ag particles with a particle size of 100~200 nm. PTFE@Ag+Ni@PVDF composite film exhibited excellent electromagnetic shielding effectiveness, with the conductivity of 7507.5 S/cm and the shielding effectiveness of 69.03 dB in the X-band range. After a 2000-cycle bending, this value still remained at 51.90 dB. Furthermore, the composite film presented excellent tensile strength of 62.1 MPa. It has great potential for applications in flexible and wearable intelligent devices. Full article
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16 pages, 3537 KiB  
Article
Characterization and Tribological Behavior of Electroless-Deposited Ni-P-PTFE Films on NBR Substrates for Dynamic Contact Applications
by Beatriz Vasconcelos, Ricardo Serra, João Oliveira and Carlos Fonseca
Coatings 2022, 12(10), 1410; https://doi.org/10.3390/coatings12101410 - 27 Sep 2022
Cited by 10 | Viewed by 3610
Abstract
The use of rubber in dynamic contacts often results in severe degradation and wear of the rubber surface, which is why dynamic rubber seal contacts are usually oil lubricated to ensure their functionality. However, the increasing demand for more convenient and environmentally friendly [...] Read more.
The use of rubber in dynamic contacts often results in severe degradation and wear of the rubber surface, which is why dynamic rubber seal contacts are usually oil lubricated to ensure their functionality. However, the increasing demand for more convenient and environmentally friendly sealing solutions has prompted the development of dry low-friction rubber coatings. In this work, and for the first time, Ni-P and polytetrafluoroethylene (PTFE) particles were co-deposited by electroless plating on Nitrile Butadiene Rubber (NBR), as a low-cost solution to improve the NBR tribological behavior. A cationic surfactant, cetyltrimethylammonium bromide (CTAB), was added to the plating bath to ensure a homogeneous and efficient incorporation of PTFE into the Ni-P. The optimized PTFE incorporation reached 6.8%, and the composite coating adhesion to NBR was 20% higher than that of nickel-phosphorous (Ni-P) films. The tribological properties of the coatings evaluated by pin-on-disk tests showed a marginal decrease in the coefficient of friction (CoF) (10%, 1 N load), compared to that of Ni-P. However, the tested PTFE-based coatings displayed significantly smoother surfaces with less debris and cracks, clearly demonstrating the benefits of the PTFE in terms of wear resistance for loads up to 5 N. Full article
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