Search Results (6)

Flexible graphite foils with varying thicknesses (S = 282 ± 5 μm, M = 494 ± 7 μm, L = 746 ± 8 μm) and an initial density of 0.70 g/cm³ were obtained using the nitrate method. The specific electrical and thermal conductivity of these foils were investigated. As the density increased from 0.70 g/cm³ to 1.75 g/cm³, the specific electrical conductivity increased from 69 to 192 kS/m and the thermal conductivity increased from 109 to 326 W/(m·K) due to the rolling of graphite foils. The study showed that conductivity and anisotropy depend on the shape, orientation, and contact area of thermally expanded graphite (TEG) mesoparticles (mesostructural factor), and the crystal structure of nanocrystallites (nanostructural factor). A proposed mesostructural model explained these increases, with denser foils showing elongated, narrowed TEG particles and larger contact areas, confirmed by electron microscopy results. For graphite foils 200 and 750 μm thick, increased density led to a larger coherent scattering region, likely due to the rotation of graphite mesoparticles under mechanical action, while thinner foils (<200 μm) with densities > 1.7 g/cm³ showed increased plastic deformation, indicated by a sharp reduction in the coherent scattering region size. This was also evident from the decrease in misorientation angles with increasing density. Rolling reduced nanocrystallite misorientation angles along the rolling direction compared to the transverse direction (TD) (for 1.75 g/cm³ density ΔMA = 1.2° (S), 2.6° (M), and 2.4° (L)), explaining the observed anisotropy in the electrical and mechanical properties of the rolled graphite foils. X-ray analysis confirmed the preferred nanocrystallite orientation and anisotropy coefficients (A) using Kearns parameters, which aligned well with experimental measurements (for L series foils calculated as: A_0.70 = 1.05, A_1.30 = 1.10, and A_1.75 = 1.16). These calculated values corresponded well with the experimental measurements of specific electrical conductivity, where the anisotropy coefficient changed from 1.00 to 1.16 and mechanical properties varied from 0.98 to 1.13. Full article

Synthetic opals, a composition of homogeneous silica spheres in the mesoscale size range, have attracted the attention of scientists due to their favorable chemical and physical properties. Their chemical inertness and stability, biocompatibility, homogeneity, elevated specific surface area, and ease of functionalization of their surfaces make them a versatile nanotool. In the present study, the Stöber process was used to investigate the effect of parameters, such as reagent concentration and synthesis temperature, on the resulting silica particle size and structure. The optimal conditions for successfully obtaining homogeneous particles in the mesoscale range with high reproducibility were investigated. Several synthesis procedures and their dependence on the reaction temperature were presented to allow the selection of the assumed diameter of silica spheres. The numerous samples obtained were examined for size, homogeneity, structure, and specific surface area. On the basis of specific surface area measurements and nuclear magnetic resonance studies, the internal hierarchical structure of the spherical silica was confirmed as consisting of a solid core and layers of secondary spheres covered by a solid shell. Structural studies (X-ray Spectroscopy, X-ray Absorption Near-Edge Structure, and nuclear magnetic resonance), together with infrared vibrational spectroscopy, showed no dependence of the structure of the obtained mesospheres on the concentration of reagents and the size of the obtained particles. Full article

The development of a new approach to describe turbulent motions in condensed matter on the basis of nonlocal modeling of highly non-equilibrium processes in open systems is performed in parallel with an experiment studying the mesostructure of dynamically deformed solids. The shock-induced mesostructure formation inside the propagating waveform registered in real time allows the transient stages of non-equilibrium processes to be qualitatively and quantitatively revealed. A new nonlocal approach, developed on the basis of the nonlocal and retarded transport equations obtained within the non-equilibrium statistical physics, is used to describe the occurrence of turbulence. Within the approach, the reason for the transition to turbulence is that the non-equilibrium spatiotemporal correlation function generates the dynamic structures in the form of finite-size clusters on the mesoscale, with almost identical values of macroscopic densities moving as almost solid particles that can interact and rotate. The fragmentation of spatiotemporal correlations upon impact forms the mesoparticles that move at different speeds and transfer mass, momentum and energy-like wave packets. The movements recorded simultaneously at two scale levels indicate the energy exchange between them. Its description required a redefinition of the concept of energy far from local thermodynamic equilibrium. The experimental results show that the irreversible part of the dynamic mesostructure remains frozen into material as a new defect. Full article

With the use of the particle flow code in two dimensions, a fractal model is established with the number of particles of different particle fractions used as the statistics to study the fractal characteristics of particle size distribution. Numerically simulated specimens obtained by four scale methods are subjected to the relative density test and the biaxial compression test to explore the influences of fractal dimension D on the macroscopic and mesomechanical properties of specimens, as well as to study the relationship between fractal dimension D and different mechanical performance indexes. Results show that the particle size distribution of each of the four groups after scale exhibits fractal characteristics, with the fractal dimension D ranging from 1.27 to 2.03. The number of fine particles in the specimen increases with the fractal dimension D, the particle aggregates become more compact, the macroscopic mechanical properties of the specimens are improved, and a linear relationship exists between the fractal dimension D and different mechanical performance indexes. A large fractal dimension D corresponds to a great mesoparticle coordination number. Full article

The presence of excited-states and charge-separated species was identified through UV and visible laser pump and visible/near-infrared probe femtosecond transient absorption spectroscopy in spin coated films of poly[N-9″-heptadecanyl-2,7-carbazole-alt-5,5-(4,7-di-2-thienyl-2′,1′,3′-benzothiadiazole)] (PCDTBT) nanoparticles and mesoparticles. Optical gain in the mesoparticle films is observed after excitation at both 400 and 610 nm. In the mesoparticle film, charge generation after UV excitation appears after around 50 ps, but little is observed after visible pump excitation. In the nanoparticle film, as for a uniform film of the pure polymer, charge formation was efficiently induced by UV excitation pump, while excitation of the low energetic absorption states (at 610 nm) induces in the nanoparticle film a large optical gain region reducing the charge formation efficiency. It is proposed that the different intermolecular interactions and molecular order within the nanoparticles and mesoparticles are responsible for their markedly different photophysical behavior. These results therefore demonstrate the possibility of a hitherto unexplored route to stimulated emission in a conjugated polymer that has relatively undemanding film preparation requirements. Full article

Metal-ceramic composite particles are of increasing interest due to their potential applications in photonic metamaterials as well as next-generation catalysts. The zirconia-gold system has received little attention due to the lack of controllable preparation methods. Well-known methods for the deposition of gold nanoshells on silica spheres, however, should be adaptable for similar zirconia-based materials. Here, we present a novel synthetic approach to the well-controlled deposition of gold on the surface of sol-gel derived zirconia mesoparticles by a stepwise method involving the immobilization of gold nanoparticles and repeated seeded-growth steps. We show that the immobilization efficiency is strongly enhanced by acidification with hydrochloric acid and additional employment of aminomethylphosphonic acid as coupling agent. The optimum conditions are identified and the subsequent incremental growth by seeded reduction of gold is demonstrated. The results shed light on the parameters governing the preparation of zirconia@gold composite particles and our synthetic approach provides a promising tool for future developments in complex nanomaterials design. Full article