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Keywords = macroprogram

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17 pages, 26463 KB  
Article
Contribution of Hot-Spot Zone in Decarburization of BOF Steel-Making: Fundamental Analysis Based upon the FactSage-Macro Program
by Prasenjit Singha and Ajay Kumar Shukla
Metals 2022, 12(4), 638; https://doi.org/10.3390/met12040638 - 7 Apr 2022
Cited by 13 | Viewed by 4247
Abstract
An improved computational model to describe the decarburization process in basic oxygen furnaces for steel making is presented in this work. A dynamic model was thus developed to calculate the decarburization rate and its breakup as a contribution coming from the hot-spot zone [...] Read more.
An improved computational model to describe the decarburization process in basic oxygen furnaces for steel making is presented in this work. A dynamic model was thus developed to calculate the decarburization rate and its breakup as a contribution coming from the hot-spot zone (under jet impact) and emulsion zone (by droplet and slag reactions). In this work, multiple interconnected equilibrium/adiabatic stoichiometric-reactor-based approaches are used to describe the overall basic oxygen steel-making process. The macroprogramming facility of FactSage™ software was used to understand the thermodynamics and kinetics of basic oxygen steel-making processes. The temperature, compositions, and volumes of various phases are estimated with the use of this model. Hot-spot temperatures in the range from 2000 to 3000 °C as a benchmark was considered for calculations. The major contribution of decarburization was established to come from hot-spot reactions in the major part of the blow, except in the last part when emulsion phase reactions govern it. This development represents an original contribution to our understanding of the BOF steel-making process. Full article
(This article belongs to the Special Issue Oxygen Steelmaking Process)
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15 pages, 5624 KB  
Article
On-Machine Measurement and Error Compensation for 6061 Aluminum Alloy Hexagonal Punch Using a Turn-Milling Machine
by Cheng-Hsien Kuo and Po-Cheng Chen
Machines 2021, 9(9), 180; https://doi.org/10.3390/machines9090180 - 25 Aug 2021
Cited by 5 | Viewed by 4490
Abstract
For machining parts with complex shapes, consisting of computer numerical control (CNC) machine tools, different CNC machine tools will be used according to the machining method. If the workpiece is removed for off-machine measurement after machining, when the size is incorrect, it will [...] Read more.
For machining parts with complex shapes, consisting of computer numerical control (CNC) machine tools, different CNC machine tools will be used according to the machining method. If the workpiece is removed for off-machine measurement after machining, when the size is incorrect, it will need to be returned to the CNC machine tool for secondary machining. In this case, the workpiece surface quality and machining accuracy will be affected, which is very time-consuming. On-machine measurement and complex machine center is a key to solve this problem. In the recent researches that the touch probe was integrated on three or five axis machine for error compensation and shape construction based on on-machine measurement, but turning-milling machine was rare. In addition, the most types of parts were thin-walled parts or thin web parts. In this study, a contact measurement system is integrated into a CNC combined turning-milling machine for on-machine measuring. Macro-programming is used to design the machining path of A6061-T6 aluminum alloy hexagonal punch, and the action of probe measurement is added to the machining path. As the measured data exceed the tolerance range, the calculated data are fed back to the controller for machining improvement by compensation. The finished hexagonal punch is measured in a 3D coordinate measuring machine and the error is compared. The experimental results show that the contact probe needs to be corrected before machining, and the size of the corrected workpiece can reach the tolerance range of ±0.01 mm. The size error of rough machining is larger than that of fined machining, and the size error of rough machining will increase with the length of the workpiece. Full article
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22 pages, 2827 KB  
Article
Self-Organization at Aqueous Colloid-Membrane Interfaces and an Optical Method to Measure the Kinetics of Exclusion Zone Formation
by Harry Jabs and Beverly Rubik
Entropy 2014, 16(11), 5954-5975; https://doi.org/10.3390/e16115954 - 17 Nov 2014
Cited by 6 | Viewed by 7744
Abstract
Exclusion zone (EZ) formation at water-membrane interfaces was studied via bright- and dark-field microscopy. Various aqueous colloids including suspensions of charged microspheres, silicon dioxide particles, and raw whole milk were studied with Nafion® hydrophilic membranes. Interfacial formations observed included EZs and more [...] Read more.
Exclusion zone (EZ) formation at water-membrane interfaces was studied via bright- and dark-field microscopy. Various aqueous colloids including suspensions of charged microspheres, silicon dioxide particles, and raw whole milk were studied with Nafion® hydrophilic membranes. Interfacial formations observed included EZs and more complex patterns including striations, double layers, banding, dendritic aggregates of particles, and double-stranded structures resembling Birkeland current filaments in cold plasmas. A complex three-dimensional dynamic structure and continuous flow patterns persist in and around EZs, maintaining movement of the colloidal particles even after EZs are fully formed, for which a schematic is proposed. Since radiant energy is critical for EZ formation, we hypothesize that these interfacial phenomena are non-equilibrium dissipative structures that self-organize and self-maintain due to ongoing dynamic processes that may involve hydrodynamic interactions. Another experimental approach undertaken involved the construction of a microscope flow cell to measure the kinetics of EZ formation using sequential microphotography analyzed with macro-programmed ImageJ software to investigate effects of different types of conditioned water. No significant difference was found between spring water and the same water treated by a magnetic vortexer. A significant difference was found for municipal tap water compared to electrolyzed alkaline tap water from the same source. Full article
(This article belongs to the Special Issue Entropy and EZ-Water)
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