Search Results (4)

Zr₄₈Cu_47.5Al₄Co_0.5 bulk amorphous alloy composites were prepared by selective laser melting (SLM) technology under different processing conditions and their non-isothermal crystallization behaviors were systematically investigated. The results show that the crystallization phases are Cu₁₀Zr₇ and CuZr₂ for both gas-atomized powder and SLMed samples. The dependence of volume fraction of Cu₁₀Zr₇ and CuZr₂ on laser energy density can be fitted by an exponential function. The crystalline sizes of Cu₁₀Zr₇ and CuZr₂ linearly increase with increasing energy density. The thermal stability is larger for the gas-atomized powders than for the SLMed bulk samples. It is interestingly found that there is an exponential relationship between the crystallization enthalpy ΔH_x and the amorphous content. In addition, the glass transition is more difficult for the gas-atomized powders than for the SLMed bulk samples. The crystallization procedure is more difficult for the SLMed bulk samples than for the gas-atomized powders. The local activation energy E_α decreases with increasing α for the gas-atomized powder and the SLMed bulk samples. In addition, the E_α is larger for the SLMed bulk samples than for the gas-atomized powder at the corresponding crystallization fraction α. The dependence of the local Avrami exponent n(α) on the α is similar for both the gas-atomized powders and the SLMed bulk samples at studied heating rates. The crystallization mechanism is also discussed. Full article

In the present work, comparisons of non-isothermal crystallization kinetics between Fe₂₀Co₂₀Ni₂₀Cr₂₀(P_0.45B_0.2C_0.35)₂₀ high-entropy metallic glass (HEMG) and the predecessor Fe₇₅Cr₅P₉B₄C₇ metallic glass (MG) were performed with X-ray diffraction and differential scanning calorimetry approaches. The HEMG possesses a harsher crystallization process compared with the predecessor MG, deriving from a higher triggering energy for all the characteristic transitions and local activation energy along with a smaller local Avrami exponent and a growth with pre-existing nuclei. Meanwhile, the glass transition is the easiest process, but the nucleation of the second crystallization case is the hardest transition for the HEMG. However, the predecessor MG possesses distinctly different crystallization features of a moderate difficulty for the glass transition, the harshest process for the growth transition of the second crystallization case, and a crystallization of growth with a diverse nucleation rate. These results conclusively prove that the non-isothermal crystallization kinetics can be significantly changed after the present high-entropy alloying with the substitution of similar solvent elements Co, Ni, and Cr with Fe in Fe₇₅Cr₅P₉B₄C₇ MG. Moreover, the two alloys possess a strong glassy formation melt with high thermal stability and diverse crystallized products after non-isothermal crystallization. Full article

In this study, dilatometry and metallography were used to investigate the effect of silicon and copper alloying on the decomposition kinetics of 54SiCr6 steel during continuous slow cooling. It is different from the published literature for using the approach of the local activation energy of the austenite decomposition E_f and the local Avrami exponent n of the volume fraction of the transformed phase f to study the kinetics of austenite-pearlitic transformation in cooled 54SiCr steel at slow cooling rates. The Johnson–Mehl–Avrami equation was used to determine the dependence of the local activation energy for austenite decomposition E_f and the local Avrami exponent n on the volume fraction of the transformed phase f. The mechanism of the austenite decomposition was analysed based on the calculated values of n. Both the local and average activation energies were used to evaluate the alloying effect, and the results were compared with those obtained from other methods. The type of microstructure formed as a result of cooling at rates of 0.5 K/s, 0.3 K/s, 0.1 K/s and 0.05 K/s was determined. The effects of changes in the cooling rate and the content of silicon (1.5–2.5 wt.%) and copper (0.12–1.47 wt.%) on the dimension of nucleation and growth kinetics of the transformed phase were studied. It was revealed that the pearlite microstructure was formed predominantly in 54SiCr6 steel as a result of continuous cooling at slow cooling rates. It was also found that alloying this steel with copper led to a significant decrease in the value of E_f, as well as to a change in the mechanism of the kinetics of the austenite-pearlite transformation, which was realised in predominantly two- and three-dimensional nucleation and growth at a constant nucleation rate. At the same time, alloying this steel with silicon led only to a slight change in E_f. The results of the study of 54SiCr steel presented the dependence of the activation energy of transformation and the local Avrami exponent on the volume fraction of the transformed phase at a given cooling rate at different copper and silicon contents. In addition, the study provides insight into the mechanism of kinetics in cooled 54SiCr steel as a function of the cooling rate. Full article

The aim of this study was to analyze the crystallization of the Mg₇₂Zn₂₄Ca₄ metallic glass alloy. The crystallization process of metallic glass Mg₇₂Zn₂₄Ca₄ was investigated by means of the differential scanning calorimetry. The glass-forming ability and crystallization are both strongly dependent on the heating rate. The crystallization kinetics, during the isothermal annealing, were modelled by the Johnson–Mehl–Avrami equation. Avrami exponents were from 2.7 to 3.51, which indicates diffusion-controlled grain growth. Local exponents of the Johnson–Mehl–Avrami equation were also calculated. In addition, the Mg phase—being the isothermal crystallization product—was found, and the diagram of the time–temperature phase transformation was developed. This diagram enables the reading of the start and end times of the crystallization process, occurring in amorphous ribbons of the Mg₇₂Zn₂₄Ca₄ alloy on the isothermal annealing temperature. The research showed high stability of the amorphous structure of Mg₇₂Zn₂₄Ca₄ alloy at human body temperature. Full article