Search Results (4)

Layered ternary materials with high nickel content are regarded as the most promising cathode materials for high-energy-density lithium-ion batteries, owing to their advantages of high capacity, low cost, and relatively good safety. However, as the nickel content increases in ternary layered materials, their thermal stability noticeably decreases. It is of paramount importance to explore the characteristics of thermal runaway for lithium-ion batteries. In this study, two high-nickel LiNi_0.9Co_0.05Mn_0.05O₂ batteries were laterally heated to thermal runaway in a sealed chamber filled with nitrogen to investigate the thermal characteristics and gas compositions. The temperature of the battery tabs was measured, revealing that both batteries were in a critical state of thermal runaway near 120 degrees Celsius. A quantitative analysis method was employed during the eruption process, dividing it into three stages: ultra-fast, fast, and slow; the corresponding durations for the two batteries were 3, 2, 27 s and 3, 3, 26 s. By comparing the changes in chamber pressure, it was observed that both batteries exhibited a similar continuous venting duration of 32 s. However, the pressure fluctuation ranges of the two samples were 99.5 and 68.2 kPa·m·s⁻¹. Compared to the other sample, the 211 Ah sample exhibited larger chamber pressure fluctuations and reached higher peak pressures, indicating a higher risk of explosion. In the experimental phenomenon captured by a high-speed camera, it took only 1 s for the sample to transition from the opening of the safety valve to filling the experimental chamber with smoke. The battery with higher energy density exhibited more intense eruption during thermal runaway, resulting in more severe mass loss. The mass loss of the two samples is 73% and 64.87%. The electrolyte also reacted more completely, resulting in a reduced number of measured exhaust components. The main components of gaseous ejections are CO, CO₂, H₂, C₂H₄, and CH₄. For the 211 Ah battery, the vented gases were mainly composed of CO (41.3%), CO₂ (24.8%), H₂ (21%), C₂H₄ (7.4%) and CH₄ (3.9%), while those for the other 256 Ah battery were mainly CO (30.6%), CO₂ (28.5%), H₂ (21.7%), C₂H₄ (12.4%) and CH₄ (5.8%). Comparatively, the higher-capacity battery produced more gases. The gas volumes, converted to standard conditions (0 °C, 101 kPa) and normalized, resulted in 1.985 L/Ah and 2.182 L/Ah, respectively. The results provide valuable guidance for the protection of large-capacity, high-energy-density battery systems. The quantitative analysis of the eruption process has provided assistance to fire alarm systems and firefighting strategies. Full article

This scientific article presents the results of computational fluid dynamics (CFD) simulations conducted using OpenFOAM to evaluate the effectiveness of a jet fan ventilation system in managing the dispersion of smoke resulting from a car fire incident within an underground car park spanning a total area of 21,670 m², situated in Tabriz, Iran. The primary objective of the study is to determine the velocity fields and evaluate visibility conditions within a 10 m radius to gauge the efficiency and effectiveness of the system. The study employs a smoke concentration production rate of 5.49 × 10⁻⁴ kg/m³s for simulations involving fire scenarios. A total of 17 fire scenarios are examined, each extending 30 m in all directions from the initial location. The research findings demonstrate that the placement of jet fan components plays a significant role in the system’s efficiency, with fans positioned near the ceiling leading to back-layering. To mitigate this issue, the recommended design solution involves the strategic installation of multiple jet fan arrays in specific zones with the addition of 10 extra jet fans, effectively curbing lateral smoke dispersion. Furthermore, the analysis of air flow rates shows that when jet fans direct an excessive airflow towards the exhaust shafts (which have a designated flow rate of 22.5 m³/s), recirculating flows occur, leading to the dispersion of smoke throughout the car park. Consequently, the utilization of low-velocity jet fans (11.2 m/s) proves to be more effective in clearing smoke compared to high-velocity jet fans (22.3 m/s). The study also emphasizes the importance of optimal positioning of supply and exhaust shafts to achieve effective smoke control, highlighting the need for placing them on opposite walls or minimizing airflow turns. Additionally, the research underscores the significance of fire resistance in jet fan units, as their failure during fire incidents can have severe consequences. Full article

The tunnel width and the transverse fire’s position both impact the heat exhaust coefficient, which is a critical component of the lateral smoke exhaust in tunnel fires. In this research, the tunnel width and the transverse location of the fire source are varied to analyze the heat exhaust coefficient of lateral smoke exhaust. When tunnel width increases, there is a noticeable decrease in the longitudinal temperature of the entrained air and smoke layer in the fire plume. Furthermore, the heat exhaust coefficients are reduced. An increase in the distance between the exhaust vent and the fire source causes an increase in the proportion of hot smoke in the smoke exhaust mass flow, which increases the heat exhaust coefficient. A calculated heat exhaust coefficient was developed using the fire source’s location and the tunnel’s width as inputs, which agrees well with the simulation results. This method can predict the heat exhaust coefficient of the lateral smoke exhaust in tunnel fires. The findings of this study provide insight into how the tunnel width and the location of a transverse fire influence the heat exhaust coefficient. Full article

Congenital heart defects (CHDs) are a common birth defect of largely unknown etiology, with high fetal and neonatal mortality. A review of CHDs and environmental contaminant exposure found that meta-analyses showed only modest associations for smoking, vehicle exhaust components, disinfectant by-products and proximity to incinerators, with stronger results from the newer, larger and better quality studies masked by the typical absence of effect in older studies. Recent studies of exposure to agricultural pesticides, solvents, metals and landfill sites also showed associations. Certain contaminants have been associated with certain CHDs, with septal defects being the most common. Frequent methodological problems include failure to account for potential confounders or maternal/paternal preconception exposure, differences in diagnosing, defining and classifying CHDs, grouping of defects to increase power, grouping of contaminants with dissimilar mechanisms, exclusion of pregnancies that result in death or later life diagnosis, and the assumption that maternal residence at birth is the same as at conception. Furthermore, most studies use measurement estimates of one exposure, ignoring the many additional contaminant exposures in daily life. All these problems can distort and underestimate the true associations. Impaired methylation is a common mechanism, suggesting that supplementary folate may be protective for any birth defect. Full article