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Keywords = iron–boron pairs

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10 pages, 2252 KB  
Article
Evaluation of Wear Resistance of AISI L6 and 5140 Steels after Surface Hardening with Boron and Copper
by Stepan Lysykh, Vasily Kornopoltsev, Undrakh Mishigdorzhiyn, Yuri Kharaev and Zhongliang Xie
Lubricants 2023, 11(2), 48; https://doi.org/10.3390/lubricants11020048 - 29 Jan 2023
Cited by 6 | Viewed by 2431
Abstract
(1) Background: Boriding is one of the most common methods of thermal-chemical treatment due to its excellent hardness and wear resistance of the produced diffusion layers. However, it has limited application compared to carburizing and nitriding because of fragility and chipping. Introducing another [...] Read more.
(1) Background: Boriding is one of the most common methods of thermal-chemical treatment due to its excellent hardness and wear resistance of the produced diffusion layers. However, it has limited application compared to carburizing and nitriding because of fragility and chipping. Introducing another alloying element into the boron media helps avoid those drawbacks and improve other surface properties of the layer. The purpose of this work is to improve the surface mechanical properties of L6 and 5140 low alloy steels by two-component surface hardening with boron and copper. (2) Methods: The treatment was performed by means of a powder-pack method using boron, copper, and aluminum powders in the following proportions: 60% B4C + 20% Al2O3 + 16% CuO + 4% NaF. The time–temperature parameters of the treatment were four hours exposure at 950 °C. Microstructure, elemental, and phase composition were investigated as well as microhardness and wear resistance of the obtained layers. (3) Results: Layers of up to 180–200 μm thick are formed on both steels as a result of treatment. Needle-like structures similar to pure boriding was obtained. The maximum microhardness was 2000 HV on L6 steel and 1800 HV on 5140 steel. These values correspond to iron borides and were confirmed by XRD analysis revealing FeB, Fe2B, and Cr5B3. The wear resistance of both steels was about ten times higher after the treatment compared to non-treated samples. (4) Conclusions: Surface hardening with boron and copper significantly improves the mechanical properties of both alloy steels. The results obtained are beneficial for different tribo-pair systems or three-body wear with abrasion and minimum impact loads. Full article
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16 pages, 1777 KB  
Article
Comparison of LID and Electrical Injection Regeneration of PERC and Al-BSF Solar Cells from a Cz-Si Ingot
by Siqi Ding, Chen Yang, Cheng Qin, Bin Ai, Xiaopu Sun, Jianghai Yang, Quan Liu and Xueqin Liang
Energies 2022, 15(20), 7764; https://doi.org/10.3390/en15207764 - 20 Oct 2022
Cited by 5 | Viewed by 2013
Abstract
In order to study the effect of device structures and silicon wafer positions on light-induced degradation (LID) and regeneration, five groups of industrial PERC and Al-BSF solar cells were fabricated by using silicon wafers from different positions of a B-doped Czochralski silicon (Cz-Si) [...] Read more.
In order to study the effect of device structures and silicon wafer positions on light-induced degradation (LID) and regeneration, five groups of industrial PERC and Al-BSF solar cells were fabricated by using silicon wafers from different positions of a B-doped Czochralski silicon (Cz-Si) ingot. Then, the cells were subjected to a dark annealing (200 °C, 30 min), the first LID (45 °C, 1 sun, 12 h), an electrical injection regeneration (175 °C, 18 A, 30 min) and the second LID (45 °C, 1 sun, 12 h) in order, and the variations of performance of the cells with processing time were measured. It was found that after the electrical injection regeneration, the efficiency losses of PERC cells decreased from 1.28–1.76%absolute in the first LID to 0.09–0.16%absolute in the second LID, while those of Al-BSF cells decreased from 0.3–0.66%absolute in the first LID to 0 in the second LID. The efficiency losses of PERC cells during the first LID were caused by the co-action of B-O-defect-induced LID (BO-LID) and dissociation of Fe-B pairs, and the latter contributed 5.81–9.56% of the efficiency loss, while those of Al-BSF cells during the first LID were almost contributed by BO-LID solely. For both kinds of cells, the cells made from the silicon wafers from middle of the ingot had the best performance throughout the experiment. In addition, the LID and regeneration treatments only affected the spectral response of the cells in the wavelength larger than 700 nm. Full article
(This article belongs to the Special Issue Recent Development of Silicon Solar Cells)
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10 pages, 4124 KB  
Article
Permeability and Load Capacity of Iron Porous Bearings with the Addition of Hexagonal Boron Nitride
by Krzysztof Gocman, Tadeusz Kałdoński, Bolesław Giemza and Artur Król
Materials 2022, 15(15), 5112; https://doi.org/10.3390/ma15155112 - 22 Jul 2022
Cited by 2 | Viewed by 1685
Abstract
Due to their properties, porous sliding bearings are considered to be maintenance-free, which means that no lubrication is required during operation. Their design enables operation at low rotational speeds with high load. Another effect of this bearing design is the lubrication continuity in [...] Read more.
Due to their properties, porous sliding bearings are considered to be maintenance-free, which means that no lubrication is required during operation. Their design enables operation at low rotational speeds with high load. Another effect of this bearing design is the lubrication continuity in the tribological pair. In this study, the selected tribological properties (such as load capacity and permeability) of new-generation iron porous bearings with boron nitride powder were experimentally investigated. Tests were carried out under various conditions, using unique test apparatus. The addition of 3% (weight) of hexagonal boron nitride (hBN) significantly increased the load capacity of tested porous bearings in comparison to the same standard bearings containing 2.5% copper. The obtained pgr·v rating reached almost 7 MPa, which is a value almost three times higher than the requirements for this type of bearing. It is worth emphasizing that such a result was obtained despite a noticeable deterioration in the air and oil permeability of the bearing. Full article
(This article belongs to the Special Issue Porous Materials and Advanced Manufacturing Technologies)
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