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Keywords = inter-basinal sedimentary correlations

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21 pages, 14878 KiB  
Article
Reservoir Characteristics of Marine–Continental Transitional Taiyuan Formation Shale and Its Influence on Methane Adsorption Capacity: A Case Study in Southern North China Basin
by Wei Jiang and Yang Hu
Appl. Sci. 2024, 14(15), 6577; https://doi.org/10.3390/app14156577 - 27 Jul 2024
Viewed by 913
Abstract
To further study the reservoir characteristics and adsorption capacity of the Taiyuan Formation shale in the South North China Basin (SNCB), the pore structure and adsorption capacity of shale are discussed using various analysis tests, including elemental geochemistry, organic geochemistry, mineral composition, low-temperature [...] Read more.
To further study the reservoir characteristics and adsorption capacity of the Taiyuan Formation shale in the South North China Basin (SNCB), the pore structure and adsorption capacity of shale are discussed using various analysis tests, including elemental geochemistry, organic geochemistry, mineral composition, low-temperature nitrogen adsorption (LTNA), and methane adsorption experiments. The results indicate that the Taiyuan Formation shale formed in a poor oxygen and anaerobic sedimentary environment in still water. The average value of total organic carbon (TOC) content is 2.37%. The organic matter type mainly consists of type III kerogen. The vitinite reflectance (Ro) ranges from 3.11% to 3.50%. The clay mineral content varies greatly, averaging at 40.7%, while the quartz content averages at 37.7%. The Taiyuan Formation shale mainly develops interparticle (InterP) pores, followed by organic pores, intraparticle (IntraP) pores, solution pores, and microfractures. BET specific surface area (SSA) is between 9.47 m2/g and 22.14 m2/g, while pore volume (PV) ranges from 0.0098 cm3/g to 0.022 cm3/g, indicating favorable conditions for shale gas storage. According to the results of the CH4 adsorption experiment, Langmuir volume from Taiyuan Formation shales exhibits 1.35~4.30 cm3/g, indicating excellent adsorption capacity. TOC content shows a positive correlation with both Langmuir volume and BET SSA from Taiyuan Formation shales, suggesting that TOC plays a crucial role in controlling microscopic pores and gas adsorption capacity. Organic matter enhances the shale adsorption capacity by providing abundant pore SSA. Due to formation compaction, the pore size of clay minerals decreases, leading to an increase in pore SSA, while kaolinite exhibits weak hydrophilic ability. Consequently, with the increase in clay minerals and kaolinite content, the shale adsorption capacity is enhanced to a certain extent. However, an increase in the carbonate mineral content may result in a decrease in the proportion of clay minerals, therefore reducing the CH4 adsorption capacity of shale. Full article
(This article belongs to the Special Issue Advances in Unconventional Natural Gas: Exploration and Development)
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19 pages, 5970 KiB  
Article
Origin of Redbeds in the Neoproterozoic Socheong Formation and Their Relation to the Dashigou Large Igneous Province
by Hawon Yun, Seung Hwan Lee and Inah Seo
Minerals 2024, 14(1), 59; https://doi.org/10.3390/min14010059 - 2 Jan 2024
Viewed by 1784
Abstract
During the latest Mesoproterozoic–Early Neoproterozoic era, extensional regimes generated a number of sedimentary basins in various regions in the Sino-Korean Craton. Mantle-plume emplacements are widely recognized in the sedimentary strata as mafic dikes and sills of the Dashigou Large Igneous Province (LIP). The [...] Read more.
During the latest Mesoproterozoic–Early Neoproterozoic era, extensional regimes generated a number of sedimentary basins in various regions in the Sino-Korean Craton. Mantle-plume emplacements are widely recognized in the sedimentary strata as mafic dikes and sills of the Dashigou Large Igneous Province (LIP). The occurrence of Fe-rich redbeds is first reported in the Neoproterozoic Socheong Formation of the Sangwon Supergroup in the Pyeongnam Basin. Their geochemical and mineralogical characteristics indicate basin-wide Fe enrichment due to hydrothermal fluid input. The episodic yet repetitive hydrothermal injection into the basin generated short-lived anoxia, recorded as greenish-gray coloration in the ferruginous beds. This hydrothermal fluid was likely sourced from the mafic igneous activities involved in the Dashigou LIP. The redbeds can be utilized as key beds for intra- or inter-basinal stratigraphic correlation and to study the negative carbon isotope excursions that occurred in the genetically related basins in the region (e.g., the Sangwon, Xu-Huai, and Dalian basins). Full article
(This article belongs to the Special Issue Large Igneous Provinces: Research Frontiers)
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19 pages, 1817 KiB  
Article
Towards an Integrated and Accurate Planktonic-Foraminiferal-Deduced Bio-Chrono-Stratigraphic Framework of Late Quaternary Mediterranean Marine Cores
by George Kontakiotis, Assimina Antonarakou, Evangelia Besiou, Elisavet Skampa and Maria V. Triantaphyllou
J. Mar. Sci. Eng. 2023, 11(12), 2345; https://doi.org/10.3390/jmse11122345 - 12 Dec 2023
Viewed by 2160
Abstract
The late Quaternary is a key stratigraphic interval as it encompasses the Late Glacial to Holocene transition, which is characterized by a series of pronounced centennial climate oscillations and subsequent short-term events of paleoceanographic variability. Across this stratigraphic interval, significant turnovers and faunal [...] Read more.
The late Quaternary is a key stratigraphic interval as it encompasses the Late Glacial to Holocene transition, which is characterized by a series of pronounced centennial climate oscillations and subsequent short-term events of paleoceanographic variability. Across this stratigraphic interval, significant turnovers and faunal changes in the composition and abundance of planktonic foraminiferal assemblages are well-documented through their high-resolution quantitative analysis performed in the south Aegean core NS-18. The identification of 10 synchronous bioevents among the Mediterranean sub-basins allows accurate inter-basinal correlations over the study time interval, thus contributing to the development of a robust chronostratigraphic framework for this setting. Moreover, the identification and timing of additional 20 diachronous bioevents, in conjunction with the already established bio-ecozonation scheme of the Aegean Sea, provide a continuous record of faunal changes (in terms of species-specific distributional abundances) which can be used as an additional locally expressed biochronological tool for the eastern Mediterranean deep-sea cores. The present study certainly indicates that the cause-and-effect relationships between the paleoceanographic/paleoclimatic perturbations and biological response require a highly resolved regional chronostratigraphy. Full article
(This article belongs to the Special Issue Advances in Marine Micropaleontology)
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20 pages, 13006 KiB  
Article
Characteristics and Geological Significance of High-Frequency Cycles in Salinized Lake Basins: The Paleogene Kumugeliemu Group in the Xinhe Area, Northern Tarim Basin
by Yanru Yang, Jingchun Tian, Xiang Zhang, Yingxu Li, Yue Zhang and Qiaoyi Xia
Minerals 2023, 13(6), 824; https://doi.org/10.3390/min13060824 - 16 Jun 2023
Cited by 1 | Viewed by 1684
Abstract
Salinized lake basins have distinctive sedimentary response characteristics, similar to marine shallow-water carbonate platforms. High-frequency cycles can also be used to reveal more sedimentological information, such as relative lake-level fluctuations, lithofacies sequence combinations, and paleogeographic evolution. In this article, a comprehensive study on [...] Read more.
Salinized lake basins have distinctive sedimentary response characteristics, similar to marine shallow-water carbonate platforms. High-frequency cycles can also be used to reveal more sedimentological information, such as relative lake-level fluctuations, lithofacies sequence combinations, and paleogeographic evolution. In this article, a comprehensive study on the stratigraphic shelf delineation and high-frequency cycles of the Paleozoic Kumugeliemu Group in Xinhe area, northern Tarim Basin, was performed using drilling cores, logging curves, and seismic analyses. As a result of the study, the following data were obtained: the three sets of marker beds in the Kumugeliemu Group in the study area could be divided into a bottom sandstone component (E1-2 km1), a lower gypsum mudstone component (E1-2 km2), a salt rock component (E1-2 km3), and an upper gypsum mudstone component (E1-2 km4) by petrology vertical overlay combination and isochronous tracking correlation, which constituted two third-order cycles (ESQ1, ESQ2). They were further divided into seven fourth-order cycles (Esq1–Esq7). Due to the droughty and saline lacustrine depositional system background, the internal rock fabric changed frequently and showed a periodic vertical overlay pattern. Stratified gypsum salt, gypsum mud (sand) rock, and gypsum rock were used as the cycle interface. A single cycle was mainly characterized by an upward shallower depositional sequence of rapid lake transgression followed by a slow lake regression, composed of massive sandstone–lamellar mudstone–lime dolomite–gypsum rock, massive sandstone–lamellar mudstone–gypsum rock (gypsum salt), massive sandstone–massive gypsum mud (sand) rock–gypsum rock, and other cycle structure types. The complete sedimentary cycle was superposed by a single cycle and compared by the inter-well thickness difference, indicating that the study area had a paleogeomorphology pattern of “West-Low–East-High”. The thickness of the cycles decreased gradually from bottom to top vertically, and five sedimentary stages were determined, i.e., freshwater, brackish, brackish water, salt lake, and semi-saltwater, reflecting the evolutionary process of increasing salinity, lake basin filling, and gradual salinization and shrinkage. Full article
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23 pages, 9051 KiB  
Review
Phosphate Rocks: A Review of Sedimentary and Igneous Occurrences in Morocco
by Radouan El Bamiki, Otmane Raji, Muhammad Ouabid, Abdellatif Elghali, Oussama Khadiri Yazami and Jean-Louis Bodinier
Minerals 2021, 11(10), 1137; https://doi.org/10.3390/min11101137 - 16 Oct 2021
Cited by 77 | Viewed by 23695
Abstract
Phosphate rocks are a vital resource for world food supply and security. They are the primary raw material for phosphoric acid and fertilizers used in agriculture, and are increasingly considered to be a potential source of rare earth elements. Phosphate rocks occur either [...] Read more.
Phosphate rocks are a vital resource for world food supply and security. They are the primary raw material for phosphoric acid and fertilizers used in agriculture, and are increasingly considered to be a potential source of rare earth elements. Phosphate rocks occur either as sedimentary deposits or igneous ores associated with alkaline rocks. In both cases, the genesis of high-grade phosphate rocks results from complex concentration mechanisms involving several (bio)geochemical processes. Some of these ore-forming processes remain poorly understood and subject to scientific debate. Morocco holds the world’s largest deposits of sedimentary phosphate rocks, and also possesses several alkaline complexes with the potential to bear igneous phosphate ores that are still largely underexplored. This paper summarizes the main geological features and driving processes of sedimentary and igneous phosphates, and discusses their global reserve/resource situation. It also provides a comprehensive review of the published data and information on Moroccan sedimentary and igneous phosphates. It reveals significant knowledge gaps and a lack of data, inter alia, regarding the geochemistry of phosphates and basin-scale correlations. Owing to the unique situation of Moroccan phosphates on the global market, they clearly deserve more thorough studies that may, in turn, help to constrain future resources and/or reserves, and answer outstanding questions on the genesis of phosphates. Full article
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