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Keywords = hydroxyarylformimidoyl chloride

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6 pages, 8300 KiB  
Communication
Amide-Assisted Rearrangement of Hydroxyarylformimidoyl Chloride to Diarylurea
by Xizhong Song, Xiaoyu Liu, Wei Yu and Yi Jin
Molecules 2021, 26(21), 6437; https://doi.org/10.3390/molecules26216437 - 25 Oct 2021
Cited by 1 | Viewed by 2258
Abstract
A novel amide-assisted rearrangement reaction of hydroxybenzimidoyl chloride has been established for the efficient synthesis of 1,3-diphenylurea derivatives. A variety of electronically and sterically different 1,3-diphenylurea derivatives can be obtained in good to excellent yields, and a proposed reaction mechanism is also presented. [...] Read more.
A novel amide-assisted rearrangement reaction of hydroxybenzimidoyl chloride has been established for the efficient synthesis of 1,3-diphenylurea derivatives. A variety of electronically and sterically different 1,3-diphenylurea derivatives can be obtained in good to excellent yields, and a proposed reaction mechanism is also presented. Full article
(This article belongs to the Section Organic Chemistry)
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