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Keywords = hollow glass microballoon

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17 pages, 5707 KiB  
Article
Investigation of Thermomechanical Properties of Hollow Glass Microballoon-Filled Composite Materials Developed by Additive Manufacturing with Machine Learning Validation
by Md Sakhawat Hossain, Sazid Noor Rabi, Sakib Mohammad, Kaden Cook, Farhan Chowdhury and Sabrina Nilufar
Polymers 2025, 17(11), 1495; https://doi.org/10.3390/polym17111495 - 28 May 2025
Viewed by 1077
Abstract
Stereolithography (SLA) is a popular additive manufacturing (AM) method frequently used in research and various industrial sectors. The acrylate resin used in this research is renowned for its flexibility and durability, enabling the creation of flawless 3D-printed parts with exceptional mechanical properties. This [...] Read more.
Stereolithography (SLA) is a popular additive manufacturing (AM) method frequently used in research and various industrial sectors. The acrylate resin used in this research is renowned for its flexibility and durability, enabling the creation of flawless 3D-printed parts with exceptional mechanical properties. This study aims to enhance the thermomechanical properties of 3D-printed hollow glass microballoon (HGM)-filled composite materials by adding minimal HGM into the acrylate resin. We investigated the material properties through uniaxial compression tests, dynamic mechanical analysis (DMA), and scanning electron microscopy (SEM). To validate the results, a numerical investigation and a machine learning (ML) approach were carried out and compared with the experimental results. Adding a small number of microballoons increases compressive strength and stiffness. The viscoelastic behavior of the samples also provides an estimate of resilience at higher temperatures, considering the addition of filler material into the resin. Our study shows that the addition of 0.04% of HGM increased compressive strength by around 99.30% compared to the neat sample, while the stiffness increased by around 31.42% compared to the neat sample at 0.05% of HGM. It can also be estimated that the suitable range of HGM addition for the resin we used exists between 0.04% and 0.05%, where the materials achieve their maximum strength and stiffness. In addition, a predictive machine learning (ML) model, namely Random Forest Regressor (RFR), shows low mean squared error (MSE), mean absolute error (MAE), and excellent R2 scores, demonstrating the goodness of the model’s performance. This modern approach can guide us to selecting a suitable filler percentage for the photopolymer resin for 3D printing and making it applicable to different engineering prospects. Full article
(This article belongs to the Special Issue 3D Printing of Polymer Composite Materials)
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15 pages, 4049 KiB  
Article
Compression Response of Silicone-Based Composites with Integrated Multifunctional Fillers
by Ingyu Bak, Jihyeon Kim, Andrew Jacob Ruba, David John Ross and Kwan-Soo Lee
Polymers 2025, 17(4), 500; https://doi.org/10.3390/polym17040500 - 14 Feb 2025
Viewed by 918
Abstract
Polydimethylsiloxane (PDMS) is known for its exceptional mechanical properties, chemical stability, and flexibility. Recent advancements have focused on developing functional PDMS composites by integrating various functional fillers, including polymers, ceramics, and metals, for advanced applications such as electronics, medical devices, and aerospace. Consequently, [...] Read more.
Polydimethylsiloxane (PDMS) is known for its exceptional mechanical properties, chemical stability, and flexibility. Recent advancements have focused on developing functional PDMS composites by integrating various functional fillers, including polymers, ceramics, and metals, for advanced applications such as electronics, medical devices, and aerospace. Consequently, there is a growing need to investigate PDMS composites to achieve higher filler loadings offering enhanced mechanical performance. This study addresses this need by utilizing the high molecular weight (MW) PDMS resin we have developed, offering its high elongation capacity of up to >6500%. We incorporated boron (B), hollow glass microballoons (HGMs), and tungsten-coated hollow glass microballoons (WHGMs) into the developed high MW PDMS. The resulting composites demonstrated excellent elastic properties and significant compression resilience (35–80%) and elastic modulus (1.28–10.15 MPa) at high filler loadings (~60 vol.%). Specifically, B/PDMS composites achieved up to 67.6 vol.% of B, HGM/PDMS composites held up to 68.6 vol.% of HGM, and WHGM/PDMS composites incorporated up to 54.0 vol.% of WHGM. These findings highlight the potential of high MW PDMS for developing high-performance PDMS composites suitable for advanced applications such as aerospace, automotive, and medical devices. Full article
(This article belongs to the Special Issue Mechanical Behaviors and Properties of Polymer Materials, 2nd Edition)
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14 pages, 4425 KiB  
Article
Influence of Graphene Nano Fillers and Carbon Nano Tubes on the Mechanical and Thermal Properties of Hollow Glass Microsphere Epoxy Composites
by Kumar D, Kiran Shahapurkar, C. Venkatesh, Muruganandhan R, Vineet Tirth, Chandru Manivannan, Ibrahim M. Alarifi, Manzoore Elahi M. Soudagar and Ahmed S. El-Shafay
Processes 2022, 10(1), 40; https://doi.org/10.3390/pr10010040 - 27 Dec 2021
Cited by 20 | Viewed by 3849
Abstract
The present work aimed to analyze the roll of carbon nano tubes and graphene nano fillers on the mechanical and thermal characteristics of hollow glass microsphere reinforced epoxy composites. Composites with varying content of hollow glass microballoons (2, 4, 6, 8, and 10 [...] Read more.
The present work aimed to analyze the roll of carbon nano tubes and graphene nano fillers on the mechanical and thermal characteristics of hollow glass microsphere reinforced epoxy composites. Composites with varying content of hollow glass microballoons (2, 4, 6, 8, and 10 wt %) reinforced in epoxy matrix were fabricated. Additionally, two more types of composites, one with graphene nano fillers and the other with carbon nano tube at a constant 0.5 wt %, were fabricated with varying weight percentages of hollow glass microballoons (2, 4, 6, 8, and 10%). The composites were fabricated using an open mold casting process. Composites were tested for thermal and mechanical properties. The tensile and flexural moduli were found to rise as the HGM concentration increased. Graphene-filled HGM/epoxy composites revealed the highest modulus compared with HGM/epoxy and HGM/CNT/epoxy composites. The impact strength of all composite types decreased as the HGM content increased. Neat epoxy specimens revealed low response as compared with all the composites tested. Further, the thermal conductivity of HGM/epoxy composites was lower as compared with other compositions and neat epoxy. Scanning electron microscopy was used to analyze the surface morphological behavior of the composites subjected to flexural test. It was found that HGM/G/E composites with 10% of HGM and 0.5% of graphene by weight in epoxy matrix were the optimum. Full article
(This article belongs to the Special Issue Particulate-Filled Advanced Polymer Composites)
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15 pages, 3621 KiB  
Article
Enhancing the Ignition, Hardness and Compressive Response of Magnesium by Reinforcing with Hollow Glass Microballoons
by Vyasaraj Manakari, Gururaj Parande, Mrityunjay Doddamani and Manoj Gupta
Materials 2017, 10(9), 997; https://doi.org/10.3390/ma10090997 - 25 Aug 2017
Cited by 51 | Viewed by 5107
Abstract
Magnesium (Mg)/glass microballoons (GMB) metal matrix syntactic foams (1.47–1.67 g/cc) were synthesized using a disintegrated melt deposition (DMD) processing route. Such syntactic foams are of great interest to the scientific community as potential candidate materials for the ever-changing demands in automotive, aerospace, and [...] Read more.
Magnesium (Mg)/glass microballoons (GMB) metal matrix syntactic foams (1.47–1.67 g/cc) were synthesized using a disintegrated melt deposition (DMD) processing route. Such syntactic foams are of great interest to the scientific community as potential candidate materials for the ever-changing demands in automotive, aerospace, and marine sectors. The synthesized composites were evaluated for their microstructural, thermal, and compressive properties. Results showed that microhardness and the dimensional stability of pure Mg increased with increasing GMB content. The ignition response of these foams was enhanced by ~22 °C with a 25 wt % GMB addition to the Mg matrix. The authors of this work propose a new parameter, ignition factor, to quantify the superior ignition performance that the developed Mg foams exhibit. The room temperature compressive strengths of pure Mg increased with the addition of GMB particles, with Mg-25 wt % GMB exhibiting the maximum compressive yield strength (CYS) of 161 MPa and an ultimate compressive strength (UCS) of 232 MPa for a GMB addition of 5 wt % in Mg. A maximum failure strain of 37.7% was realized in Mg-25 wt % GMB foam. The addition of GMB particles significantly enhanced the energy absorption by ~200% prior to compressive failure for highest filler loading, as compared to pure Mg. Finally, microstructural changes in Mg owing to the presence of hollow GMB particles were elaborately discussed. Full article
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