Search Results (3)

The New Energy and Industry Technology Development Organization (NEDO) road map (Japan, 2017) has proposed that a polymer electrolyte fuel cell (PEFC) system, which operates at a temperature of 90 °C and 100 °C, be applied for stationary and mobility usage, respectively. This study suggests using a thin polymer electrolyte membrane (PEM) and a thin gas diffusion layer (GDL), at the same time, to achieve better power-generation performance, at a higher temperature than usual. The focus of this paper is to clarify the effect of separator thickness on the distribution of temperature at the reaction surface (T_react), with the relative humidity (RH) of the supply gasses and initial operation temperature (T_ini), quantitatively. In this study, separator thickness is investigated in a system using a thin PEM and a thin GDL. Moreover, this study investigates the difference between the maximum temperature and the minimum temperature obtained from the distribution of T_react as well as the relation between the standard deviation of T_react − T_ini and total voltage, to clarify the effect of separator thickness. The impact of the flow rates of the supply gases on the distribution of T_react is not large, among the investigated conditions. It is noticed that the temperature distribution is wider when a separator thickness of 2.0 mm is selected. On the other hand, it is observed that the temperature increases along with the gas flow through the gas channel, by approximately 2 °C, when using a separator thickness between 1.5 mm and 1.0 mm. The impact of the RH on the distributions of T_react − T_ini is larger at T_ini = 100 °C, when a separator thickness of 1.0 mm is selected. It is revealed that the wider temperature distribution provides a reduction in power-generation performance. This study proposes that the thin separators, i.e., with a thickness of 1.5 mm and 1.0 mm, are not suitable for higher temperature operation than usual. Full article

In order to characterize high temperature polymer electrolyte fuel cells (HT-PEFCs) in operando, neutron radiography imaging, in combination with the deuterium contrast method, was used to analyze the hydrogen distribution and proton exchange processes in operando. These measurements were then combined with the electrochemical impedance spectroscopy measurements. The cell was operated under different current densities and stoichiometries. Neutron images of the active area of the cell were captured in order to study the changeover times when the fuel supply was switched between hydrogen and deuterium, as well as to analyze the cell during steady state conditions. This work demonstrates that the changeover from proton to deuteron (and vice versa) leads to local varying media distributions in the electrolyte, independent of the overall exchange dynamics. A faster proton-to-deuteron exchange was re-discovered when switching the gas supply from H₂ to D₂ than that from D₂ to H₂. Furthermore, the D₂ uptake and discharge were faster at a higher current density. Specifically, the changeover from H to D takes 5–6 min at 200 mA cm⁻², 2–3 min at 400 mA cm⁻² and 1–2 min at 600 mA cm⁻². An effect on the transmittance changes is apparent when the stoichiometry changes. Full article

Fuel cells have been attracting significant attention recently as highly efficient and eco-friendly energy generators. Here, we have comprehensively reviewed all types of fuel cells using computational analysis based on a citation network that detects emerging technologies objectively and provides interdisciplinary data to compare trends. This comparison shows that the technologies of solid oxide fuel cells (SOFCs) and electrolytes in polymer electrolyte fuel cells (PEFCs) are at the mature stage, whereas those of biofuel cells (BFCs) and catalysts in PEFCs are currently garnering attention. It does not mean, however, that the challenges of SOFCs and PEFC electrolytes have been overcome. SOFCs need to be operated at lower temperatures, approximately 500 °C. Electrolytes in PEFCs still suffer from a severe decrease in proton conductivity at low relative humidity and from their high cost. Catalysts in PEFCs are becoming attractive as means to reduce the platinum catalyst cost. The emerging technologies in PEFC catalysts are mainly heteroatom-doped graphene/carbon nanotubes for metal-free catalysts and supports for iron- or cobalt-based catalysts. BFCs have also received attention for wastewater treatment and as miniaturized energy sources. Of particular interest in BFCs are membrane reactors in microbial fuel cells and membrane-less enzymatic biofuel cells. Full article