Search Results (8)

This work investigated the structural response and phase transformation dynamics of silica-bearing cherts subjected to high-temperature processing (up to 1400 °C) and prolonged mechanochemical activation. Through a combination of X-ray diffraction (XRD) with Rietveld refinement, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and transmission electron microscopy (HRTEM), we trace the crystallographic pathways of quartz, moganite, tridymite, and cristobalite under controlled thermal and mechanical stress regimes. The experimental results demonstrated that phase behavior is highly dependent on intrinsic properties such as initial phase composition, impurity presence, and crystallinity. Heating at 1400 °C induced irreversible conversion of quartz, moganite, and tridymite into cristobalite. Samples enriched in cristobalite and tridymite exhibited notable increases in crystallinity, whereas quartz-dominant samples showed either stability or a decline in structural order. Rietveld analyses underscored the critical influence of microstrain and crystallite size on thermal resilience and phase persistence. Thermal profiles revealed by DSC and TGA expose overlapping processes including polymorphic transitions, minor phase dehydration, and redox-driven changes, likely associated with trace components. Mechanochemical processing resulted in partial amorphization and the emergence of phases such as opal and feldspar minerals (microcline, albite, anorthite), interpreted as the product of lattice collapse and subsequent reprecipitation. Heat treatment of chert leads to a progressive rearrangement and recrystallization of its silica phases: quartz collapses around 1000 °C before recovering, tridymite emerges as an intermediate phase, and cristobalite shows the greatest crystallite size growth and least deformation at 1400 °C. These phase changes serve as markers of high-temperature exposure, guiding the identification of heat-altered lithic artefacts, reconstructing geological and diagenetic histories, and allowing engineers to adjust the thermal expansion of ceramic materials. Mechanochemical results provide new insights into the physicochemical evolution of metastable silica systems and offer valuable implications for the design and thermal conditioning of silica-based functional materials used in high-temperature ceramics, glasses, and refractory applications. From a geoarchaeological standpoint, the mechanochemically treated material could simulate natural weathering of prehistoric chert tools, providing insights into diagenetic pathways and lithic degradation processes. Full article

Molten titanium-containing blast furnace slag can be used to obtain cast stone materials by controlling a reasonable heat treatment system. The material acquired during this process showcases residual stress, which additionally impacts the macroscopic characteristics of the material. This article simulates the process of manufacturing microcrystalline cast stones based on the self-crystallisation ability of titanium-containing products. This research employs X-ray diffraction to precisely and conveniently assess the residual stress of microcrystalline cast stones and investigates how viscosity and the thermal expansion coefficient influence the residual stress level. The study provides a theoretical foundation for explaining titanium-containing blast furnace slag and combines characterisation methods such as XRD (X-ray diffraction), SEM (Scanning electron microscope), DTA (Differential thermal analysis), and theoretical calculations such as Factpage and Fullprop to study the effect of the TiO₂ content on the microstructure of self-crystallised mechanical characteristics of microcrystalline cast stones through residual stress. The results of the experiment indicate that as the TiO₂ content in the system increases, the glass phase is reduced, the crystallinity improves, and the main crystal phase changes from a feldspar phase to a diopside phase. Furthermore, its viscosity, thermal expansion coefficient, and residual stress decrease while its corresponding compressive strength and bending strength increase. Full article

In recent years, the vitrified bond diamond grinding wheel has been applied widely in automotive, aerospace and machine tools of manufacturing industries. However, the main problems of low intensity and poor wettability between the vitrified bond and diamond abrasive limit its further application. In this study, BaO was added into the basic SiO₂–B₂O₃–Al₂O₃–R₂O vitrified bond system, and the impact of BaO on the wettability, thermal and mechanical behavior of vitrified bond and vitrified bond diamond composites was systematically discussed, respectively. The test indicated that when the vitrified bond containing BaO of 6 wt.% was sintered with diamond abrasive at 750 °C, a continuous barium feldspar phase transition layer between diamond abrasive and the bond was generated, which ameliorated the wet property of the bond–diamond abrasive. The contact angle varied from 59° on the blank sample to 35°, and the expansion coefficient changed from 6.24 × 10⁻⁶/K to 5.30 × 10⁻⁶/K. The Rockwell hardness and flexural strength of the vitrified bond diamond composites achieved the peaks of 117.5 MPa and 113.6 MPa, respectively, which increased by 20.2% and 16.5% compared with that of sample without the addition of BaO. Full article

The aim of the present study is to link the thermal expansion, spectral reflectance, and physico-mechanical aspects of different types of commercial granitic rocks with their mineralogical and chemical composition. The granitic rock types were characterized using several analyses, including petrography, chemical, mineralogical, and thermo-gravimetrical analysis using XRF, XRD, and TG/DTG/DSC techniques. The rock types were subjected to several performance tests, such as tests of their thermal expansion, spectral reflectance, and physico-mechanical properties. The results revealed that quartz, albite, and potash feldspar with minor amounts of mica (biotite/muscovite/annite) are the main mineralogical constitutes, in addition to some alteration minerals, such as kaolinite, saussorite, and prehnite. The studied granitic rocks were classified as monzogranite/syenogranite of high K-calc-alkaline and peraluminous characters and are related to late- to post-collisional settings. The thermogravimetrical analysis revealed that the overall mass loss over the whole temperature range up to 978 °C did not exceed 3% of the initial weight for all studied rocks. The results of thermal expansion revealed that the maximum change in linear thermal expansion for all rock types did not exceed 0.015% of their initial lengths at an unusual air temperature of 50 °C. The spectral analysis revealed that iron and hydroxyl ions are the main spectral absorption features that appeared in the VIS-NIR and SWIR regions, in addition to the appearance of the common and distinctive absorption peaks of the main mineral composition. Furthermore, the spectral reflectance demonstrated that the granitic rock types of low iron oxide content achieved a high reflectivity percent in the VIS-NIR and SWIR spectral regions compared with those of high iron content. As a general trend, the granitic rock types of high iron content and/or lower quartz content exhibited a high performance regarding their physical and mechanical properties, such as water absorption, apparent porosity, bulk density, compressive strength, and abrasion resistance. The results of water absorption, density, strength, and abrasion resistance of the studied granitic rocks are in the range of 0.14–0.31%, 2582–2644 kg/m³, 77.85–222.75 MPa, and 26.27–55.91 Ha, respectively, conforming to the requirements of ornamental stones according to the ASTM standard. Full article

Pyrophyllite (Al₂Si₄O₁₀(OH)₂) is a phyllosilicate often associated with quartz, mica, kaolinite, epidote, and rutile minerals. In its pure state, pyrophyllite exhibits unique properties such as low thermal and electrical conductivity, high refractive behavior, low expansion coefficient, chemical inertness, and high resistance to corrosion by molten metals and gases. These properties make it desirable in different industries such as refractory; ceramic, fiberglass, and cosmetic industries; as filler in the paper, plastic, paint, and pesticide industries; as soil conditioner in the fertilizer industry; and as a dusting agent in the rubber and roofing industries. Pyrophyllite can also serve as an economical alternative in many industrial applications to different minerals as kaolinite, talc, and feldspar. To increase its market value, pyrophyllite must have high alumina (Al₂O₃) content, remain free of any impurities, and possess as much whiteness as possible. This paper presented a review of pyrophyllite’s industrial applications, its important exploitable properties, and the specifications required for its use in industry. It also presents the most effective and economical techniques for enriching low-grade pyrophyllite ores to make them suitable for various industrial applications. Full article

Slawsonite’s (SrAl₂Si₂O₈) structure evolutions depending on temperature (27–1000 °C) have been studied by in situ single-crystal X-ray diffraction. The SrO₇ polyhedron expands regularly with the temperature increase. Silicon and aluminum cations are ordered in tetrahedral sites of the studied slawsonite; no significant changes in their distribution as temperature increases were observed. Slawsonite demonstrates a relatively high volume thermal expansion (α_V = 23 × 10⁻⁶ °C⁻¹) with high anisotropy, typical for framework feldspar-related minerals and synthetic compounds. It was found that, contrary to previously published data, the crystal structure of slawsonite is stable in the studied temperature range and no phase transitions occur up to 1000 °C. The role of Ca and Ba substitution for Sr and Al/Si ordering on polymorphism of natural MAl₂Si₂O₈ (M = Ca, Sr, Ba) is herein discussed. Full article

The aim of this paper is to numerically predict the temperature effect on the tensile strength of granitic rock. To this end, a numerical approach based on the embedded discontinuity finite elements is developed. The underlying thermo-mechanical problem is solved with a staggered method marching explicitly in time while using extreme mass scaling, allowed by the quasi-static nature of the slow heating of a rock sample to a uniform target temperature, to increase the critical time step. Linear triangle elements are used to implement the embedded discontinuity kinematics with two intersecting cracks in a single element. It is assumed that the quartz mineral, with its strong and anomalous temperature dependence upon approaching the α-β transition at the Curie point (~573 °C), in granitic rock is the major factor resulting in thermal cracking and the consequent degradation of tensile strength. Accordingly, only the thermal expansion coefficient of quartz depends on temperature in the present approach. Moreover, numerically, the rock is taken as isotropic except for the tensile strength, which is unique for each mineral in a rock. In the numerical simulations mimicking the experimental setup on granitic numerical rock samples consisting of quartz, feldspar and biotite minerals, the sample is first heated slowly to a target temperature below the Curie point. Then, a uniaxial tension test is numerically performed on the cooled down sample. The simulations demonstrate the validity of the proposed approach as the experimental deterioration of the tensile strength of the rock is predicted with agreeable accuracy. Full article

Framework silicates form about 70% of the Earth’s crust, mainly feldspars ~50–60% and quartz ~10–15%. Less-abundant feldspathoids include nepheline-, leucite-, and sodalite-group minerals, rich in structurally challenging properties. This review paper deals with anhydrous feldspar-, nepheline-, and leucite/pollucite groups, emphasising the importance of parallel studies on natural and synthetic samples. Four topics are covered. For decades, petrologists have analysed nephelines and recalculated their compositions as endmember molecules but, by not following rules of stuffed-tridymite crystal chemistry, have not estimated reliably the excess SiO₂ present in solid solution. Some materials scientists make similar mistakes, and a new approach is described here. Synthesis studies of analogue feldspars, nephelines, and leucite/pollucites led to collaborative studies, mainly using laboratory and synchrotron X-ray powder diffraction methods at room and elevated temperatures, to study thermal expansion and displacive phase transitions. Such work was recently expanded to address the spontaneous strain relations. Topics covered here include work on nepheline/kalsilite analogues in the system SrAl₂O₄—BaAl₂O₄; thermal expansion of (K,Na)Al-, RbAl-, RbGa-, and SrAl-feldspars; and thermal expansion and phase transitions in analogue leucites KGaSi₂O₆ (tetragonal to cubic) and K₂MgSi₅O₁₂ (monoclinic to orthorhombic). Results are reviewed in the context of research published in mineralogical and more-widely in physical sciences journals. Full article