Search Results (4)

This article suggests a new waveguide design that utilizes a “walled” architecture. Instead of relying on conventional gap waveguide structures to create electronic bandgaps and prevent field leakage, the proposed design introduces a “walled” guiding mechanism. This technique preserves transmission while maintaining the multilayer approach and eliminates the need for nails or chemical bonds to attach the layers. Simulations were carried out in the W-band (75–110 GHz) and D-band (110–170 GHz) using several metals, and measurements were performed in the W-band using aluminum. The simulation results show that the reflection coefficient was less than −40 dB over the entire D-band. At the same time, the average insertion loss was around 0.0054 dB/mm and around 0.0065 dB/mm for silver and gold, respectively. Similarly, the reflection coefficient was less than −45 dB over the 75–110 GHz range, with an average insertion loss of 0.0018 dB/mm for silver and 0.003 dB/mm for gold, respectively. The aluminum model’s reflection coefficient was less than −35 dB, and the average insertion loss was 0.0035 dB/mm. The experimental results achieved a reflection coefficient of less than –30 dB and the average transmission coefficient was −0.2 dB, with an insertion loss of 0.002 dB/mm. The simple stacking ability of the weightless walled metal plates and easy fabrication makes the proposed transmission line a promising technology in mmWave and Terahertz applications. Full article

This review article covers the synthesis and design of conjugated polymers for carefully adjusting energy levels and energy band gap (EBG) to achieve the desired photovoltaic performance. The formation of bonds and the delocalization of electrons over conjugated chains are both explained by the molecular orbital theory (MOT). The intrinsic characteristics that classify conjugated polymers as semiconducting materials come from the EBG of organic molecules. A quinoid mesomeric structure (D-A ↔ D⁺ = A⁻) forms across the major backbones of the polymer as a result of alternating donor–acceptor segments contributing to the pull–push driving force between neighboring units, resulting in a smaller optical EBG. Furthermore, one of the most crucial factors in achieving excellent performance of the polymer is improving the morphology of the active layer. In order to improve exciton diffusion, dissociation, and charge transport, the nanoscale morphology ensures nanometer phase separation between donor and acceptor components in the active layer. It was demonstrated that because of the exciton’s short lifetime, only small diffusion distances (10–20 nm) are needed for all photo-generated excitons to reach the interfacial region where they can separate into free charge carriers. There is a comprehensive explanation of the architecture of organic solar cells using single layer, bilayer, and bulk heterojunction (BHJ) devices. The short circuit current density (J_sc), open circuit voltage (V_oc), and fill factor (FF) all have a significant impact on the performance of organic solar cells (OSCs). Since the BHJ concept was first proposed, significant advancement and quick configuration development of these devices have been accomplished. Due to their ability to combine great optical and electronic properties with strong thermal and chemical stability, conjugated polymers are unique semiconducting materials that are used in a wide range of applications. According to the fundamental operating theories of OSCs, unlike inorganic semiconductors such as silicon solar cells, organic photovoltaic devices are unable to produce free carrier charges (holes and electrons). To overcome the Coulombic attraction and separate the excitons into free charges in the interfacial region, organic semiconductors require an additional thermodynamic driving force. From the molecular engineering of conjugated polymers, it was discovered that the most crucial obstacles to achieving the most desirable properties are the design and synthesis of conjugated polymers toward optimal p-type materials. Along with plastic solar cells (PSCs), these materials have extended to a number of different applications such as light-emitting diodes (LEDs) and field-effect transistors (FETs). Additionally, the topics of fluorene and carbazole as donor units in conjugated polymers are covered. The Stille, Suzuki, and Sonogashira coupling reactions widely used to synthesize alternating D–A copolymers are also presented. Moreover, conjugated polymers based on anthracene that can be used in solar cells are covered. Full article

Herein, the preparation of nanotubular and porous TiO₂ structures (TNS) is presented for photocatalytic applications. Different TNS were prepared in three different types of glycerol- and ethylene glycol-based electrolytes on a large area (approx. 20 cm²) via anodization using different conditions (applied potential, fluoride concentration). Morphology, structure, and optical properties of TNS were characterized by Scanning Electron Microscopy (SEM), X-ray Diffractometry (XRD), and Diffuse Reflectance Spectroscopy (DRS), respectively. All TNS possess optical band-gap energy (E_BG) in the range from 3.1 eV to 3.2 eV. Photocatalytic degradation of caffeine was conducted to evaluate the efficiency of TNS. Overall, nanotubular TiO₂ possessed enhanced degradation efficiencies (up to 50% degradation) compared to those of porous TiO₂ (up to 30% degradation). This is due to the unique properties of nanotubular TiO₂, e.g., improved incident light utilization. As the anodization of large areas is, nowadays, becoming a trend, we show that both nanotubular and porous TiO₂ are promising for their use in photocatalysis and could be potentially applicable in photoreactors for wastewater treatment. We believe this present work can be the foundation for future development of efficient TiO₂ nanostructures for industrial applications. Full article

In this paper, a defected ground-structured antenna with a stub-slot configuration is proposed for future 5G wireless applications. A simple stub-slot configuration is used in the patch antenna to get the dual band frequency response in the 5G mid-band and the upper unlicensed frequency region. Further, a 2-D double period Electronic band gap (EBG) structure has been implemented as a defect in the metallic ground plane to get a wider impedance bandwidth. The size of the slots and their positions are optimized to get a considerably high impedance bandwidth of 12.49% and 4.49% at a passband frequency of 3.532 GHz and 6.835 GHz, respectively. The simulated and measured realized gain and reflection coefficients are in good agreement for both operating bandwidths. The overall antenna structure size is 33.5 mm × 33.5 mm. The antenna is fabricated and compared with experimental results. The proposed antenna shows a stable radiation pattern and high realized gain with wide impedance bandwidth using the EBG structure, which are necessary for the requirements of IoT applications offered by 5G technology. Full article