Search Results (3)

Unauthorised graffiti is a challenge in urban environments, affecting railway structures, stations, tracks, and vehicles. Inefficient cleaning methods increase the costs and downtime of railcars, limiting passenger transport. In turn, they are harmful to the operator’s health and the environment, due to the VOCs they release. This study focuses on the feasibility of dry-ice blasting, replacing carbon dioxide with ambient air as an innovative and sustainable solution to remove graffiti from rail vehicles. Experimental tests have been carried out with 13 different aerosols, controlling the temperature (<−80 °C), pressure (up to 3 bar), projection distance (0.5 cm) and exposure times (30″/1′/2′/4′/6′/8′/++). The results showed that ultra-freezing with ambient air preserved the integrity of the support materials and altered the topography, colourimetry and adhesion of the aerosols tested, achieving the total removal of one of the paints. Preliminary results suggest that ultra-freezing with ambient air could be a viable and sustainable solution for graffiti removal on railway structures, transferable to other urban environments. Full article

Water-in-oil (w/o) nanoemulsions stabilized with amino acid surfactants (AAS) are one example of nanotechnology detergents of the “brush on, wipe off”-type for removing graffiti coatings from different sensitive surfaces. The high-pressure homogenization (HPH) process was used to obtain the nanostructured fluids (NSFs), including the non-toxic and eco-friendly components such as AAS, esterified vegetable oils, and ethyl lactate. The most effective NSF detergent was determined by response surface methodology (RSM) optimization. Afterwards, several surface properties, i.e., topography, wettability, surface free energy, and the work of water adhesion to surfaces before and after their coverage with the black graffiti paint, as well as after the removal of the paint layers by the eco-remover, were determined. It was found that the removal of graffiti with the use of the NSF detergent is more dependent on the energetic properties and microporous structure of the paint coatings than on the properties of the substrates on which the layers were deposited. The use of NSFs and knowledge of the surface properties could enable the development of versatile detergents that would remove unwanted contamination from various surfaces easily and in a controlled way. Full article

The removal of graffiti or over-painting requires special attention in order to not induce the surface destruction but to also address all of the important eco-compatibility concerns. Because of the necessity to avoid the use of volatile and toxic petroleum-based solvents that are common in cleaning formulations, much attention has recently been paid to the design of a variety of sustainable formulations that are based on biodegradable raw materials. In the present contribution we propose a new approach to graffiti cleaning formulations that are composed of newly synthesized green solvents such as esterified plant oils, i.e., rapeseed oil (RO), sunflower oil (SO), or used cooking oil (UCO), ethyl lactate (EL), and alkylpolyglucosides (APGs) as surfactants. Oil PEG-8 ester solvents were synthesized through the direct esterification/transesterification of these oils using monobutyltin(IV) tris(2-ethylhexanoate) and titanium(IV) butoxide catalysts under mild process conditions. The most efficient formulations, determined by optimization through the response surface methodology (RSM) was more effective in comparison to the reference solvents such as the so-called Nitro solvent (denoting a mixture of toluene and acetone) and petroleum ether. Additionally, the optimal product was found to be effective in removing graffiti from glass, metal, or sandstone surfaces under open-field conditions in the city of Wrocław. The performed studies could be an invaluable tool for developing future green formulations for graffiti removal. Full article