Open AccessArticle
On the Structural and Vibrational Properties of Solid Endohedral Metallofullerene Li@C60
by
Martina Vrankić, Takeshi Nakagawa, Melita Menelaou, Yasuhiro Takabayashi, Naoya Yoshikane, Keisuke Matsui, Ken Kokubo, Kenichi Kato, Saori Kawaguchi-Imada, Hirokazu Kadobayashi, John Arvanitidis, Yoshiki Kubota and Kosmas Prassides
Cited by 1 | Viewed by 1979
Abstract
The endohedral lithium fulleride, Li
+@C
60•−, is a potential precursor for new families of molecular superconducting and electronic materials beyond those accessible to date from C
60 itself. Solid Li@C
60 comprises (Li@C
60)
2 dimers, isostructural and
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The endohedral lithium fulleride, Li
+@C
60•−, is a potential precursor for new families of molecular superconducting and electronic materials beyond those accessible to date from C
60 itself. Solid Li@C
60 comprises (Li@C
60)
2 dimers, isostructural and isoelectronic with the (C
59N)
2 units found in solid azafullerene. Here, we investigate the structural and vibrational properties of Li@C
60 samples synthesized by electrolytic reduction routes. The resulting materials are of high quality, with crystallinity far superior to that of their antecedents isolated by chemical reduction. They permit facile, unambiguous identification of both the reduced state of the fulleride units and the interball C-C bonds responsible for dimerization. However, severe orientational disorder conceals any crystal symmetry lowering due to the presence of dimers. Diffraction reveals the adoption of a hexagonal crystal structure (space group
P6
3/
mmc) at both low temperatures and high pressures, typically associated with close-packing of spherical monomer units. Such a situation is reminiscent of the structural behavior of the high-pressure Phase I of solid dihydrogen, H
2.
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