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Keywords = anilinobenzoic acid methyl ester

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Article
Ethylene Polymerization and Copolymerization with Polar Monomers Using Nickel Complexes Bearing Anilinobenzoic Acid Methyl Ester Ligand
by Hailong Cheng, Yue Su, Yanming Hu, Xuequan Zhang and Zhengguo Cai
Polymers 2018, 10(7), 754; https://doi.org/10.3390/polym10070754 - 9 Jul 2018
Cited by 9 | Viewed by 5726
Abstract
Neutral nickel complexes containing an anilinobenzoic acid methyl ester ligand are prepared and applied for the ethylene polymerization and copolymerization with polar monomers. The complex C2 containing isopropyl substituent on the aniline ligand conducts ethylene polymerization with high activity and good thermal stability. [...] Read more.
Neutral nickel complexes containing an anilinobenzoic acid methyl ester ligand are prepared and applied for the ethylene polymerization and copolymerization with polar monomers. The complex C2 containing isopropyl substituent on the aniline ligand conducts ethylene polymerization with high activity and good thermal stability. Most importantly, the catalyst promotes the copolymerization of ethylene and polar monomers with high activity (up to 277 kg·mol−1·h−1), affording ester-functionalized semicrystalline polyethylene with reasonable polar monomer content (up to 3.20 mol %). Full article
(This article belongs to the Special Issue Multi-functional Polymer Composites and Structures)
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