Search Results (5)

This study develops a novel geopolymer foamed concrete using coal gangue and slag as precursors, along with a composite alkali activator comprising sodium silicate and sodium hydroxide, based on the physical foaming method. The Box–Behnken Design within Response Surface Methodology was applied to optimize the mix proportions of coal gangue–slag-based geopolymer foamed concrete. The effects of alkali activator dosage, sodium silicate modulus, water-to-binder ratio, and foam content on 28-day compressive strength and thermal conductivity were systematically investigated to determine the optimal mix for achieving a balance between mechanical and thermal performance. Scanning Electron Microscopy and other characterization techniques were used to analyze the microstructural features. The results show that foam content has the most significant influence on both mechanical and thermal performance, while the interaction between sodium silicate modulus and foam content exhibits the most pronounced combined effect. The optimized mix design consists of 9.1% alkali activator dosage, a sodium silicate modulus of 1.07, a water-to-binder ratio of 0.44, and foam content of 50%, resulting in a 28-day compressive strength of 2.30 MPa and thermal conductivity of 0.0781 W/(m·K). The observed performance enhancement is primarily attributed to the increased heterogeneity in the pore structure. This study provides theoretical and technical support for the development of integrated thermal insulation and load-bearing wall materials suitable for severely cold regions. Full article

The objective of this research is to fabricate waste-based alkali-activated foams with better properties in a quick time by using energy-efficient techniques such as microwave irradiation. The present study reports the effect of microwave heating parameters, including heating time and output power, on the properties of porous alkali-activated materials (AAMs) that use coal gangue (CG) as a precursor. The effects of concrete waste (CW) content (0–20 wt %) on the performance and microstructure of CG-based AAMs were investigated. Mechanical, thermal, and microstructural investigations were conducted to characterize the obtained materials. The experimental results indicate that the best characteristics of CG-based alkali-activated foams were achieved when microwave power and microwave heating time were 800 W and 10 min, respectively. The foams prepared by adding the waste concrete powder increased stability and showed lower bulk density and thermal conductivity. When the waste concrete powder content was 10 wt %, the CG-based alkali-activated foams showed the best overall performance. At the same time, the mechanical properties of the alkali-activated foams declined only slightly (~9%). The findings of this work provide a basis for further studies on improving the characteristics of CG-based alkali-activated foams due to the physical effect of a microwave field on fresh mortar without the use of a chemical foaming agent while reducing energy consumption in the production process. Full article

The feasibility of composite-activated coal gangue (CACG) as the primary cementitious material for concrete was experimentally studied in this paper. The effects of concrete strength grade on slump and slump flow, compressive strength, splitting tensile strength, axial compressive strength, elastic modulus, and drying shrinkage of alkali-activated coal gangue concrete (AACGC) were experimentally investigated. Experimental results indicated that the slump and slump flow of the AACGC were smaller than that of ordinary Portland cement concrete (OPCC). The mechanical properties of the AACGC were superior to those of the OPCC. The compressive strength, splitting tensile strength, axial compressive strength, and elastic modulus of the AACGC were 1.17 times, 1.04 times, 1.47 times, and 1.04 times those of the OPCC, respectively. With the increase in concrete strength grade, the mechanical properties of the AACGC have gradually increased. The difference in failure modes of axial compressive strength between the AACGC and OPCC was analyzed. Moreover, the empirical formulas of the elastic modulus and compressive strength for the OPCC in various regions codes were summarized, and found that the empirical formula in GB 50010-2002 code and EN 1922 Eurocode 2 was also applicable to the AACGC. Finally, the mass-loss rate and drying shrinkage for the AACGC at different concrete strength grades were systematically analyzed, and a hyperbolic prediction model was proposed to reflect the drying shrinkage behavior of the AACGC. Full article

The suitability of applying shrinkage reducing additives in alkali activated coal gangue-slag composites is discussed in this study. The effect of sulphoaluminate cement (SAC), high performance concrete expansion agent (HCSA) and U-type expansion agent (UEA) on the reaction process, shrinkage behavior, phase composition, microstructure and mechanical properties are evaluated. The results show that the addition of SAC slightly mitigates the early stage reaction process, while HCSA and UEA can either accelerate or inhibit the reaction depending on their dosage. The addition of SAC presents an ideal balance between drying shrinkage reduction and strength increment. As for HCSA and UEA, the shrinkage and mechanical properties are sensitive to their replacement level; excessive dosage would result in remarkable strength reduction and expansion. The specific surface area and average pore size of the hardened matrix are found to be closely related with shrinkage behavior. SAC addition introduces additional hydrotalcite phases within the reaction products, while HCSA and UEA mainly result in the formation of CaCO₃ and Ca(OH)₂. It is concluded that applying expansive additives can be an effective approach in reducing the drying shrinkage of alkali activated coal gangue-slag mixtures, while their type and dosage must be carefully handled. Full article

Herein, a new geopolymer is recognized as a potential alternative cementing material of ordinary Portland cement (OPC), which is used for reducing carbon emissions and efficiently recycling the waste. Therefore this paper mainly studied the alkali-activated coal gangue-slag concrete (ACSC) was prepared by using the coal gangue-slag and Na₂SiO₃ and NaOH complex activator. The ratio of coal gangue (calcined and uncalcined) coarse aggregate replacing the gravel was 0%, 30%, 50%, 70%, and 100%. The water and salt freeze-thaw resistance, compressive strength, chloride permeation, microstructure, performance mechanism, inner freeze-thaw damage distribution, and mechanics models of ACSC were investigated. Results show that ACSC displayed excellent early age compressive strength, and the compact degree and uniformity of structure were better compared with the ordinary Portland cement (OPC) when the coal gangue replacement rate was less than 50%. The ACSC demonstrated the best chloride penetration resistance under 30% uncalcined coal gangue content, which was less than 27.75% lower than that of using OPC. At the same number cycles, especially in the salt freezing, the calcined coal gangue had lowered advantages of improving resistance freeze-thaw damage resistance. Water and salt accumulative freeze-thaw damage mechanics models of ACSC were established by using the relative dynamic elasticity modulus. The exponential function model was superior to the power function model with better precision and relativity, and the models accurately reflected the freeze-thaw damage effect. Full article